Investigations on Selectivity of Gas-Liquid Reactions in Capillaries

Biocatalysis offers a broad spectrum of possible ecological and economic advantages over conventional chemical catalysis processes, e.g., lower energy consumption and high enantio selectivity. The focus of this work is on gas-liquid reactions. These are of great importance in the chemical and biochemical industry and subject of current research since they are often limited by mass transfer or show low selectivity. Different suitable biocatalytically gas-liquid reaction systems were tested in capillary reactor designs in order to obtain information about the interaction between reaction and fluid mechanics. Furthermore, an optical measuring method was established. The experiments were performed in batch mode in a glass beaker with a flow cuvette for UV/Vis measurement of product concentration.     

Expanding the social performance of food production landscapes: measuring health and well-being benefits

Advocates of integrating food production landscapes within urban, suburban, campus and other design arenas cite multiple and integrated benefits, including enhanced food security and quality; land access for small farmers; psychological and social benefits; educational opportunities; and green infrastructure contributions, among others. If performance can be understood as ‘the fulfilment of a claim’ then landscape performance measures for food production would ideally encompass the overall range of cited benefits. Yet in current practice the performance of food production landscapes tends to be measured in limited ways, most often by weight and value of harvest. The aim of this paper is to identify expanded methods and metrics for measuring the performance of food production landscapes, in particular for health and well-being benefits. Through a transdisciplinary literature review, evidence for mental well-being, physical activity and human nutrition benefits of food production landscapes is presented, and performance metrics and evaluation methods are catalogued.     

Micro-channel development and hydrogen adsorption properties in templated microporous carbons containing platinum nanoparticles

Ordered microporous carbons containing dispersed platinum nanoparticles were fabricated and chosen as suitable models to investigate micro-structure development and hydrogen transport properties of zeolite-templated carbons. X-ray photoelectron spectroscopy analysis revealed that the enhanced heat of adsorption is related to the narrow micro-channels templated from the zeolite and the presence of certain CO groups on the carbon. The lack of a well-defined and intense rotational transition line and the persistent broad H₂ recoil spectrum in neutron scattering results suggests a distribution of binding sites. Most interestingly, hydrogen diffusion occurs on two time scales, consisting of a fast liquid-like jump diffusion on the timescale of picoseconds along with an even faster bulk-like diffusion. The liquid-like motion is characterized by a diffusion constant of (2.1 ± 0.3) × 10⁻⁸ m²/s with an activation energy of ca. 77 K; both values indicate somewhat lower mobility than similar dynamics of H₂ on nanotubes, activated carbon XC-72, or Grafoil, yet greater mobility than that of bulk liquid. These unusual characteristics for hydrogen in carbons are believed to arise from the network of narrow pores in this zeolite-templated image of the zeolite. In fact, the diffusion constants of the templated carbons are extremely similar to those measured for zeolite 13X.     

Filter Bank Channelizers for Multi-Standard Software Defined Radio Receivers

The ability to support multiple channels of different communication standards, in the available bandwidth, is of importance in modern software defined radio (SDR) receivers. An SDR receiver typically employs a channelizer to extract multiple narrowband channels from the received wideband signal using digital filter banks. Since the filter bank channelizer is placed immediately after the analog-to-digital converter (ADC), it must operate at the highest sampling rate in the digital front-end of the receiver. Therefore, computationally efficient low complexity architectures are required for the implementation of the channelizer. The compatibility of the filter bank with different communication standards requires dynamic reconfigurability. The design and realization of dynamically reconfigurable, low complexity filter banks for SDR receivers is a challenging task. This paper reviews some of the existing digital filter bank designs and investigates the potential of these filter banks for channelization in multi-standard SDR receivers. We also review two low complexity, reconfigurable filter bank architectures for SDR channelizers based respectively on the frequency response masking technique and a novel coefficient decimation technique, proposed by us recently. These filter bank architectures outperform existing ones in terms of both dynamic reconfigurability and complexity.     

Non‐Covalent Functionalization of Graphene Using Self‐Assembly of Alkane‐Amines

A simple, versatile method for non‐covalent functionalization of graphene based on solution‐phase assembly of alkane‐amine layers is presented. Second‐order Møller–Plesset (MP2) perturbation theory on a cluster model (methylamine on pyrene) yields a binding energy of ≈220 meV for the amine–graphene interaction, which is strong enough to enable formation of a stable aminodecane layer at room temperature. Atomistic molecular dynamics simulations on an assembly of 1‐aminodecane molecules indicate that a self‐assembled monolayer can form, with the alkane chains oriented perpendicular to the graphene basal plane. The calculated monolayer height (≈1.7 nm) is in good agreement with atomic force microscopy data acquired for graphene functionalized with 1‐aminodecane, which yield a continuous layer with mean thickness ≈1.7 nm, albeit with some island defects. Raman data also confirm that self‐assembly of alkane‐amines is a non‐covalent process, i.e., it does not perturb the sp² hybridization of the graphene. Passivation and adsorbate n‐doping of graphene field‐effect devices using 1‐aminodecane, as well as high‐density binding of plasmonic metal nanoparticles and seeded atomic layer deposition of inorganic dielectrics using 1,10‐diaminodecane are also reported.     

Polyelectrolyte multilayer electrostatic gating of graphene field-effect transistors

We apply polyelectrolyte multilayer films by consecutive alternate adsorption of positively charged polyallylamine hydrochloride and negatively charged sodium polystyrene sulfonate to the surface of graphene field effect transistors. Oscillations in the Dirac voltage shift with alternating positive and negative layers clearly demonstrate the electrostatic gating effect in this simple model system. A simple electrostatic model accounts well for the sign and magnitude of the Dirac voltage shift. Using this system, we are able to create p-type or n-type graphene at will. This model serves as the basis for understanding the mechanism of charged polymer sensing using graphene devices, a potentially technologically important application of graphene in areas such as DNA sequencing, biomarker assays for cancer detection, and other protein sensing applications.