Comparative assessment of genotoxicity of mineral water packed in polyethylene terephthalate (PET) and glass bottles

The potential migration of genotoxic compounds into mineral water stored in polyethylene terephthalate (PET) bottles was evaluated by an integrated chemical/biological approach using short-term toxicity/genotoxicity tests and chemical analysis. Six commercial brands of still and carbonated mineral water bottled in PET and in glass were stored at 40 °C for 10 days in a stove according to the standard EEC total migration test (82/711/EEC), or at room temperature in the dark. After treatment, the samples were analysed using gas-chromatography/mass spectrometry (GC/MS) to detect volatile and non-volatile compounds, the Microtox^® test to evaluate potential toxicity of the samples, and three mutagenicity tests - Tradescantia and Allium cepa micronucleus tests and the Comet assay on human leukocytes - to detect their genotoxic activity.GC/MS analysis did not detect phthalates or acetaldehyde in the water samples. The Microtox^® test found no toxic effects. Mutagenicity tests detected genotoxic properties of some samples in both PET and glass bottles. Statistical analyses showed a positive association between mineral content and mutagenicity (micronuclei in A. cepa and DNA damage in human leukocytes). No clear effect of treatment and PET bottle was found. These results suggest the absence of toxic compounds migrating from PET regardless of time and conditions of storage. In conclusion, bottle material and stove treatment were not associated with the genotoxic properties of the water; the genotoxic effects detected in bottled water may be related to the characteristics of the water (minerals and CO₂ content).     

Nanofilled polyols for viscoelastic polyurethane foams

The use of polyether polyols is common in polyurethane industry, particularly in soft PU applications. In particular, viscoelastic foams, characterized by slow recovery after compression, are obtained using poly(ethylene oxide) (PEO) polyols. Nanofilled polyols can be used for the production of viscoelastic foams with improved fire resistance properties. The high polarity of polyether polyols is responsible of a poor affinity with the organic modifiers used in commercial organically modified montmorillonite (omMMT). In this work, organically modified montmorillonites were prepared, having an improved affinity with the polyether polyols used for the production of soft PU foams. The montmorillonite was modified by using polyetheramines with different ethyleneoxide/propyleneoxide amounts. A strongly intercalated/exfoliated structure was obtained after mixing the polyol with the omMMT. The viscosity increased by three orders of magnitude and the diffraction angles of the MMT measured by x‐ray analysis decreased to values lower than 1.5°. The intercalated structure was preserved after the curing stage, when the isocyanate was added to the polyol/omMMT. The resulting polyurethane had an irregular open cell structure, and was characterized by a mechanical properties comparable to those of unfilled polyurethane. Copyright © 2009 Society of Chemical Industry     

Homoepitaxial CVD diamond: Raman and time-resolved PL characterization

In this work, we report on the structural characterization of homoepitaxial Microwave Plasma Enhanced CVD diamond grown onto Ib diamond substrates by varying systematically the methane to hydrogen ratio in the gas mixture (1–7% CH₄). X-ray diffraction, Raman spectroscopy and photoluminescence (PL) have been used to characterize the diamond samples. Raman measurements pointed out the excellent crystalline quality and phase purity of the specimens. PL measurements in the 1.7–2.7 eV energy range have shown completely flat spectra, excluding the presence of nitrogen-related optical centers. Such results show that the homoepitaxial CVD diamond can be grown, at moderate microwave power (720 W), and at growth rates not too low ( 1 μm/h) preserving a good quality. Moreover, the homoepitaxial crystals exhibited a strong free-exciton recombination radiation at room temperature even at the highest methane concentration used (7%). Preliminary measurements of the lifetime of the free exciton at room temperature have been also performed. The excitation was produced by a 5 ns pulsed laser irradiation at energies above the diamond band gap. The results have been compared with the structural properties of the samples and correlated with the growth conditions.     

Simulations of the Oxidation and Degradation of Platinum Electrocatalysts

Improved understanding of the fundamental processes leading to degradation of platinum nanoparticle electrocatalysts is essential to the continued advancement of their catalytic activity and stability. To this end, the oxidation of platinum nanoparticles is simulated using a ReaxFF reactive force field within a grand‐canonical Monte Carlo scheme. 2–4 nm cuboctahedral particles serve as model systems, for which electrochemical potential‐dependent phase diagrams are constructed from the thermodynamically most stable oxide structures, including solvation and thermochemical contributions. Calculations in this study suggest that surface oxide structures should become thermodynamically stable at voltages around 0.80–0.85 V versus standard hydrogen electrode, which corresponds to typical fuel cell operating conditions. The potential presence of a surface oxide during catalysis is usually not accounted for in theoretical studies of Pt electrocatalysts. Beyond 1.1 V, fragmentation of the catalyst particles into [Pt₆O₈]^4? clusters is observed. Density functional theory calculations confirm that [Pt₆O₈]^4? is indeed stable and hydrophilic. These results suggest that the formation of [Pt₆O₈]^4? may play an important role in platinum catalyst degradation as well as the electromotoric transport of Pt^2+/4+ ions in fuel cells.     

