湿塑性水泥土增强研究

从水泥在水泥-水-粘土系统中水化的特点出发，阐述了湿塑性水泥土的强度形成过程，主要是依赖于水泥石的强度骨架与粘土之间的结构连接。通过实验，研究了几种外加剂对湿塑性水泥土的增强作用及其增强机理，结果表明，外加剂能改善水泥土的水化介质环境和结构粘接，可改善水泥土的稠度和强度。     

Vibrational spectroscopic characterization of rigid rod polymers: 3. Microstructural changes in stressed polymers

Highly oriented poly(p-phenylene benzobisthiazole) films were stressed in a miniature hydraulic tensile tester interfaced to a fast scanning Fourier transform infra-red spectrometer. The changes in relative intensity, polarization, frequency and shape of infrared bands have been useful in the elucidation of microstructures. With the short time resolution achievable, vibrational bandshape and frequency have been shown to change at different rates when an external stress was applied.     

用固体核磁技术分析PE 100管材料的抗熔垂性

用固体核磁技术分析了2种具有不同抗熔垂性能的聚乙烯管材料的凝聚态结构与流变性能。管材树脂的抗熔垂性能与其核磁迟豫特性紧密相关,好的抗熔垂性能对应更长的纵向迟豫时间。抗熔垂性能好的双峰管材料的重均分子量更高,高相对分子质量部分的含量更多。     

吊车断裂弹簧钢板的焊接修复

吊车上的板弹簧是一个很重要的零件,它在反复应力下工作,承受较大的冲击负荷和振动,要求其应具有较高的疲劳强度、抗拉强度等性能。由于板弹簧为碳含量较高的合金钢,焊接性差,修复断裂的板弹簧较困难。某公司的一台日本进口TL-252型25t吊车,在使用二年内先后发现五块弹簧钢板断裂,给现场施工带来了不便和一定的经济损失。经制定严格的工艺,对断裂板弹簧成功地进行了焊接修复,修复后使用效果很好。1板簧材料及可焊性分析断裂的弹簧钢板为日本钢号SUP6,相当于我国的60Si2Mn弹簧钢,其化学成份见表1。表1SUP6钢的化学成份(%)C Si Mn S P …     

火焰光度法测定氧化铝中的氧化钠

氧化铝原料纯度高,熔点高,不被氢氟酸—硫酸所分解,但能迅速熔解于热的硫—磷混酸溶液中。控制溶液中硫—磷混酸的浓度,并在氧化钠系列标准溶液中配入等量的硫—磷混酸,即可在火焰光度计上直接测量氧化钠的含量。     

组分对发射盐物相、浸渍温度和稳定性的研究

311、411、612、2.4：0．6：1是常用的阴极钪酸盐（Ba：Ca：Al2摩尔比，分别添加微量Sc2O3）配比。相同工艺条件，4种配比钪酸盐的衍射峰区别不大；相同温度条件，2．4：0．6：1的阴极钪酸盐对纯钨基的浸渍度最高，达到99．34％；同时24：0．6：1的阴极钪酸盐在空气中的稳定性也是最好的。     

新型绝缘树脂及应用

本文介绍了FUCHEM系列无溶剂绝缘树脂的性能及应用，着重探讨了产品的阻燃、低收缩、高耐腐蚀、高耐热等级等特性。     

新型绝缘树脂的应用

本文介绍了FUCHEM系列无溶剂绝缘树脂的性能及应用，着重探讨了产品的阻燃，低收缩，高耐腐蚀，高耐热等级等特性。     

Formation of Polymeric Lewis Acid–Lewis Base Complexes with Well-defined Organoboron Polymers

The binding of Lewis bases to organoboron polymeric Lewis acids has been studied and the parameters that determine the complexation equilibrium have been investigated, which include (i) the strength of the individual Lewis acids and Lewis bases, (ii) concentration, and (iii) temperature. While the strongly Lewis acidic borane polymers poly(4-bis(pentafluorophenyl)borylstyrene) (PS-BPf) and poly(4-(di-2-thienylboryl)styrene) (PS-BTh) form isolable complexes with strong Lewis bases such as 4-t-butylpyridine (^tPy), a temperature dependent equilibrium is established with weaker bases such as THF. Similarly, the weakly Lewis acidic boronate polymer poly(4-diethoxyborylstyrene) (PS-BOEt) undergoes a temperature dependent equilibrium with the strong Lewis base 4-dimethylaminopyridine (DMAP), while poly(4-pinacolatoborylstyrene) (PS-BPin) does not significantly bind to pyridine bases. Decomplexation of PS-BTh· ^t Py is achieved by treatment with the stronger Lewis acid, B(C₆F₅)₃, thereby confirming the reversible nature of the polymeric Lewis acid–base adducts. This paper is dedicated to Professor Ian Manners in gratitude of his guidance throughout the years and recognition of his scientific accomplishments     

动态硫化NBR/PFPA热塑性弹性体流变性能的研究

对动态硫化NBR／石油发酵尼龙（PFPA）共混型热塑性弹性体的流变性能进行了研究。结果表明，NBR／PFPA为假塑性流体；表观粘度随剪切速率和剪切应力的增大而减小，随温度升高而降低；粘流活化能随PFPA用量的增大而减小。