Mixed-Metal MOF-74 Templated Catalysts for Efficient Carbon Dioxide Capture and Methanation

The vast chemical and structural tunability of metal–organic frameworks (MOFs) are beginning to be harnessed as functional supports for catalytic nanoparticles spanning a range of applications. However, a lack of straightforward methods for producing nanoparticle-encapsulated MOFs as efficient heterogeneous catalysts limits their usage. Herein, a mixed-metal MOF, NiMg-MOF-74, is utilized as a template to disperse small Ni nanoclusters throughout the parent MOF. By exploiting the difference in Ni O and Mg O coordination bond strength, Ni²⁺ is selectively reduced to form highly dispersed Ni nanoclusters constrained by the parent MOF pore diameter, while Mg²⁺ remains coordinated in the framework. By varying the ratio of Ni to Mg in the parent MOF, accessible surface area and crystallinity can be tuned upon thermal treatment, influencing CO₂ adsorption capacity and hydrogenation selectivity. The resulting Ni nanoclusters prove to be an active catalyst for CO₂ methanation and are examined using extended X-ray absorption fine structure and X-ray photoelectron spectroscopy. By preserving a segment of the Mg²⁺-containing MOF framework, the composite system retains a portion of its CO₂ adsorption capacity while continuing to deliver catalytic activity. The approach is thus critical for designing materials that can bridge the gap between carbon capture and CO₂ utilization.     

On the integration of SIC and MIMO DoF for interference cancellation in wireless networks

Recent advances in MIMO degree-of-freedom (DoF) models allowed MIMO research to penetrate the networking community. Independent from MIMO, successive interference cancellation (SIC) is a powerful physical layer technique used in multi-user detection. Based on the understanding of the strengths and weaknesses of MIMO DoF and SIC, we propose to have DoF-based interference cancellation (IC) and SIC help each other so that (i) precious DoF resources can be conserved through the use of SIC and (ii) the stringent SINR threshold criteria can be met through the use of DoF-based IC. In this paper, we develop the necessary mathematical models to realize the two ideas in a multi-hop wireless network. Together with scheduling and routing constraints, we develop a cross-layer optimization framework with joint DoF IC and SIC. By applying the framework on a throughput maximization problem, we find that SIC and DoF IC can indeed work in harmony and achieve the two ideas that we propose.     

Intraphase Microstructure–Understanding the Impact on Organic Solar Cell Performance

A comprehensive study of the effect of intraphase microstructure on organic photovoltaic (OPV) device performance is undertaken. Utilizing a bilayer device architecture, a small molecule donor (TIPS‐DBC) is deposited by both spin‐coating and by thermal evaporation in vacuum. The devices are then completed by thermal evaporation of C₆₀, an exciton blocking layer and the cathode. This bilayer approach enables a direct comparison of device performance for donor layers in which the same material exhibits subtle differences in microstructure. The electrical performance is shown to differ considerably for the two devices. The bulk and interfacial properties of the donor layers are compared by examination with photoelectron spectroscopy in air (PESA), optical absorption spectroscopy, charge extraction of photo‐generated charge carriers by linearly increasing voltage (photo‐CELIV), time‐resolved photoluminescence measurements, X‐ray reflectometry (XR), and analysis of dark current behavior. The observed differences in device performance are shown to be influenced by changes to energy levels and charge transport properties resulting from differences in the microstructure of the donor layers. Importantly, this work demonstrates that in addition to the donor/acceptor microstructure, the intraphase microstructure can influence critical parameters and can therefore have a significant impact on OPV performance.     

The Effect of Ageing on Exciton Dynamics,Charge Separation,and Recombination in P3HT/PCBM Photovoltaic Blends

A study of how light‐induced degradation influences the fundamental photophysical processes in the active layer of poly(3‐hexylthiophene)/[6,6]‐phenyl C₆₁‐butyric acid methyl ester (P3HT/PCBM) solar cells is presented. Non‐encapsulated samples are systematically aged by exposure to AM 1.5 illumination in the presence of dry air for different periods of time. The extent of degradation is quantified by the relative loss in the absorption maximum of the P3HT, which is varied in the range 0% to 20%. For degraded samples an increasing loss in the number of excitons within the P3HT domains is observed with longer ageing periods. This loss occurs rapidly, within the first 15 ps after photoexcitation. A more pronounced decrease in the population of polarons than excitons is observed, which also occurs on a timescale of a few picoseconds. These observations, complemented by a quantitative analysis of the polaron and exciton population dynamics, unravel two primary loss mechanisms for the performances of aged P3HT/PCBM solar cells. One is an initial ultrafast decrease in the polaron generation, apparently not related to the exciton diffusion to the polymer/fullerene interface; the second, less significant, is a loss in the exciton population within the photoexcited P3HT domains. The steady‐state photoinduced absorption spectra of degraded samples exhibits the appearance of a signal ascribed to triplet excitons, which is absent for non‐degraded samples. This latter observation is interpreted considering the formation of degraded sites where intersystem crossing and triplet exciton formation is more effective. The photovoltaic characteristics of same blends are also studied and discussed by comparing the decrease in the overall power conversion efficiency of solar cells.     

