Experimental and computational analysis of the coolant distribution considering the viscosity of the cutting fluid during machining with helical deep hole drills

An experimental analysis regarding the distribution of the cutting fluid is very difficult due to the inaccessibility of the contact zone within the bore hole. Therefore, suitable simulation models are necessary to evaluate new tool designs and optimize drilling processes. In this paper the coolant distribution during helical deep hole drilling is analyzed with high-speed microscopy. Micro particles are added to the cutting fluid circuit by a developed high-pressure mixing vessel. After the evaluation of suitable particle size, particle concentration and coolant pressure, a computational fluid dynamics (CFD) simulation is validated with the experimental results. The comparison shows a very good model quality with a marginal difference for the flow velocity of 1.57% between simulation and experiment. The simulation considers the kinematic viscosity of the fluid. The results show that the fluid velocity in the chip flutes is low compared to the fluid velocity at the exit of the coolant channels of the tool and drops even further between the guide chamfers. The flow velocity and the flow pressure directly at the cutting edge decrease to such an extent that the fluid cannot generate a sufficient cooling or lubrication. With the CFD simulation a deeper understanding of the behavior and interactions of the cutting fluid is achieved. Based on these results further research activities to improve the coolant supply can be carried out with great potential to evaluate new tool geometries and optimize the machining process.The full text can be downloaded at https://link.springer.com/article/10.1007/s40436-021-00383-w     

Nanoscale FeS2 (Pyrite) as a Sustainable Thermoelectric Material

We have synthesized undoped, Co-doped (up to 5%), and Se-doped (up to 4%) FeS₂ materials by mechanical alloying in a planetary ball mill and investigated their thermoelectric properties from room temperature (RT) to 600 K. With decreasing particle size, the undoped FeS₂ samples showed higher electrical conductivity, from 0.02 S cm^?1 for particles with 70 nm grain size up to 3.1 S cm^?1 for the sample with grain size of 16 nm. The Seebeck coefficient of the undoped samples showed a decrease with further grinding, from 128 μV K^?1 at RT for the sample with 70-nm grains down to 101 μV K^?1 for the sample with grain size of 16 nm. The thermal conductivity of the 16-nm undoped sample lay within the range from 1.3 W m^?1 K^?1 at RT to a minimal value of 1.2 W m^?1 K^?1 at 600 K. All doped samples showed improved thermoelectric behavior at 600 K compared with the undoped sample with 16 nm particle size. Cobalt doping modified the p-type semiconducting behavior to n-type and increased the thermal conductivity (2.1 W m^?1 K^?1) but improved the electrical conductivity (41 S cm^?1) and Seebeck coefficient (-129 μV K^?1). Isovalent selenium doping led to a slightly higher thermal conductivity (1.7 W m^?1 K^?1) as well as to an improved electrical conductivity (26 S cm^?1) and Seebeck coefficient (110 μV K^?1). The ZT value of FeS₂ was increased by a factor of five by Co doping and by a factor of three by Se doping.     

Effect of Bismuth Nanotubes on the Thermoelectric Properties of BiSb Alloy Nanocomposites

Bismuth nanotubes have been synthesized and successfully included in Bi_1?x Sb _x nanoalloys to form composite structures. The nanotubes were synthesized by transformation of a β-BiI precursor with n-BuLi solution leading to tubular bismuth structures. The Bi_1?x Sb _x nanoalloys were produced by ball milling. Three series of composite structures were synthesized by including different fractions (0 wt.%, 3 wt.%, 5 wt.%) of nanotubes in nanoalloys of different composition x. Investigation of thermoelectric and structural properties revealed a decrease of the thermal conductivity of up to 40% for the composites in comparison with alloys without nanotube inclusions. This effect can be attributed to enhanced phonon scattering. Seebeck coefficients and electrical conductivities were both slightly enhanced in the composite series with 3 wt.% nanotube inclusions, leading to enhancement of $$ ZT \ \left(ZT=\frac {(S^2 \sigma)}{\kappa}\,{ {T}}\right) $$ throughout the series compared with the nanoalloy series without nanotube inclusions.     

Oxidative stability of extra virgin olive oil blended with sesame seed oil during storage: an optimization study based on combined design methodology

In this study, extra virgin olive oil (EVOO) was mixed with sesame seed oil (SSO) at different concentrations (100:0, 90:10, 80:20, 70:30 and 60:40 w/w) and stored for 90 days at room conditions. To see the effect of mixing level and storage period, a combined design having two mixtures (EVOO and SSO) and one process factor (storage period) was used. Main oxidation parameters (free fatty acid content, refractive index, peroxide value and p-anisidine value) and major fatty acid composition of the samples were characterized. It was observed that EVOO is quite sensitive to oxidation compared to SSO and increase of SSO in the blended oil samples decreased the oxidation of the product during storage. Major fatty acids were palmitic, oleic and linoleic acids. Addition of SSO caused a significantly change in the fatty acid composition. The results showed that EVOO could be stored for longer time by mixing of SSO having strong antioxidant activity.     

Controller design and performance evaluation for deadlock avoidance in automated flexible manufacturing cells

In this paper, the design of a deadlock avoidance controller is described. The uncontrolled system is modeled using colored Petri nets. The system controller is based on a restrictive (not maximally permissive) deadlock avoidance policy to resolve deadlocks and control the real-time resource allocation decisions in the system. Performance evaluation of systems controlled by not maximally permissive algorithms is essential in determining the applicability and effectiveness of the control algorithms. The performance of the controlled system is compared with performance of optimal control policies to quantify the effects of the restrictiveness of the deadlock avoidance policy on system performance.     

