Studies on the synthesis and chromatographic behaviour of the esters of gallic acid and galloylglycollic acid

Several esters of gallic acid, and galloylglycollic acid have been synthesised, the latter for the first time. Their behaviour on thin-layer chromatograms have been examined and five suitable solvent systems are described, which enable their convenient separation and identification on the basis of R_f values.     

An authorization model for multimedia digital libraries

In this paper we present a generalized authorization model for multimedia digital libraries. Our aim is to support the enforcement of access control requirements of the original data sources without the need to create a new, unified model for the digital library. We integrate the three most widely used access control models (i.e., mandatory, discretionary, and role-based) within a single framework, allowing seamless accesses to data protected by these security models. In particular, we address the access control needs of continuous media data while supporting quality of service (QoS) requirements and preserving operational semantics. The technical core of the paper focuses on the development of metadata and the corresponding metastructure to represent authorization policies and QoS requirements and shows their applicabilty to continuous media. We define our security objects based on the Synchronized Multimedia Integration Language (SMIL), which controls multimedia presentations. Following the synchronization constructs par and seq of SMIL, we define a normal form for multimedia streams, called SMIL normal form. SMIL normal form provides a syntax-independent representation of semantically equivalent multimedia data. SMIL normal form compositions are extended (decorated) with RDF statements, representing security and QoS metadata. Interpretation of these statements and, therefore, the authorization and QoS requirements of the decorated multimedia object are defined by the metastructure, represented as a DAML+OIL ontology. We propose the concept of generalized subject that encompasses all access permissions of a given user regardless of the multiple permissions in different access control models. Finally, we develop methods to generate secure views for each generalized subject and retrieve them using a secure multimedia server.     

Preliminary assessment of U.K. human dietary and inhalation exposure to polybrominated diphenyl ethers

This study reports concentrations of BDEs 47, 99, 100, 153, and 154 in outdoor air [median sigmaPBDE (sum of BDEs 47, 99, 100, 153, and 154) = 18 pg m(-3)] in air from a range of office and home indoor microenvironments (median sigmaPBDE = 762 pg m(-3)) and vegan and omnivorous duplicate diet samples (median sigmaPBDE = 154 and 181 pg g(-1) dryweightforvegan and omnivorous diets, respectively). Median daily human exposure to sigmaPBDE via inhalation is 6.9 ng/person and 90.5 ng/person via diet but the relative significance of these pathways may vary considerably between individuals. Median concentrations in indoor air were higher in workplace (sigmaPBDE = 1082 pg m(-3)) than in domestic (sigmaPBDE = 128 pg m(-3)) microenvironments, and substantial differences in concentrations in air from different rooms in the same office building were found. When data from the only mechanically ventilated room was excluded, a significant positive correlation (p < 0.001) was observed between PBDE concentrations and both the number of electrical appliances and polyurethane foam-containing chairs. Concentrations of sigmaPBDE and BDEs 47 and 99 were significantly higher (p < 0.1) in omnivorous diet samples than in vegan diet samples, implying that while plant-based foods contribute appreciably, higher exposure occurs via ingestion of animal-based comestibles.