The Effect of Polymer Optoelectronic Properties on the Performance of Multilayer Hybrid Polymer/TiO2 Solar Cells

We report a study of the effects of polymer optoelectronic properties on the performance of photovoltaic devices consisting of nanocrystalline TiO₂ and a conjugated polymer. Three different poly(2‐methoxy‐5‐(2′‐ethylhexoxy)‐1,4‐phenylenevinylene) (MEH‐PPV)‐based polymers and a fluorene–bithiophene copolymer are compared. We use photoluminescence quenching, time‐of‐flight mobility measurements, and optical spectroscopy to characterize the exciton‐transport, charge‐transport, and light‐harvesting properties, respectively, of the polymers, and correlate these material properties with photovoltaic‐device performance. We find that photocurrent is primarily limited by the photogeneration rate and by the quality of the interfaces, rather than by hole transport in the polymer. We have also studied the photovoltaic performance of these TiO₂/polymer devices as a function of the fabrication route and device design. Including a dip‐coating step before spin‐coating the polymer leads to excellent polymer penetration into highly structured TiO₂ networks, as was confirmed through transient optical measurements of the photoinduced charge‐transfer yield and recombination kinetics. Device performance is further improved for all material combinations studied, by introducing a layer of poly(ethylene dioxythiophene) (PEDOT) doped with poly(styrene sulfonic acid) (PSS) under the top contact. Optimized devices incorporating the additional dip‐coated and PEDOT:PSS layers produced a short‐circuit current density of about 1 mA cm^–2, a fill factor of 0.50, and an open‐circuit voltage of 0.86 V under simulated AM 1.5 illumination (100 mW cm^–2, 1 sun). The corresponding power conversion efficiency under 1 sun was ≥ 0.4 %.     

Assessment of the value of rivers for Otters (Lutra lutra)

The British otter Lutra lutra L. requires good water quality, an adequate supply of fish and certain types of vegetation or cavities (holts) adjacent to water bodies for resting and breeding sites. In the U.K. otters and their holts are legally protected. Trained surveyors are needed to confirm the presence of otters on a river as the animals are rarely seen, but their tracks and droppings (spraints) may be detected. To evaluate a river for otters, information is required on water quality, fish species and biomass, as well as available habitat. Pioneer evaluation work based on the River Corridor Survey techniques has been done on Welsh rivers with good otter populations. Riparian vegetation, especially trees, is shown to be particularly important. This work is now being extended to areas on the margins of otter distribution such as the lower river Wye in England and Wales. Such surveys provide important management information for water authorities and give opportunities for enhancement work to benefit this animal.     

The role of autonomy in adolescent psychotherapy.

Adolescents' desire and need for autonomy may have a significant impact on the therapeutic relationship. The implications of this idea are examined, both theoretically and empirically. First, adolescent autonomy is conceptualized in relational terms, and some of the conditions for the growth of autonomy are outlined. Then, this conceptualization is applied to a study of the therapeutic relationship in adolescent psychotherapy where it is shown how some of therapists' and adolescents' interactions and reactions can be understood by recognizing the influence of adolescent autonomy. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Review of Language in the Americas.

Reviews the book, Language in the Americas by Joseph H. Greenberg (1987). Greenberg's work on universals of language has crossed disciplinary boundaries to become known to many psychologists interested in language. His equally important work in language classification, of which Language in the Americas is one part, remains unfamiliar to psychologists. This book is a pioneering work in that it is the first genetic classification of the indigenous languages of both North and South America. Greenberg maintains that all of the languages of the Americas belong to three families: Eskimo-Aleut, Na-Dene, and a family that he has named Amerind. This assertion is both important and controversial; the controversy lies in the grouping of most of the languages including all of those of South and Central America into the Amerind family. Most of Language in the Americas consists of the Amerind etymological dictionary, arranged so that the reader can assess lexical similarities within and between subgroups. Greenberg's discussion is informed, articulate, profound, and to the point. He draws on relevant sources and examples from diverse fields of knowledge. The depth and breadth of his scholarship and the clarity of his presentation create a work that is an intellectual pleasure to read. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Self-efficacy expectations predict survival for patients with chronic obstructive pulmonary disease.

Evaluated the validity of self-efficacy expectations as predictors of mortality for 119 patients with chronic obstructive pulmonary disease. Ss completed 4 physiological measures that represent common clinical indicators of disease severity: forced expiratory volume in 1 s(FEV1.0), arterial blood gas measurement of resting partial pressure of oxygen (PaO?), single-breath diffusing capacity (DLCO), and maximum oxygen uptake (V02max) during exercise. In addition, self-reported self-efficacy expectation for walking on a treadmill was measured. Self-efficacy was a significant univariate predictor of 5-yr survival. However, when controlling for FEV1.0 in multivariate survival analysis, self-efficacy had only a marginal effect. Simple self-report scales may provide significant information about health status. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Age effects on block design: Qualitative performance features and extended-time effects.

Qualitative performance features and extended-time effects on the Block Design subtest of the Wechsler Adult Intelligence Scale—Revised (WAIS—R) were examined in 145 healthy Ss (aged 50–95 yrs). Raw scores were calculated at standard and extended time limits; error types and starting points were recorded for a subgroup of Ss. In Ss age 60 yrs and older, there was a consistent decline with age in overall scores at both time limits. Extra time allotments resulted in modest but significant increases in scores. Older and younger Ss benefited equally from the extra time, indicating that the age-related decline on this task cannot be accounted for by general age-related psychomotor slowing. Single- and multiblock rotation errors were relatively common, whereas stimulus boundedness and broken configurations were rare. Despite some potential limitations in generalizability, the results suggest that the incorporation of qualitative scoring procedures in the assessment of visuoconstructional skills may enhance understanding of normal and abnormal brain–behavior relationships. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Evidence-Based Solutions for Overcoming Access Barriers, Decreasing Attrition, and Promoting Change With Underserved Families.

Various definitions exist for what constitutes family therapy. In this article, we consider family therapy to encompass any intervention that targets family interactions and conceptualizes problems as existing beyond individual clients. Numerous individual studies and several quantitative reviews have established family therapy as an effective treatment modality and the treatment of choice for many disorders. However, critiques of existing service provision highlight the unfortunate fact that numerous barriers to treatment exist at multiple levels of the broader ecology, preventing many families from benefiting from these services. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Predicting Youth Access to Tobacco: The Role of Youth Versus Store-Clerk Behavior and Issues of Ecological Validity.

Twenty-one 15- to 17-year-olds attempted to purchase cigarettes in 232 stores in the manner that confederates typically do in access studies, as well as in the manipulative ways (e.g., lying about their ages) that youth smokers do, thereby modeling youth access to tobacco within versus outside of studies, respectively. Youth typical-research versus manipulative behavior was contrasted with clerk behavior (requests for youth ID cards) to examine the relative contributions of both to youth access to tobacco for the 1st time. Results revealed that clerk behavior was the strongest predictor of cigarette sales to youth and hence underscore the need for interventions with merchants. Sales nonetheless were higher under youth-manipulative conditions and thereby highlight the low ecological validity of access research. (PsycINFO Database Record (c) 2010 APA, all rights reserved)