The influence of loading rates on hardening effects in elasto/viscoplastic strain-hardening materials

In this paper the influence of increasing loading rates on hardening effects is analyzed for rate-dependent elastoplastic materials. The effects of different loading rates on hardening rules are discussed with regard to the constitutive behavior of strain-hardening materials in elasto/viscoplasticity. A suitable procedure for the numerical simulation of rate-sensitive material behavior is illustrated. A comparative analysis is presented on constitutive relations in strain-hardening plasticity without rate effects and with rate effects in order to show the different role played by hardening rules in the rate-sensitivity analysis of elasto/viscoplastic strain-hardening materials. By reporting suitable numerical simulations for the adopted constitutive relations it is shown that when the rate of application of the loading is increased the influence of hardening has a different effect in the mechanical behavior of structures. Computational results and applications are finally illustrated in order to show numerically the different role played by hardening on the plastic strains when the loading rates are incremented for elasto/viscoplastic strain-hardening materials and structures.     

Streaming‐Enabled Parallel Dataflow Architecture for Multicore Systems

We propose a new framework design for exploiting multi‐core architectures in the context of visualization dataflow systems. Recent hardware advancements have greatly increased the levels of parallelism available with all indications showing this trend will continue in the future. Existing visualization dataflow systems have attempted to take advantage of these new resources, though they still have a number of limitations when deployed on shared memory multi‐core architectures. Ideally, visualization systems should be built on top of a parallel dataflow scheme that can optimally utilize CPUs and assign resources adaptively to pipeline elements. We propose the design of a flexible dataflow architecture aimed at addressing many of the shortcomings of existing systems including a unified execution model for both demand‐driven and event‐driven models; a resource scheduler that can automatically make decisions on how to allocate computing resources; and support for more general streaming data structures which include unstructured elements. We have implemented our system on top of VTK with backward compatibility. In this paper, we provide evidence of performance improvements on a number of applications.     

Effectiveness of high-resolution SAR for water resource management in low-income semi-arid countries

This article presents an efficient framework and a sustainable pilot project on the effective use of spaceborne synthetic aperture radar (SAR) in low-income countries and semi-arid climatic contexts. The technical efficiency was pursued by integrating SAR models and hydrological assessment methods; the socio-economical sustainability was guaranteed by the joint work of scientists, technicians, and volunteers. The pilot project was developed in the Yatenga region, a Sahelian area in northern Burkina Faso. In particular, an original development of SAR interferometry algorithms was tailored to the peculiar climate, the soil characteristics, and the land cover of the semi-arid regions. A digital elevation model (DEM) was derived, and an original approach based on the use of SAR amplitude images is proposed for its validation. The achieved resolution (9 m) is significantly better than that of the previously available DEMs in the study area (30 m). Based on the DEM, the soil sedimentation rate of small reservoirs was estimated together with the average soil loss in the contributing catchments due to the erosion process. A multi-temporal filter was implemented on the SAR images for monitoring of water intake volume in small reservoirs, and its seasonal evolution. The developed tools provide an innovative contribution for the improvement of water resource management in the study area. This approach is repeatable and scalable to suit situations with similar economic and climatic conditions.     

The Juxtaposed approximate PageRank method for robust PageRank approximation in a peer-to-peer web search network

We present Juxtaposed approximate PageRank (JXP), a distributed algorithm for computing PageRank-style authority scores of Web pages on a peer-to-peer (P2P) network. Unlike previous algorithms, JXP allows peers to have overlapping content and requires no a priori knowledge of other peers’ content. Our algorithm combines locally computed authority scores with information obtained from other peers by means of random meetings among the peers in the network. This computation is based on a Markov-chain state-lumping technique, and iteratively approximates global authority scores. The algorithm scales with the number of peers in the network and we show that the JXP scores converge to the true PageRank scores that one would obtain with a centralized algorithm. Finally, we show how to deal with misbehaving peers by extending JXP with a reputation model. Partially supported by the EU within the 6th Framework Programme under contract 001907 “Dynamically Evolving, Large Scale Information Systems” (DELIS).     

Transforming paper documents into XML format with WISDOM++

The transformation of scanned paper documents to a form suitable for an Internet browser is a complex process that requires solutions to several problems. The application of an OCR to some parts of the document image is only one of the problems. In fact, the generation of documents in HTML format is easier when the layout structure of a page has been extracted by means of a document analysis process. The adoption of an XML format is even better, since it can facilitate the retrieval of documents in the Web. Nevertheless, an effective transformation of paper documents into this format requires further processing steps, namely document image classification and understanding. WISDOM++ is a document processing system that operates in five steps: document analysis, document classification, document understanding, text recognition with an OCR, and transformation into HTML/XML format. The innovative aspects described in the paper are: the preprocessing algorithm, the adaptive page segmentation, the acquisition of block classification rules using techniques from machine learning, the layout analysis based on general layout principles, and a method that uses document layout information for conversion to HTML/XML formats. A benchmarking of the system components implementing these innovative aspects is reported. Received June 15, 2000 / Revised November 7, 2000