A novel microstream injection molding method for thermotropic liquid crystalline polymers to promote mechanical isotropy: A matrixing microbeam X-ray study

The effects of flow-altering inserts and mold cavity geometry on the mechanical properties of an injection molded liquid crystalline polymer were studied to produce parts with properties approaching macroscopically isotropic state. By inserting fine metal mesh barriers to the gates of the mold cavities, a large number of highly oriented microstreams are produced. After their creation these highly oriented streams of differing flow vectors intertwine and this texture remains reasonably intact even after substantial shearing and extension history imparted on them during ensuing flow into the cavity. This method is effective in the interior away from the skin regions formed under the shearing flow during injection. The local molecular orientation was determined using a matrixing microbeam WAXS technique that allows precision movement of the sample in the microbeam X-ray. Samples produced with the 1.0 mm² mesh showed large variations in the local symmetry axis with respect to the machine as measured by microbeam X-ray diffraction incrementally from the edge to the core of the parts. In comparison, samples with no mesh insert showed only gradual changes in the tilt angle (angle between local symmetry axis and flow direction). The modulus and tensile strengths of all samples with the 1.0 mm² mesh inserts were found to approach virtual global mechanical isotropy.     

Real time mechano-optical study on deformation behavior of PTMO/CHDI-based polyetherurethanes under uniaxial extension

Real time mechano-optical properties of two homologous segmented, thermoplastic polyurethanes (TPUs) obtained from the stoichiometric reactions of trans-1,4-cyclohexyl diisocyanate (CHDI) and poly(tetramethylene oxide)glycol (PTMO) were investigated. PTMO oligomers used had number average molecular weights M_n of 1020 and 2040 g/mol, resulting in TPUs with urethane hard segment contents of 14 and 7.5% by weight. AFM studies showed intertwined microphase morphology. Stress–strain measurements demonstrated the formation of very strong, elastomeric materials, with ultimate tensile strengths of 23–25 MPa and elongation at break values of about 1000%. Mechano-optical behavior of these polymers exhibited multiple regime behavior. The first strain optical regime is linear where primarily the soft segments orient. The transition between the first and second strain optical regimes was found to correspond to the saturation of straining of the soft segments that lead to start of rotation of hard segments in the stretching direction. The start of Regime II coincides with the onset of strain hardening and the distance between the hard segments increases appreciably with stretching in this regime. Increasing the soft segment length was found to promote its strain-induced crystallization.     

Antioxidant activity and polyphenol content of Turkish thyme (Thymus vulgaris) monitored by liquid chromatography and tandem mass spectrometry

Like tea, the leaves of Turkish thyme (Thymus vulgaris) can be boiled in water to produce an extract. This is widely used as syrup for the treatment of coughs and bronchitis at alternative medicine clinics in many parts of the world. In the current study, we assessed the phenolic content and antioxidant activity of thyme. The antioxidant activities of both ethanol and aqueous extracts of thyme were determined using various in vitro methods. The total phenolic and total flavonoid contents were determined to be a gallic acid equivalent and a quercetin equivalent, respectively. Finally, the quantities of the phenolic compounds were detected using high-performance liquid chromatography and tandem mass spectrometry. The total phenolic compounds in the aqueous extract and ethanol extracts of Turkish thyme were 256.0 μg gallic acid equivalent/mg dried extract and 158.0 μg gallic acid equivalent/mg dried extract, respectively. Conversely, the total flavonoid compounds in both extracts were 44.2 μg and 36.6 μg quercetin equivalent/mg dried extract, respectively. For the first time, we determined phenolic contents and investigated the antioxidant potential of thyme. The results indicate that Turkish thyme is a good dietary source with phenolic properties.     

Utilization of Whey and Grape Must for Citric Acid Production by Two Yarrowia lipolytica Strains

In this study, utilization of whey and grape must were investigated for citric acid production using Yarrowia lipolytica NBRC 1658 and a domestic strain Y. lipolytica 57. In addition to its use as a sole nutrient source, whey was also fortified with glucose or fructose as well as other nutrients. The best results for citric acid production were obtained in the medium containing whey supplemented with fructose. Maximum citric acid concentrations in this medium were 49.23 and 32.65 g/L for the domestic and NBRC 1658 strains, respectively. In grape must, maximum citric acid concentrations obtained using domestic and NBRC 1658 strains were 32.09 and 10.39 g/L, respectively. Both of the natural nutrient sources were found to be promising for utilization in citric acid production process. A domestic Turkish yeast strain was confirmed to be superior for citric acid production for the first time. This can be targeted for enhancing citric acid production efficiencies from locally available substrates such as whey or grape must.     

Photovoltaic textile structure using polyaniline/carbon nanotube composite materials

In this paper, an investigation of flexible electrodes for photovoltaic textile structures utilizing polymer‐based organic materials is presented. The composite structure consisting of a blend of water dispersible carbon nanotube:polyaniline (CNT:PANI) components with poly(3,4 ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) was applied to be used as the hole collecting electrode in photovoltaic textile applications. Both photovoltaic textiles and conventional solar cells were fabricated by using a blend of poly(3‐hexylthiophene‐2,5‐diyl) (P3HT):(6,6)‐phenyl C61‐butyric acid methyl ester (PCBM). All devices were characterized by measuring current versus voltage characteristics under AM 1.5 conditions. The nanoscale morphology of the photovoltaic structures was investigated using scanning electron microscopy and atomic force microscopy.