Confusion,social knowledge and the design of intelligent machines

This paper explores the notion of confusion as it applies to the design of intelligent machines and suggests that it arises from the social nature of knowledge. It provides a framework for analysing the causes of confusion and shows how confusion normally reveals itself after the cause of the confusion has occurred. This places practical limitations on how intelligent machines can react to confusion when it is noticed. The paper also describes a prototype system that aims to minimize the effects of confusion by allowing the users to explore the design rationale of the system.     

Controlled morphology and optical properties of n-type porous silicon: effect of magnetic field and electrode-assisted LEF

Fabrication of photoluminescent n-type porous silicon (nPS), using electrode-assisted lateral electric field accompanied with a perpendicular magnetic field, is reported. The results have been compared with the porous structures fabricated by means of conventional anodization and electrode-assisted lateral electric field without magnetic field. The lateral electric field (LEF) applied across the silicon substrate leads to the formation of structural gradient in terms of density, dimension, and depth of the etched pores. Apart from the pore shape tunability, the simultaneous application of LEF and magnetic field (MF) contributes to a reduction of the dimension of the pores and promotes relatively more defined pore tips as well as a decreased side-branching in the pore walls of the macroporous structure. Additionally, when using magnetic field-assisted etching, within a certain range of LEF, an enhancement of the photoluminescence (PL) response was obtained.     

Survey of integrated‐circuit‐oscillator phase‐noise analysis

This tutorial distills the salient phase‐noise analysis concepts and key equations developed over the last 75 years relevant to integrated circuit oscillators. Oscillator phase and amplitude fluctuations have been studied since at least 1938 when Berstein solved the Fokker–Planck equations for the phase/amplitude distributions of a resonant oscillator. The principal contribution of this work is the organized, unified presentation of eclectic phase‐noise analysis techniques, facilitating their application to integrated circuit oscillator design. Furthermore, we demonstrate that all these methods boil down to obtaining three things: (1) noise modulation function; (2) noise transfer function; and (3) current‐controlled oscillator gain. For each method, this paper provides a short background explanation of the technique, a step‐by‐step procedure of how to apply the method to hand calculation/computer simulation, and a worked example to demonstrate how to analyze a practical oscillator circuit with that method. This survey article chiefly deals with phase‐noise analysis methods, so to restrict its scope, we limit our discussion to the following: (1) analyzing integrated circuit metal–oxide–semiconductor/bipolar junction transistor‐based LC, delay, and ring oscillator topologies; (2) considering a few oscillator harmonics in our analysis; (3) analyzing thermal/flicker intrinsic device‐noise sources rather than environmental/parametric noise/wander; (4) providing mainly qualitative amplitude‐noise discussions; and (5) omitting measurement methods/phase‐noise reduction techniques. Copyright © 2013 John Wiley & Sons, Ltd.     

Tough,strong, hard,and chemically durable enstatite-zirconia glass-ceramic

Strong glass-ceramics (GCs) have been envisaged and widely researched for various applications, including large architectural panels, ballistic impact protection, bioactive medical implants, and odontological prostheses. Here, we report on the development and characterization of a novel hard, strong and tough enstatite-zirconia (MgSiO₃-ZrO₂) glass-ceramic derived from a 51SiO₂–35MgO–6Na₂O–4ZrO₂–4TiO₂ (mol%) glass. The best GC was developed by treating glass samples for nucleation at 700°C for 12 hours, followed by crystal growth at 1090°C for 3 minutes. It was characterized by X-ray fluorescence (XRF), differential scanning calorimetry (DSC), X-ray diffraction (XRD), scanning electron microscopy (SEM), and high-resolution transmission electron microscopy (HR-TEM), and contained plate-like enstatite, zirconia, and Ti-containing crystals. We investigated the nucleating ability of ZrO₂ and TiO₂ in inducing internal nucleation. In the early stage of crystallization, enstatite spherulites were observed, which were precipitated by heterogeneous nucleation on previously nucleated ZrO₂ nano-crystals. At more advanced stages, at high temperatures, they transformed into plate-like crystals. The ball-on-three-balls strength, elastic modulus, and Vickers micro-hardness of the GC are 323 ± 26 MPa, 146 ± 13 GPa, and 6.9 ± 0.1 GPa (load = 5N), respectively. The indentation (K_C), single-edge notched beam bending (K_IC), and crack tip (K_tip) fracture toughness are 2.8 ± 0.6 MP.m^0.5, 2.2 ± 0.3 MP.m^0.5, 1.9 ± 0.3 MP.m^0.5, respectively. The crack propagation profile after a controlled Vickers indentation was quite intricate. The enstatite and zirconia crystals enhanced crack deflection, bridging and branching, hindering crack propagation. According to the ISO 6872 for dental materials, the chemical solubility of our GC is 80 ± 5 μg/cm². Due to this positive combination of high strength, toughness, hardness, and chemical durability, this new glass-ceramic is envisioned as a candidate for several applications and could be further developed for memory disc substrates, architectural cladding and tiles, ceramic glazes, and dental materials.     

