Two-Stage Ozonation – Adsorption Purification of Ground Water from Trichloroethylene and Tetrachloroethylene with Application of Commercial Carbon Adsorbents

ABSTRACT

The aim of the research is to choose the most efficient adsorbent for two-stage ozone-sorption purification of groundwater containing both trichloroethylene (TCE) and tetrachloroethylene (PCE) between three carbon sorbents produced in Russia (AUT-M, CAUSORB-221, and AG-3). Sorption isotherms of TCE and PCE on AUT-M and CAUSORB-221 at 296 K were fitted by the Freundlich equation. The better TCE and PCE sorption ability of AUT-M in comparison with CAUSORB – 221 and AG-3 was demonstrated.

The optimum parameters for ozonation and sorption stages of groundwater purification from TCE and PCE are elucidated using laboratory and pilot-plant scales. Prolonged test of this technology for purification of ground demonstrated that the higher achievable efficiency of destruction with ozone is 94% for TCE and 38% for PCE. Ozonation-sorption treatment of groundwater allows one to achieve TCE and PCE removal efficiency of 96-97% and 92-94% correspondingly. The most efficient carbon sorbent is microporous carbon fiber AUT-M. Using this sorbent, TCE and PCE concentrations in treated water decrease below the MPC level (5 μg/L) adopted in Russia. It is concluded that the combination of ozonation with sorption of residual contaminants by carbon sorbents is a promising way for the purification of waters containing chlorinated contaminants.     

Piecewise approximate analytical solutions for a Jeffcott rotor with a snubber ring

In the paper two approximate analytical methods for calculating nonlinear dynamic responses of an idealised model of a rotor system are devised in order to obtain robust analytical solutions, and consequently speed up the computations maintaining high computational accuracy. The physical model, which is similar to a Jeffcott rotor, assumes a situation where gyroscopic forces can be neglected and concentrates on the dynamic responses caused by interactions between a whirling rotor and a massless snubber ring, which has much higher stiffness than the rotor. The system is modelled by two second-order differential equations, which are linear for non-contact and strongly nonlinear for contact scenarios. The first and the simpler method has been named one point approximation (1PA) and uses only one point in the first-order Taylor expansion of the nonlinear term. It is suitable for soft impacts and gives a reasonable prediction of responses ranging from period one to period four motion. The second and more accurate method of multiple point approximation (MPA) expands the nonlinear term many times when the rotor and the snubber ring are in contact and it can even be used for calculating chaotic responses. The methods are evaluated by a comparison with direct numerical integration showing an excellent level of accuracy.     

Aqueous fullerene C60 solution suppresses herpes simplex virus and cytomegalovirus infections

Abstract

Fullerene C₆₀ is known as a promising therapeutic agent due to its antioxidant, anti-inflammatory and other properties, along with the lack of noticeable toxicity. In this article, we describe antiviral properties of aqueous fullerene C₆₀ dispersion (ndC₆₀) produced by biocompatible diafiltration technology and C₆₀ amino derivatives against Herpes simplex virus type 1 (HSV-1) and Human cytomegalovirus (HCMV) infections. Their activity in vitro was evaluated by a plaque reduction assay using Vero and HF cells in pre- and post-treatment modes. Therapeutic efficacy of dnC₆₀ and C₆₀ derivatives was studied in DBA mice using cutaneous model of HSV-1 infection. Data obtained indicated low cytotoxicity of all used compounds for both cell lines (CC₅₀ > 1?mg/ml). The antiviral activity of dnC₆₀ in most tests exceeded the activity of both C₆₀ amino adducts and acyclovir (ACV), and it demonstrated significant therapeutic effect against HSV-1 skin infection in mice.     

