Relation of anodic and cathodic performance to pH variations in membraneless microbial fuel cells

One-compartment (membraneless) microbial fuel cells (MFCs) are effective tools to test new bio-technology at a laboratory level. More efforts in MFC design and materials are necessary to move from laboratory tests to real applications.     

The behavior of dietary fiber in the gastrointestinal tract determines its physiological effect

A diet rich in dietary fiber (DF) is considered healthy and recommended dietary intake of DF is established all over the world. The physiological effect of DF is mostly related to its behavior during digestion. In this review, the behavior of DF in the human digestive tract is discussed and linked to its physiological effect with special attention to four aspects of such behavior: (i) the modulation of bioavailability by the plant cell walls, (ii) the effect of DF on the rheological and colloidal state of digesta, (iii) the binding of DF with phenolic compounds, bile salts, mineral ions, and digestive enzymes, and (iv) DF fermentation in the large intestine and the corresponding effect on microbiota composition. It is stressed that the detailed chemical characterization of DF is crucial to explain its effect on health and that DF behavior in the digestive tract can be modulated by interactions with other food and meal components so that information of the bare content in DF of food is not sufficient to predict its physiological effect.     

Oxidative Stress and Low-Grade Inflammation in Polycystic Ovary Syndrome: Controversies and New Insights

The pathophysiology of Polycystic Ovary Syndrome (PCOS) is quite complex and different mechanisms could contribute to hyperandrogenism and anovulation, which are the main features of the syndrome. Obesity and insulin-resistance are claimed as the principal factors contributing to the clinical presentation; in normal weight PCOS either, increased visceral adipose tissue has been described. However, their role is still debated, as debated are the biochemical markers linked to obesity per se. Oxidative stress (OS) and low-grade inflammation (LGI) have recently been a matter of researcher attention; they can influence each other in a reciprocal vicious cycle. In this review, we summarize the main mechanism of radical generation and the link with LGI. Furthermore, we discuss papers in favor or against the role of obesity as the first pathogenetic factor, and show how OS itself, on the contrary, can induce obesity and insulin resistance; in particular, the role of GH-IGF-1 axis is highlighted. Finally, the possible consequences on vitamin D synthesis and activation on the immune system are briefly discussed. This review intends to underline the key role of oxidative stress and low-grade inflammation in the physiopathology of PCOS, they can cause or worsen obesity, insulin-resistance, vitamin D deficiency, and immune dyscrasia, suggesting an inverse interaction to what is usually considered.     

Computational flowfield analyses of hypersonic problems with reacting boundary layer

A mathematical model able to deal with high temperature gas effects in hypersonic flow fields is presented. In order to assess this model, four typical hypersonic applications are considered. The numerical results are presented and compared with experimental data. The effects of the catalyticity of the materials on the heat fluxes are also highlighted.     

Control of beam vibrations by means of piezoelectric devices: theory and experiments

The problem of the attenuation of the vibration effects in active cantilever beams has been approached by two strategies, position and velocity control, which have been simulated numerically and analysed experimentally. The numerical simulation has been developed by means of a finite element approach based on an Euler–Bernoulli model and subsequent modal factorisation. Each device as well as each electronic circuit, present in the single-input single-output control system has been modelled and the results of the numerical simulations have been compared with the ones obtained in the experimental tests. A good correspondence has been obtained in all the examined cases.     

Feasibility of horizon-switching predictive control under positional and incremental input saturations

This paper proves the validity of a basic feasibility property which makes it possible to extend, to the case of set-point tracking in ANCBI systems under joint positional and incremental input saturations, the approach in [Mosca, E. (2005). Predictive switching supervisory control of persistently disturbed input-saturated plants. Automatica, 41, 55-67] restricted to positional input saturation and the pure regulation problem. An example on the use of the proposed technique is considered.     

Predictive switching supervisory control of persistently disturbed input-saturated plants

Predictive switching logic schemes are considered whereby a feedback-gain is switched-on at any time from a family of candidate feedback-gains so as to control a discrete-time input-saturated LTI system possibly subject to persistent bounded disturbances of unknown arbitrary magnitude. It is constructively shown that such schemes do exist which ensure, along with good tracking performance, global asymptotic and semi-global exponential stability in the noiseless case, as well as finite l_∞-induced gain to the disturbance-to-state map, whenever the structure of the disturbed plant can make such properties conceptually achievable, viz., the disturbance which enters an Asymptotically Null-Controllable with Bounded Input (ANCBI) system acts directly only on the stable modes, while the critically unstable ones are indirectly affected by the disturbance only via the feedback controls. More generally, in ANCBI systems general disturbances of suitably bounded magnitude can also be handled by the scheme, provided that the switching logic be equipped with an appropriate hysteresis facility.     

Surface Reconstruction Engineering with Synergistic Effect of Mixed-Salt Passivation Treatment toward Efficient and Stable Perovskite Solar Cells

Surface passivation treatment is a widely used strategy to resolve trap-mediated nonradiative recombination toward high-efficiency metal-halide perovskite photovoltaics. However, a lack of passivation with mixture treatment has been investigated, as well as an in-depth understanding of its passivation mechanism. Here, a systematic study on a mixed-salt passivation strategy of formamidinium bromide (FABr) coupled with different F-substituted alkyl lengths of ammonium iodide is demonstrated. It is obtained better device performance with decreasing chain length of the F-substituted alkyl ammonium iodide in the presence of FABr. Moreover, they unraveled a synergistic passivation mechanism of the mixed-salt treatment through surface reconstruction engineering, where FABr dominates the reformation of the perovskite surface via reacting with the excess PbI₂. Meanwhile, ammonium iodide passivates the perovskite grain boundaries both on the surface and top perovskite bulk through penetration. This synergistic passivation engineer results in a high-quality perovskite surface with fewer defects and suppressed ion migration, leading to a champion efficiency of 23.5% with mixed-salt treatment. In addition, the introduction of the moisture resisted F-substituted groups presents a more hydrophobic perovskite surface, thus enabling the decorated devices with excellent long-term stability under a high humid atmosphere as well as operational conditions.