Effect of Microstructure on the Radioluminescence and Transparency of Ce-Doped Strontium Hafnate Ceramics

In this paper we report on the fabrication and characterization of SrHfO(3):Ce ceramics. Powders were prepared by solid-state synthesis using metal oxides and carbonates. X-ray diffraction measurements showed that phase-pure SrHfO(3) is formed at 1200°C. Inductively coupled plasma spectroscopy confirmed the purity and composition of each batch. SrHfO(3) exhibits several phase changes in the solid, but this does not appear to be detrimental to the ceramics. Microprobe experiments showed uniform elemental grain composition, whereas aluminum added as charge compensation for trivalent cerium congregated at grain boundaries and triple points. Radioluminescence spectra revealed that the light yield decreases when the concentration of excess Sr increases. The decrease in the light yield may be related to the change of Ce(3+) into Ce(4+) ions. For stoichiometric SrHfO(3):Ce, the light yield is about four times that of bismuth germanate (BGO), the conventional benchmark, indicating great potential for many scintillator applications.     

Photophysics of polyaniline: Sequence-length distribution dependence of photoluminescence quenching as studied by fluorescence measurements and Monte Carlo simulations

The dependence of the fluorescence quenching of electropolymerized poly(aniline-co-m-chloroaniline) with polymer composition has been investigated. Fluorescence emission in polyaniline is quenched when the polymer is oxidized (brought to emeraldine state); the copolymers exhibit decreasing quenching as chloroaniline contents increases. Quenching shows a strong decrease in the presence of 0.1% m-chloroaniline monomers in the feed. The presence of dichloroaniline units in the copolymer was confirmed by XPS measurements and a terpolymerization reaction scheme was developed, obtaining the kinetic parameters. By Monte Carlo simulation the sequence length distributions for different compositions were obtained and compared; it was found that quenching, for low aniline contents, requires aniline sequences of at least three units. The strong decrease in quenching at low m-chloroaniline contents is attributed to a double effect: breaking of conjugation in the emeraldine form by the presence of the chlorinated unit, and a disruption of the close chain packing in the crystalline domains, preventing state delocalization and thus efficient quenching.     

Dynamic Allocation of Ragged Arrays Using C++: Potentiality for Finite-Element Method Software

A ragged array is an irregularly shaped data structure that is an extremely convenient and natural means of implementing storage schemes that exploit the symmetry and sparsity of the different stiffness matrices involved in the finite-element method. Ragged arrays have the potential for improving the programmer’s productivity as well as enhancing code maintainability. Additionally, no performance degradation was detected when ragged arrays were used; the performance of the Gauss elimination procedure, implemented in C++ using ragged arrays, was comparable to the performance of the same procedure implemented in FORTRAN using traditional data structures.     

On the influence of residual stresses on the fracture behavior of a structural steel in the KIc temperature range

The increase with increasing temperature of K_Ic, measured with 2CT and 1'CT specimens, from about 10³N mm at 77 K to about 2.10³ N mm at about 170 K is attributed to the increasing proportion of dimple to cleavage fracture as revealed by scanning electron microscope investigation.

The specimens were prestrained to different partial scale yielding states by the same kind of loading, performed at 298 K, as in the later K_Ictests, performed at 77 K. After pretension K_Ic = K^*_Ic is increased by a maximum amount of about half of the value K⁰_Icof nonprestrained specimens, after precompression it is reduced by the same amount if this value is evaluated from the load at which a pop-in occurs. The value K_Ic = K^**_Ic for the final fracture lies between K^*_Ic and K⁰_Ic. These results are interpretated in terms of the residual stress states due to prestraining.