Durability of particleboards made from wood particles chemically modified with propionic anhydride: results after six years in ground stake-test

Propionylated particleboard stakes with 12.2% propionyl content were tested in ground contact in Western Greece. The stakes showed severe attack after five years of testing and total decay after six years, whereas the unmodified boards showed total decay during the fourth year of testing.     

Surface area production during grinding

During grinding, in cascading mills, the mass distribution of the material moves continuously to finer sizes. Grinding models are usually designed to predict the size distribution of the mill products either as a function of effective breakage events and the time or the energy consumed by the mill. Mill products are always tested for their size analysis and their fineness is usually expressed as the size d through which a certain amount of material passes, i.e. d₈₀. However, particulate materials have some supplementary properties that a grinding model should predict as well. The specific surface area is such an important supplementary property. Initially, the present work examines the relationship between mass distribution and the surface area of ground materials and determines the conditions under which, mass distribution can be used to determine the surface area. Based on these findings the work further examines the operating conditions of a cascading mill under which the surface area of the material increases at the highest rate. The operating parameter examined is the mill load ratio expressed as the mass ratio of mill grinding media and the material present in the mill.     

Implementation of a high speed frequency synthesizer employing a dual input phase accumulator

We present a new PLL based frequency synthesizer, in which we have replaced the conventional phase frequency detector and the dividers (programmable counters) with a sequential dual input phase accumulator (DIPA), consisting of a digital circuit employing adders, registers and a ladder. The main feature of the DIPA is that the two input frequencies are not required to be normalized (divided down) to the step frequency of the synthesizer. Instead, the two different high frequencies, that is the reference and the output frequency of the synthesizer, are applied directly. The DIPA samples and normalizes their phases at very high rates, calculates their phase difference, producing an output that consists of a dc component proportional to the phase difference and harmonics of the two input high frequencies. These harmonics are high frequencies and can easily be rejected by a wide bandwidth filter of the loop, without affecting the high convergence speed of the loop. Moreover, these harmonics do not generate spurs near the output frequency. The resolution of the DIPA based synthesizer depends only on the length of the digital word of the DIPA, and its convergence speed depends on the lower of the two input frequencies. The output of the DIPA is a linear function of the phase difference of the two input frequencies and its dynamic range exceeds the limit of ±2π that governs the conventional phase detectors. Thus, the proposed frequency synthesizer based on the DIPA has low phase noise, no spurs nearby the output frequency, high resolution and fast convergence rate. Additionally, the output frequency can be digitally modulated under the control of the closed loop, either by phase or frequency modulation.     

Optimization methodology of dynamic data structures based on genetic algorithms for multimedia embedded systems

Modern multimedia application exhibit high resource utilization. In order to efficiently run this kind of applications in embedded systems, the dynamic memory subsystem needs to be optimized. A key role in this optimization is played by the dynamic data structures that reside in every real-life application. This paper presents a novel and automated way to optimize dynamic data structures. The search space is pruned using genetic algorithms that converge to the best multilayered data structure implementation for the targeted applications.     

Microstructure effect on the properties of a commercial low-fusing dental porcelain

The aim of this study was to investigate the effect of firing cycle on a dental porcelain microstructure in order to correlate microstructure changes with mechanical and thermal properties. A commercial low-fusing dental porcelain powder (Omega 900, Vita) was investigated for this purpose. The powder was treated at different temperatures in the range 750–1000 °C. The fired samples were characterized in terms of their morphology and microstructure, and their mechanical and thermal properties were evaluated. The results showed that firing temperature affects porcelain microstructure influencing significantly in this way both the mechanical properties and the thermal expansion coefficient of the fired objects. Firing at 800 °C led to a homogeneous structure. After treatment at this temperature, the leucite crystals exhibit their maximum concentration and they are well dispersed into the glassy phase. As a consequence the optimum mechanical strength and the maximum thermal expansion coefficient are observed in these samples.     