Internal migration of scientists in Russia and the USA: the case of physicists

To assess endocrinologic and metabolic research productivity in East Asia (i.e., China, Japan, and South Korea) and correlations between socioeconomic factors and endocrinologic and metabolic research productivity. Articles (except editorials, conference abstracts, letters, news, and corrections) published in 134 endocrinology and metabolism journals in 2005–2014 were screened with the Web of Science database. Total and annual numbers of articles, study designs, impact factors, citations, and articles in high-impact-factor journals were determined for China, Japan, and South Korea. Annual numbers of articles were related to socioeconomic factors for each country. In 2005–2014, there were 144,660 articles from East Asia published in endocrinology and metabolism journals: 10,190, 9470, and 3124 from Japan, China, and South Korea, respectively. Japan published the most randomized controlled trials, followed by China and South Korea, respectively. China had the most articles in high-impact-factor journals, followed by Japan and South Korea, respectively. South Korea had the highest average impact factor and number of citations. During the period studied, annual numbers of articles from China and South Korea increased remarkably (P < 0.05) but remained stable for Japan. Annual numbers of articles from China and South Korea were positively correlated with gross domestic product and expenditure on health care (P < 0.05). The increase in endocrinology and metabolism articles during 2005–2014 in China and South Korea was associated with improved socioeconomic conditions. China has made progress in scientific publication in the past decade; however, there is still room for improvement.     

Residual stresses in the graded interlayer between W and CuCrZr alloy

Journal of Materials Science - One of the big challenges for realizing future nuclear fusion reactors is the development of materials able to withstand the high thermal loads and particle fluxes...     

Four-Variable Model of an Enzymatic Oscillator Based on Trypsin

This paper describes a four-variable model for an enzymatic oscillator based on trypsin. Variables in this model are concentrations of the essential proteins (trypsin and trypsinogen) and small molecules (masked and active inhibitors of trypsin) within the network. Importantly, to simplify the model, non-essential side reactions are neglected and essential reactions are assumed to follow first or second order kinetics. Numerical solutions of this reduced model semi-quantitatively reproduce experimentally determined periods, amplitudes, and phase shifts of oscillations in the concentrations of several species in the network. Moreover, linear stability analysis shows that oscillations in the trypsin oscillator emerge and disappear through Hopf bifurcation. The model will be helpful in situations where simplicity is necessary such as detailed analysis of dynamics and modeling of reaction-diffusion systems.     

Metallic nanocrystals near ultrasmooth metallic films for surface-enhanced Raman scattering application

We studied the effect of the substrate on the surface-enhanced Raman scattering (SERS) signals of metallic nanocrystal films by making a direct comparison between cases with metallic and semiconducting substrate surfaces. Ag nanoparticles smaller than 10?nm were synthesized and uniform arrays were formed on both ultrasmooth metallic and Si surfaces. These substrates provide reproducible SERS signals with high enhancement factors over large areas. Moreover, a SERS signal about one order of magnitude higher was obtained in the metallic surface case as compared with the Si substrate case, which is attributed to stronger plasmon coupling between the nanoparticles and their charge-conjugate images in the underlying metallic surface. The interpretation of our experimental results was confirmed by our finite difference time domain calculations. The dependence of the interaction between the nanoparticles and the substrate surface on the direction of the incident electromagnetic field is also discussed.     

Piecewise linear approach to an archetypal oscillator for smooth and discontinuous dynamics

In a recent paper we examined a model of an arch bridge with viscous damping subjected to a sinusoidally varying central load. We showed how this yields a useful archetypal oscillator which can be used to study the transition from smooth to discontinuous dynamics as a parameter, alpha, tends to zero. Decreasing this smoothness parameter (a non-dimensional measure of the span of the arch) changes the smooth load-deflection curve associated with snap-buckling into a discontinuous sawtooth. The smooth snap-buckling curve is not amenable to closed-form theoretical analysis, so we here introduce a piecewise linearization that correctly fits the sawtooth in the limit at alpha=0. Using a Hamiltonian formulation of this linearization, we derive an analytical expression for the unperturbed homoclinic orbit, and make a Melnikov analysis to detect the homoclinic tangling under the perturbation of damping and driving. Finally, a semi-analytical method is used to examine the full nonlinear dynamics of the perturbed piecewise linear system. A chaotic attractor located at alpha=0.2 compares extremely well with that exhibited by the original arch model: the topological structures are the same, and Lyapunov exponents (and dimensions) are in good agreement.