Application of mid-infrared spectroscopy: measuring hydrogen peroxide concentrations in bleaching baths

The presented work applies mid-infrared attenuated total reflection (ATR) spectroscopy to the measurment of hydrogen peroxide in aqueous matrices. The performance of different ATR crystals mounted in flow cells was investigated in the presence of aqueous hydrogen peroxide solutions. Quantitative determination has been achieved by evaluation of specific OH stretching and deformation vibrations with linear correlation between peak areas or peak heights and hydrogen peroxide concentration in the range of 1-10% (weight in water). Important aspects such as chemical stability of the waveguide material and influences of pH and ionic strength on the performance are discussed. Feasibility for the investigation of real world samples is demonstrated by measuring industrial bleaching solutions with known concentrations of hydrogen peroxide fitting well with calibration graphs established with neat hydrogen peroxide solutions. The presented sensor system is capable of determining hydrogen peroxide within complex matrices and clearly corroborates the potential of providing an in situ measurement concept for on-line hydrogen peroxide detection.     

Monitoring post-tsunami vegetation recovery in Phang-Nga province,Thailand, based on IKONOS imagery and field investigations – a contribution to the analysis of tsunami vulnerability of coastal ecosystems

A major tsunami in December 2004 devastated the coastal ecosystems along the Andaman Sea coast of Thailand. Since intact coastal ecosystems provide many important services for local communities at the Andaman Sea, it is crucial to investigate to what extent (in terms of percentage area and speed) the affected ecosystems were capable of recovering after the tsunami. Field measurements and multi-date IKONOS imagery were used to estimate the recovery and succession patterns of coastal vegetation types in the Phang-Nga province of Thailand, three years after the tsunami. Thus, this study contributes to a holistic understanding of the ecological vulnerability of the coastal area to tsunamis. A zone-based change detection approach is applied by comparing two change detection techniques: the first method involves the calculation of a recovery rate based on multi-temporal TNDVI (transformed normalized difference vegetation index) images (TNDVI approach), whereas the second approach is a combined approach of the change vector analysis (CVA). Although these two methods provide different types of information (quantitative for the TNDVI approach, qualitative for the CVA), they are comparable in terms of results and accuracies. The results reveal that recovery processes vary based on the type of the ecosystem and, furthermore, are strongly influenced by human activities. Grasslands, coconut plantations and the mixed vegetation cover could recover faster than the mangroves and casuarina forests. Among the forest ecosystems, recovery rates of casuarina forests were higher than for mangroves, but the recovery area was smaller. This study also discusses the potential and some limitations and inaccuracies of applying high-resolution optical imagery for assessing vegetation recovery at a local scale.     

Principles of Branching Morphology and Anatomy in Arborescent Monocotyledons and Columnar Cacti as Concept Generators for Branched Fiber‐Reinforced Composites

The branching of arborescent (tree‐like) monocotyledonous plants of the genus Dracaena or of columnar cacti differ considerably from that observed in other dicotyledonous or gymnosperm trees. The investigated ramifications exhibit distinctive morphological and anatomical features. In arborescent monocotyledons the side branches are attached to the main stem by a fiber‐reinforced tissue newly formed during secondary growth, clasping the main stem and finally resulting in a “flange‐mounted” structure. In the case of columnar cacti the most obvious feature is the pronounced constriction at the attachment point of the branches that is also mirrored in the lignified vascular tissue. One might argue that these characteristic morphological and anatomical features in regions exposed to high mechanical stresses represent structural weaknesses. However, the outer shape and the inner structures of the ramifications cause considerable stability and structural integrity of the stem‐branch connection under static and dynamic loading. Our results allow concluding that load‐adaptation in ramified plant structures is a result of a combination of optimization in outer shape and fiber arrangement within the ramifications. Numerical methods simulating the mechanical behavior based on data obtained from the studied plants support this assumption. A deeper understanding of the outer shape of the connection between shoot and branch as well as of the arrangement of the lignified vascular tissues in the branching region, may contribute toward alternative concepts for branched technical light‐weight‐structures. In particular for braided fiber‐reinforced composites this biomimetic approach might help to keep the demand on the available design space as small as possible.     

徘徊的残像——Ben van Berkel访谈录

BenvanBerkel曾就读于阿姆斯特丹Rietveld学院和伦敦建筑协会建筑学院（AA）。1988年．他和艺术历史学家CarolineBos共同创立了UNStudio。1996年。他参与鹿特丹知名的伊拉斯谟大桥的外形设计。这深刻地影响了他对当代建筑的理解．从而形成自己独具一格的风格。亦成为UNStudio营运理念的基础。BenvanBerkeI在许多知名的大学担任过客座讲师。与他人合作撰写了大量论文和专著。BenvanBerkel目前是德国法兰克福StaedeIschule概念设计系的教授和建筑学院院长。而他在中国的第一个项目，已开始在杭州建设。     

