Evidences of the Cerium Oxide-Catalysed DPF Regeneration in a Real Diesel Engine Exhaust

The active phase Ce_0.5Pr_0.5O₂ has been loaded on commercial substrates (SiC DPF and cordierite honeycomb monolith) to perform DPF regeneration experiments in the exhaust of a diesel engine. Also, a powder sample has been prepared to carry out soot combustion experiments at laboratory. Experiments performed in the real diesel exhaust demonstrated the catalytic activity of the Ce–Pr mixed oxide for the combustion of soot, lowering the DPF regeneration temperature with regard to a counterpart catalyst-free DPF. The temperature for active regeneration of the Ce_0.5Pr_0.5O₂-containing DPF when the soot content is low is in the range of 500–550 °C. When the Ce_0.5Pr_0.5O₂-containing DPF is saturated with a high amount of soot, pressure drop and soot load at the filter reach equilibrium at around 360 °C under steady state engine operation due to passive regeneration. The uncoated DPF reached this equilibrium at around 440 °C. Comparing results at real exhaust with those at laboratory allow concluding that the Ce_0.5Pr_0.5O₂-catalysed soot combustion in the real exhaust is not based on the NO₂-assisted mechanism but is most likely occurring by the active oxygen-based mechanism.     

Novel poly(vinyl alcohol)-g-poly(hydroxy acid) copolymers: Synthesis and characterization

Poly(vinyl alcohol) (PVA) was reacted with three hydroxy acids (HA), namely D,L-lactic acid (LA), glycolic acid (GA) and D,L-3-hydroxybutyric acid (HB). The graft copolymers obtained were thoroughly characterized by ¹H and ¹³C NMR, FTIR, and DSC. Copolymer compositions were in the range 14–45 mol% HA with average lateral chain lengths in the range 1.1–1.3. The CO stretching band, arising from the lateral polyester chains, presents significant differences from that of pure polyesters. In case of the VALA and VAGA copolymers, carbonyl groups are almost completely interassociated with hydroxyl groups and as a result the carbonyl band presents a single contribution; however, splitting appears in VAHB. The band at about 1735 cm^?1 already observed for Poly(3-hydroxybutyrate) P3HB was reexamined in the light of molecular models for VAHB and the splitting observed was attributed to C–H???OC and to O–H???OC hydrogen bonding. The thermal analysis of copolymers demonstrates that esterification suppresses crystallinity and increases free volume, both accounting for a Tg reduction with regard to PVA. The stronger intermolecular hydrogen bonding interactions found in PVA with the chemically modified PVAs opens an interesting way towards miscibility with polyesters and other polymer systems containing carbonyl groups.     

澳大利亚水资源管理及水权制度建设的经验与启示

根据赴澳大利亚水资源的现状、管理体制的考察和学习,总结澳洲水资源管理和水权制度建设的经验,针对目前江西水权制度建设工作提出建议。     

欧洲电力需求侧管理对中国的启示(上)——来自中国赴欧洲电力需求侧管理的培训报告

学习借鉴欧洲国家开展电力需求侧管理的经验,对促进我国电力需求侧管理深入发展、建设资源节约型社会具有重要现实意义。全面介绍了欧盟成员国在开展需求侧管理、能效管理、能源服务等方面的行政法规、标准标识、财税政策以及市场激励、市场交易、市场竞争机制,在建筑节能和发展可再生能源方面形成的相关的制度体系。分析了我国电力需求侧管理工作的不足,并从出发点、政府作用、实施重点和实施手段上进行了国际比较,对进一步推动电力需求侧管理工作提出了加强法律法规建设、加快建立激励机制、加强标准和评估体系建设、大力开发应用新技术等政策性建议。深入挖掘电力需求侧管理资源,应成为我国建设节约型社会的重要战略举措。     

The Origin of the High Voltage in DPM12/P3HT Organic Solar Cells

Organic solar cells made using a blend of DPM12 and P3HT are studied. The results show that higher V_oc can be obtained when using DPM12 in comparison to the usual mono‐substituted PCBM electron acceptor. Moreover, better device performances are also registered when the cells are irradiated with sun‐simulated light of 10–50 mW cm^?2 intensity. Electrochemical and time‐resolved spectroscopic measurements are compared for both devices and a 100‐mV shift in the density of states (DOS) is observed for DPM12/P3HT devices with respect to PCBM/P3HT solar cells and slow polaron‐recombination dynamics are found for the DPM12/P3HT devices. These observations can be directly correlated with the observed increase in V_oc, which is in contrast with previous results that correlated the higher V_oc with different ideality factors obtained using dark‐diode measurements. The origin for the shift in the DOS can be correlated to the crystallinity of the blend that is influenced by the properties of the included fullerene.     