Analysis of in situ monitored thermal cycling benefits for wireless packaging early reliability evaluation

With the increasing complexity of the power amplifier (PA) module architecture, the probability of a thermally induced stress related failure mechanism increases. To help evaluate the increase in module complexity, a more sophisticated in situ monitored thermal cycle reliability test is available. The module is monitored in real time using a resistance daisy chain methodology designed to provide coverage using resistance feedback throughout the entire hierarchy of the module and carrier board interface. Monitored temperature cycling allows for real time failure feedback and enhanced failure signature information. Further, the testing technique has proven to be a valuable method for capturing the early stages of a module mechanical failure at the temperature extremes. Moreover, statistical evaluation of the failure data (Weibull analysis) is improved and better accuracy of the failures in time (FIT) rate can be determined.     

Downlink user selection and resource allocation for semi-elastic flows in an OFDM cell

We are concerned with user selection and resource allocation in wireless networks for semi-elastic applications such as video conferencing. While many packet scheduling algorithms have been proposed for elastic applications, and many user selection algorithms have been proposed for inelastic applications, little is known about optimal user selection and resource allocation for semi-elastic applications in wireless networks. We consider user selection and allocation of downlink transmission power and subcarriers in an orthogonal frequency division multiplexing cellular system. We pose a utility maximization problem, but find that direct solution is computationally intractable. We first propose a method that makes joint decisions about user selection and resource allocation by transforming the utility function into a concave function so that convex optimization techniques can be used, resulting in a complexity polynomial in the number of users with a bounded duality gap. This method can be implemented if the network communicates a shadow price for power to power allocation modules, which in turn communicate shadow prices for rate to individual users. We then propose a method that makes separate decisions about user selection and resource allocation, resulting in a complexity linear in the number of users.     

Amplification of tunable, picosecond pulses from a single-mode, short cavity dye laser

The design and performance of an Nd⁺³:YAG pumped, short cavity dye laser-dye amplifier system is reported. This system produces narrow bandwidth, broadly tunable picosecond pulses with energies in the millijoule range.     

An improved scan laser with a VO2programmable mirror

A 10.6 μm scan laser has been constructed and operated with an off-axis cathode ray tube, high reflectance multilayer thin-film structures, and a tapered plasma discharge tube. Equations are given for the switching time of a high-reflectance spot on the VO2and for the relation of scan laser output power to cavity geometry, cavity losses, and the gain of the active CO2medium. A scan capability of2.1 times 10^{3}easily resolvable directions was demonstrated, and sequential and randomly addressed spot rates of 10⁵/s were achieved. The equations relating output power and cavity mode size were experimentally verified using a nonscanned beam.     

Frequency-Dependent Attenuation Effects in Pulsed Doppler Ultrasound: Experimental Results

The quantitative capability of pulsed Doppler ultrasound in clinical practice is limited by the effects of frequency-dependent attenuation of ultrasound in tissue, as well as several other spectral-broadening mechanisms which distort the Doppler spectrum of an ultrasonic echo. In this communication, we present results of in vitro experiments which demonstrate the magnitude of the errors expected in clinical measurements of blood flow parameters when frequency-dependent attenuation Of ultrasound in biological tissue is ignored. It is shown that errors as large as 15 percent may occur in Doppler measurements of blood flow velocity through 7 cm of intervening tissue. A comparison is also made between experimental results and a theoretical model which includes the effects of scattering and attenuation.     

Scale up of 2,4-dichlorophenol removal from aqueous solutions using Brassica napus hairy roots

Chlorophenols are harmful pollutants, frequently found in the effluents of several industries. For this reason, many environmental friendly technologies are being explored for their removal from industrial wastewaters. The aim of the present work was to study the scale up of 2,4-dichlorophenol (2,4-DCP) removal from synthetic wastewater, using Brassica napus hairy roots and H₂O₂ in a discontinuous stirred tank reactor. We have analyzed some operational conditions, because the scale up of such process was poorly studied. High removal efficiencies were obtained (98%) in a short time (30 min). When roots were re-used for six consecutive cycles, 2,4-DCP removal efficiency decreased from 98 to 86%, in the last cycle. After the removal process, the solutions obtained from the reactor were assessed for their toxicity using an acute test with Lactuca sativa L. seeds. Results suggested that the treated solution was less toxic than the parent solution, because neither inhibition of lettuce germination nor effects in root and hypocotyl lengths were observed. Therefore, we provide evidence that Brassica napus hairy roots could be effectively used to detoxify solutions containing 2,4-DCP and they have considerable potential for a large scale removal of this pollutant. Thus, this study could help to design a method for continuous and safe treatment of effluents containing chlorophenols.