Summary The Stefan-Winkelmann diffusion technique has been used to determine vapor pressures of high boiling point compound-solvents mixtures. Data are reported at a temperature of 67°C for the mixtures polyphenyl ether (6 rings) — benzene and carbowax 1500 — benzene and at a temperature of 100°C for the mixtures polyphenyl ether (6 rings) — toluene and tricresylphosphate-toluene. The range of concentration is only limited by the appearance of a solid phase, and results are in good agreement with those determined by vapor pressure osmometry.Nomenclature A
Vapour source
- B
Flowing gas phase
- c
Concentration, g-mol/cm3
- DAB
Molecular diffusion coefficient, cm2/s
- hi
Total interface depth, cm
- K
Parameter defined by equation (6), dimensionless
- I
Polymer or high boiling point compound
- MA
Molecular weight
- NAZ
Molar flux, g-mol/(cm2) (s)
- PA
Partial pressure at the interface, atm
- P
Total pressure, atm
- R
Gas constant, (atm) (cm3) / (°K) (g-mol)
- T
Temperature, °K
- t
Time, s
- YA
Molar fraction at the interface, dimensionless
- zo
Initial interface depth, cm
- zi
Drop of the interface depth, cm
- z
Interface position
Greek Letters A
Density of the liquid phase, g/cm3相似文献
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