基于多传感器数据融合的电磁测量系统

本文主要从多传感器数据融合和虚拟仪器两方面介绍了一种电磁场测量系统的设计方法。     

Identification of Human Adenovirus in Respiratory Samples with Luminex Respiratory Virus Panel Fast V2 Assay and Real-Time Polymerase Chain Reaction

In order to compare the last version of the Respiratory Virus Panel (RVP) Fast assay for human Adenovirus (hAdv) detection with a specific real-time polymerase chain reaction (qPCR), which is considered the gold standard for hAdv detection, nasopharyngeal samples collected from 309 children (age range, four months to eight years) with respiratory tract infection were tested using the RVP Fast v2 assay (Luminex Molecular Diagnostics, Inc., Toronto, ON, Canada) and a specific TaqMan qPCR to identify hAdv DNA. The RVP Fast v2 assay detected 30/61 (49.2%) hAdv infections that had been identified by real-time qPCR, demonstrating a significantly lower detection rate (p < 0.001). The sensitivity of the RVP Fast v2 assay in comparison to qPCR was lower in younger children (42.9% vs. 57.7%; Cohen’s kappa coefficient, 0.53); in samples with co-infections (40.0% vs. 56.7%; Cohen’s kappa coefficient, 0.52); and in samples with hAdv type C (45.9% vs. 57.1%; Cohen’s kappa coefficient, 0.60). Samples with lower viral loads were associated with a significantly lower sensitivity of the RVP Fast v2 assay (35.1% vs. 68.2%, p = 0.01; Cohen’s kappa coefficients, 0.49). The RVP Fast v2 assay has important limitations for the detection of hAdv and cannot be used to evaluate whether hAdvs are the main etiologic agent responsible for an outbreak or when epidemiological studies are performed.     

Macrotexture influence on vibrational mechanisms of the tyre–road noise of an asphalt rubber pavement

The road surface is one of the most important factors that have influence on the current traffic noise. Usually, for dense surfaces, impacts of the tyre on the pavement generate vibrations which are the dominant mechanisms in the tyre–road noise. In this study, the effect of muffling these vibrations, by the incorporation of crumb rubber (CR) from wasted tyres into asphalt pavements, has been evaluated acoustically. Close proximity measurements have been carried out to register the sound emission generated in the contact zone between a reference tyre and an experimental asphalt pavement with CR. The analysis of the measurements indicates that the incorporation of CR as well as the air voids content has less influence than the macrotexture of the road surface on the acoustical behaviour of this experimental asphalt pavement.     

Improving the training time of support vector regression algorithms through novel hyper-parameters search space reductions

The selection of hyper-parameters in support vector machines (SVM) is a key point in the training process of these models when applied to regression problems. Unfortunately, an exact method to obtain the optimal set of SVM hyper-parameters is unknown, and search algorithms are usually applied to obtain the best possible set of hyper-parameters. In general these search algorithms are implemented as grid searches, which are time consuming, so the computational cost of the SVM training process increases considerably. This paper presents a novel study of the effect of including reductions in the range of SVM hyper-parameters, in order to reduce the SVM training time, but with the minimum possible impact in its performance. The paper presents reduction in parameter C, by considering its relation with the rest of SVM hyper-parameters (γ and ε), through an approximation of the SVM model. On the other hand, we use some characteristics of the Gaussian kernel function and a previous result in the literature to obtain novel bounds for γ and ε hyper-parameters. The search space reductions proposed are evaluated in different regression problems from UCI and StatLib databases. All the experiments carried out applying the popular LIBSVM solver have shown that our approach reduces the SVM training time, maintaining the SVM performance similar to when the complete range in SVM parameters is considered.