The statistics of the thermal motion of the atoms during imaging process in transmission electron microscopy and related techniques

The concern of this work is the influence of the thermal motion of the atoms on electron scattering simulations, used for quantitative interpretation of results in high-resolution electron microscopy. We distinguish between the influence of inelastic phonon excitation and the effect of a moving lattice on images generated by elastically scattered electrons. It is shown that, analog to aberrations, the impact of a moving lattice differs substantially with respect to different imaging conditions and cannot be described by the Debye–Waller damping applicable in XRD. We derive a new formalism, based on the frozen lattice and multislice approach, to incorporate the statistics of the thermal motion into elastic TEM imaging simulations, taking into account different imaging conditions. The averaging over different atom positions is generally performed within a density matrix framework, which can be linearized in the special case of off-axis electron holography. All findings are supported by explicit numerical simulations: molecular dynamics simulations are performed to get a realistic thermal motion and the electron scattering simulations are performed within the new multislice algorithm.     

The sources of normativity: Young children's awareness of the normative structure of games.

In two studies, the authors investigated 2- and 3-year-old children's awareness of the normative structure of conventional games. In the target conditions, an experimenter showed a child how to play a simple rule game. After the child and the experimenter had played for a while, a puppet came (controlled by a 2nd experimenter), asked to join in, and then performed an action that constituted a mistake in the game. In control conditions, the puppet performed the exact same action as in the experimental conditions, but the context was different such that this act did not constitute a mistake. Children's normative responses to the puppet's acts (e.g., protest, critique, or teaching) were scored. Both age groups performed more normative responses in the target than in the control conditions, but the 3-year-olds did so on a more explicit level. These studies demonstrate in a particularly strong way that even very young children have some grasp of the normative structure of conventional activities. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Chemical and Structural Properties of Nickel Hydroxide Xerogels Obtained by the Sol-Gel Procedure in the Presence of Acetic Acid

The sol-gel route to glasses and ceramics has attracted an increasing amount of scientific and technological interest recently. In this process, sols with different concentrations are used as precursors for xerogels and to produce materials that consist of fine oxide particles. In the present work, nickel hydroxide gels have been obtained via the hydrolysis of a molecular precursor in the presence of acetic acid. The chemical aspects of the material transformation have been studied by using Fourier transform infrared (FTIR) spectroscopy and differential scanning calorimetry (DSC) for different acetic acid contents and several heat-treatment temperatures. The carboxylic acid acts as a ligand at a molecular level in the precursor, therefore modifying the entire hydrolysis and condensation process. Small-angle X-ray scattering (SAXS) studies and density measurements have been performed for the structural characterization of the xerogels. A denser, final oxide material is obtained when a higher acetic acid concentration is used. The porosity of the dry gels coarsens when they are heat-treated up to a temperature of ∼400°C and its density decreases. The material that has been heat-treated up to a temperature of 800°C densifies and exhibits a finer porosity. The chemical properties at a molecular level satisfactorily explain and are well correlated with the structural characteristics of the studied material.     

Standsicherheitsuntersuchungen sowie Aufschluss- und Abbauplanung der Erweiterung des Steinbruchs Fischbach in Oberbayern der Rohrdorfer Gruppe

This article deals with the extension of the quarry “Fischbach” in Upper Bavaria. In the quarry primarily limestone is mined, which is further transported to Rohrdorf for cement production. For the planned expansion firstly a geotechnical mapping of all benches is made. All benches are divided into segments, then gap data are taken. In addition, rock samples are taken from the mining area and uniaxial compressive tests are carried out. This data is basis of a differentiated geomechanical classification of the benches and slopes. The subsequent rock classification defines the rock strength of individual bench-areas. Furthermore, the slopes are tested on stability in actual condition and after enlargement. This happens on the one hand through a regional breakdown, on the other hand through a local viewing on benches. These stability considerations yield factors of safety and let assume a safe slope height.     

Material requirements for the adoption of unconventional silicon crystal and wafer growth techniques for high‐efficiency solar cells

Silicon wafers comprise approximately 40% of crystalline silicon module cost and represent an area of great technological innovation potential. Paradoxically, unconventional wafer‐growth techniques have thus far failed to displace multicrystalline and Czochralski silicon, despite four decades of innovation. One of the shortcomings of most unconventional materials has been a persistent carrier lifetime deficit in comparison to established wafer technologies, which limits the device efficiency potential. In this perspective article, we review a defect‐management framework that has proven successful in enabling millisecond lifetimes in kerfless and cast materials. Control of dislocations and slowly diffusing metal point defects during growth, coupled to effective control of fast‐diffusing species during cell processing, is critical to enable high cell efficiencies. To accelerate the pace of novel wafer development, we discuss approaches to rapidly evaluate the device efficiency potential of unconventional wafers from injection‐dependent lifetime measurements. Copyright © 2015 John Wiley & Sons, Ltd.