A Complete Separation of Hexane Isomers by a Functionalized Flexible Metal Organic Framework

The separation ability of branched alkane isomers (nHEX, 3MP, 22DMB) of the flexible and functionalized microporous iron(III) dicarboxylate MIL‐53(Fe)‐(CF₃)₂ solid is evaluated through a combination of breakthrough experiments (binary or ternary mixtures), adsorption isotherms, X‐ray diffraction temperature analysis, quasi‐elastic neutron scattering measurements and molecular dynamics simulations. A kinetically controlled molecular sieve separation between the di‐branched isomer of hexane 22DMB from a mixture of paraffins is achieved. The reported total separation between mono‐ and di‐branched alkanes which was neither predicted nor observed so far in any class of porous solids is spectacular and paves the way towards a potential unprecedented upgrading of the RON of gasoline.     

Parlay‐based service provision in circuit‐ and packet‐switched telecommunications networks

The spectrum of potential value added services over Internet telephony is wide, but the current service provision solutions are inadequate or proprietary. The nature of Internet differs significantly from that of circuit switched network, however, VoIP architectures can capitalize service control architectures in the PSTN world. We describe such an architecture based on the intelligent network and the Parlay, employing distributed objects and mobile agents as enabling technologies. This architecture has been implemented in the PSTN and the Internet and it has provided a framework for service provisioning, augmenting the space of supported services. Copyright © 2004 John Wiley & Sons, Ltd.     

A plane-polar near-field to far-field transformation with the fast Hankel transform method

It is known that a direct radial integration, used to compute the far-field from uniformly spaced plane-polar near-field measurements requires the evaluation of a large amount of Bessel functions and hence CPU time. Up to 1985 only unequally spaced fast Hankel algorithms were available. Hansen [3] developed an algorithm that was usable for equally spaced measurements points, but only for order zero. His theory is generalised in this paper and applied to a plane-polar near-field to far-field transformation.     

Quand les objets deviennent communicants La mise en confiance des acteurs humains et la question des traces numériques

The “Internet of things” is likely to give a second breath to the information society. However, the loss of control over personal information is both problematical and widely criticized. The “promise” of a better society offered by new services based on communication between machines carries with it frightening corollaries: it evokes a totalitarian space, where anonymous exchanges are no longer possible and the various traits of people’s digital identities are stored by agents of public and business powers. It is thus the management of digital tracking technologies that we wish to explore in this publication. Our hypothesis is that current criticism of a police state or of new forms of economic alienation is taking place at far too general a level. It obscures the real problem with the profusion of tracking methods, which for us reveals a crisis of confidence (as Giddens means it), at the individual level, in the means of production of telecommunications, which is the result of a deficit in the standardization process. From this perspective, the issue of the profusion of tracing technologies and their management transcends the issue of social control to encompass that of social responsibility and of modalities of proofs when the system fails.     

Accumulation and quality of storage protein in developing cowpea,mung bean and soya bean seeds

This study was carried out to compare the time course of laying down seed storage protein in three legumes viz: cowpea (Vigna unquiculata), mung bean (Phaseolus aureus) and soya bean (Glycine max) planted in two replications. Pods were harvested periodically during seed maturation and studied for changes in fresh and dry weights, total sulphur, total nitrogen and protein content. At early stages of development crude protein formed about one-third of dry weight in the legumes but decreased to about one-quarter at maturity. The total sulphur which formed a substantial amount of the sulphur amino-acids in mature seeds did not change much in mung bean and cowpea but increased by about 24% from 20 to 69 days after flowering (DAF) in soya bean. Storage protein accumulation was very rapid between 10 and 14 DAF (10.4% day^?1) in mung bean, 7 and 14 DAF (12.9% day^?1) in cowpea and between 20 and 30 DAF (9.4 day^?1) in soya bean. Thereafter, protein accumulation declined slightly and gradually approached zero at time of seed maturity. The sulphur-to-nitrogen ratios gradually increased with maximum values in the mature seeds. Although seed protein content and quality (on S/N ratio basis) were highest in soya bean, accumulation of storage protein seemed to be faster in cowpea than mung bean and soya bean during seed maturation.     

Ultrafast Doppler imaging of blood flow dynamics in the myocardium

Imaging intramyocardial vascular flows in real-time could strongly help to achieve better diagnostic of cardiovascular diseases. To date, no standard imaging modality allows describing accurately myocardial blood flow dynamics with good spatial and temporal resolution. We recently introduced a novel ultrasonic Doppler imaging technique based on compounded plane waves transmissions at ultrafast frame rate. The high sensitivity of this ultrafast Doppler technique permits to image the intramyocardial blood flow and its dynamics. A dedicated demodulation-filtering process is implemented to compensate for the large tissue velocity of the myocardium during the cardiac cycle. A signed power Doppler processing provides the discrimination between arterial and venous flows. Experiments were performed in vivo in a large animal open chest model ( N = 5 sheep) using a conventional ultrasonic probe placed at the surface of the heart. Results show the capability of the technique to image intramyocardial vascular flows in normal physiological conditions with good spatial (200 μm) and temporal resolution (10 ms). Flow dynamics over the cardiac cycle were investigated and the imaging method demonstrated a phase opposition of flow waveforms between arterial and venous flows. Finally, ultrafast Doppler combined with tissue motion compensation was found able to reveal vascular flow disruption in ischemic regions during occlusion of the main diagonal coronary artery.     

High pass filter with above IC integrated SrTiO3 high K MIM capacitors

This paper describes realization and characterization of SrTiO₃ (STO) high K MIM capacitors above BiCMOS integrated circuit (IC). These capacitances are connected to IC and are used as coupling capacitors in order to realize a high pass filter. Surface capacitance achieved is 10 nF/mm² with capacitance value of 1.2 nF. The process for STO MIM fabrication does not exceed 400 °C, which is compatible with interconnections. Typical K and dielectric losses values obtained are, respectively 110% and 2%. Yield obtained reaches 83% for capacitors. A functional high pass filter using these STO capacitors was realized in this study. It exhibits a cut-off frequency at 6.5 kHz and a constant gain at higher frequencies of −1.3 dB.     

Index Calculus in Class Groups of Non-hyperelliptic Curves of Genus Three

We study an index calculus algorithm to solve the discrete logarithm problem (DLP) in degree 0 class groups of non-hyperelliptic curves of genus 3 over finite fields. We present a heuristic analysis of the algorithm which indicates that the DLP in degree 0 class groups of non-hyperelliptic curves of genus 3 can be solved in an expected time of . This heuristic result relies on one heuristic assumption which is studied experimentally. We also present experimental data which show that a variant of the algorithm is faster than the Rho method even for small group sizes, and we address practical limitations of the algorithm.