XSD: A Hierarchical Access Method for Indexing XML Schemata

Search operations and browsing facilities over an XML document database require special support at the physical level. Typical search operations involve path queries. This paper proposes a hierarchical access method to support such operations and to facilitate browsing. It advocates the idea of searching large XML collections by administering efficiently XML schemata. The proposed approach may be used for indexing XML documents according to their structural proximity. This is obtained by organizing the schemata of a large XML document collection in a hierarchical way by merging structurally close schemata. The proposed structure, which is called XML Schema Directory (XSD), is a balanced tree and it may serve two purposes: (1) to accelerate XML query processing and (2) to facilitate browsing. Received 15 March 2001 / Revised 12 April 2001 / Accepted in revised form 11 May 2001     

Support software for the development of programmable logic controller applications

Enhancements to the software aids, used for the development of Programmable Logic Controller programs, are proposed in this work. A possible architecture of the software realizing these enhancements and the language constructs required for its configuration to a specific application are also presented. Based on this architecture, experimental software aids have been developed to demonstrate that it is quite feasible to provide the major services considered in this proposal. These services allow the program developer to emulate the dynamic operation of a specific programmable controller to alternative scenarios of input variations and relationships over a defined time horizon, and configure displays of graphics and timing diagrams which may assist him in following up and testing the program execution.     

Liquid-phase theoretical antioxidant activity trend of some cinnamic acid antioxidants

The trend in antioxidant activity of four cinnamic acid antioxidants, derived on the basis of their liquid-phase phenolic O H bond dissociation enthalpies, is determined theoretically, with the aid of the polarizable continuum model at the density functional theory level. Three solvents, differing in their hydrogen-bonding ability and polarity—n-heptane, acetonitrile, and ethanol—were used to model different environmental situations. The trends in solution-phase antioxidant activity appeared different in each solvent; still, the theoretical antioxidant activity trend derived in n-heptane was in excellent agreement with the experimental one in the lipid systems and the gas-phase system. Different ortho substituents show notably different solvent effects. These results could lead to the determination of reliable antioxidant activity trends in real-solution environments of interest in food or biological science frameworks.     

Gas/particle partitioning of seven volatile polycyclic aromatic hydrocarbons in a heavy traffic urban area

Air samples (vapor- and particle-phase) were taken for 19 sampling events during the period from December 1997 to July 1998 in an urban site in the center of Athens. The urban site is densely populated and characterized by heavy traffic circulation and elevated concentrations of VOCs, NO(x), CO and smoke. Seven volatile polycyclic aromatic hydrocarbons (PAHs) were determined in samples. The temperature dependence of gas-phase atmospheric concentration of PAHs, C(g), was investigated using diagrams of natural logarithm of partial pressures (lnP) vs. reciprocal mid-point temperatures. For the six of seven volatile PAHs, the temperature dependence of lnP was statistically significant (at least at the 90% confidence level) and the temperature accounted for 21-67% of the variability in gas-phase concentrations. The gas-phase concentration C(g) of the very volatile PAHs was affected more significantly by changes in temperature, but the variation of the less-volatile PAHs fluoranthene and pyrene C(g), was better explained by changes in temperature. The temperature dependence of gas/particle partitioning constant K(P) was also examined. Regressions of log(K(P))(-1) vs. T(-1) for fluorene, fluoranthene and pyrene were classified into two different temperature ranges. The gas/particle partitioning of PAHs was studied by correlating the partition constant to the sub-cooled liquid saturation vapor pressure (P(L)(o)). The Junge adsorption model underestimated the particle fraction of volatile PAHs probably due to the presence of non-exchangeable fraction. Slopes (m(r)) of the regressions logK(P) vs. logP(L)(o) were different from the value -1 as Pankow's theory predicts. The short distance between the sampling point and the emission sources is also estimated to be a factor that causes deviations from the theoretical value. Evidence that atmospheric conditions favorable for secondary aerosol formation coincide with higher value of m(r), was provided by limited sampling events. An interrelation was found to exist between the m(r) values, allowing the prediction of the gas/particle partitioning of a series of seven PAHs by the measurement of a single PAH partitioning.