Enhancement of Critical Current Density of MgB<Subscript>2</Subscript> by Glutaric Acid Doping: a Simultaneous Improvement on the Intrinsic and Extrinsic Properties

In this study, we report an enhancement of critical current density of bulk MgB₂ superconductors by glutaric acid (C₅H₈O₄) doping. The effects of glutaric acid doping on MgB₂ lattice resulted in a record self-field J _c of the order of 10⁶ A/cm². A simultaneous improvement in the connectivity, pinning force, and H _c2 is the major factor that determined excellent J _c performance. X-ray diffraction analysis showed that samples were single-phase MgB₂ with a minor trace of impurities. A dramatic change in grain morphology and homogeneity in grain distribution was found in the SEM images of doped samples. We observed that homogeneity in grain distribution played a crucial role in the connectivity and the upper critical field (H _c2) of the doped samples. We were able to introduce a new dopant through a two-step mixing approach which is suitable to overcome the degradation of low field and self-field J _c reported for carbon-doped MgB₂ superconductor samples.     

Novel Design of UWB Jeans Based Textile Antenna for Body-Centric Communications

This research presents an ultra-wideband (UWB) textile antenna design for body-centric applications. The antenna is printed on a 1 mm thick denim substrate with a 1.7 relative permittivity. The jeans substrate is sandwiched between a partial ground plane and a radiating patch with a Q-shaped slot. The slotted radiating patch is placed above the substrate and measures 27.8 mm × 23.8 mm. In free space, the antenna covers the ultra-wideband spectrum designated by the Federal Communication Commission (FCC). Various parameters of the antenna design were changed for further performance evaluation. Depending on the operating frequency, the antenna's realized gain varied from 2.7 to 5 dB. The antenna achieved high radiation efficiency with an omnidirectional radiation pattern. A parametric study was performed in research on varying antenna substrates and other components of the antenna. The three outermost layers of the human body are used to model a human phantom for on-body simulation. After that, the antenna was placed at five different distances from the phantom. The findings demonstrate that at close distances to the phantom, the antenna's gain and efficiency at lower frequencies are reduced. The antenna's radiation efficiency and gain were much higher at higher frequencies for distances greater than 6 mm. Compared to free space, the antenna's radiation pattern was more omnidirectional, especially at higher frequencies. This antenna is novel, compact and has an ultra wide bandwidth, a maximum of 94.60% radiation efficiency and a 5 dBi gain that will make it a good candidate for body-centric communications.     

An economic model predictive control approach to integrated production management and process operation

Managing production schedules and tracking time‐varying demand of certain products while optimizing process economics are subjects of central importance in industrial applications. We investigate the use of economic model predictive control (EMPC) in tracking a production schedule. Specifically, given that only a small subset of the total process state vector is typically required to track certain scheduled values, we design a novel EMPC scheme, through proper construction of the objective function and constraints, that forces specific process states to meet the production schedule and varies the rest of the process states in a way that optimizes process economic performance. Conditions under which feasibility and closed‐loop stability of a nonlinear process under such an EMPC for schedule management can be guaranteed are developed. The proposed EMPC scheme is demonstrated through a chemical process example in which the product concentration is requested to follow a certain production schedule. © 2016 American Institute of Chemical Engineers AIChE J, 63: 1892–1906, 2017     

Smart places: Multi-agent based smart mobile virtual community management system

Now-a-days advances in mobile device technology aim to build complex computational systems providing a maximum level of flexibility, decentralization, simplest form of interactivity, and ease of use. Recently, the launch of the agent-oriented platform JaCaMo and its Android client based platform JaCa-Android have provided an appropriate level of abstraction to build smart mobile client server systems providing these attributes. By using these platforms, we have developed a multi-agent based Smart Mobile Virtual Community Management System (SMVCMS) that makes it possible to provide a decentralized and open management of virtual communities. This paper addresses the design and architecture of our multi-agent server and client application. It elaborates different features of our system; such as how a participant in virtual communities is supported by a Jason agent that encapsulates the logic and the control of the participation in a virtual community (such as publishing posts, notifying members, making recommendations for the user, etc.). It also discusses how the set of CArtAgOartifacts provides the basic functionalities and operations giving access to the functionalities for knowledge exchange in virtual communities, and personal agents onAndroid exploit these artifacts to execute their tasks while achieving their individual and collective goals. We have employed SMVCMS in the context of Smart Cities and found that the system fulfills the desired goals, such as decentralization of community management, personalized automatic management and discovery of communities, autonomy of agents and flexibility so that any agent can create its own community with the maximum level of ease.     

Synthesis of reactor blend of linear and branched polyethylene using metallocene/Ni‐diimine binary catalyst system in a single reactor

This work reports the synthesis of a series of reactor blends of linear and branched polyethylene materials using a combination of [1,4‐bis(2,6‐diisopropylphenyl) acenaphthene diimine nickel(II) dibromide] ( 1 )/MMAO, known as an active catalyst for the production of branched polyethylene, and [rac‐ethylenebis(indenyl) zirconium dichloride] ( 2 )/MMAO, which is active for the production of linear polyethylene. The polymerization runs were performed at various levels of temperature, pressure, and catalyst 2 molar fractions. At 5°C, there was very low influence of catalyst 2 molar fraction on the overall catalyst activity. However, at 30°C and 50°C, the overall catalyst activity increased linearly with catalyst 2 molar fraction. The same linear dependency was also found for the polymerization reactions carried out at 60°C and 100°C. At various levels of temperature and ethylene pressure, higher melting temperature and crystallinity were observed with an increase in catalyst 2 molar fraction. At 60°C and 100 psig, the DSC thermograms of the polymers produced with 1 / 2 /MMAO exhibited two distinct peaks with melting temperatures closely corresponding to the melting temperatures of the polymers produced with the individual catalysts, 1 /MMAO and 2 /MMAO. The GPCV analysis of all polyethylene samples showed monomodal molecular weight distributions with low polydispersities. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 2212–2217, 2005     

Synthesis of poly(acrylamide‐co‐4‐vinylpyridine) hydrogels and their application in heavy metal removal

A series of poly(acrylamide‐co‐4‐vinylpyridine) hydrogels having varied acrylamide/4‐vinylpyridine content and different crosslink ratios of N,N′‐methylene‐bisacrylamide was prepared by using solution polymerization. The prepared hydrogel polymers were characterized by their elemental analysis, infrared spectroscopy, and equilibrium water content. The polymers were investigated toward metal ion uptake of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II). The polymers were more sensitive to Cu(II) and Ni(II) and the order of metal ion binding was Ni(II), Cu(II) > Zn(II) > Co(II) > Mn(II). Metal ion uptake by the polymers was reduced as the pH of the medium decreased. Recycling of the resins resulted in high recovery of the metal ions from their aqueous solutions. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2522–2526, 2003     

Characterization of Mineral Ores from Northern and Northwest Pakistan

Pakistan is home to many varieties of minerals, some of which make it prominent in the mineral world. The exploration of Pakistan’s mineral wealth is far from complete and has rarely been conducted in the north and northwest of the country. This article presents the newest exploration and examination of minerals from an unexploited area in Pakistan. Several materials characterization techniques were carried out to examine and identify the phase and structure of the minerals, including x-ray diffraction, energy dispersive x-ray spectroscopy, scanning electron microscopy, and transmission electron microscopy. In this study, several commonly found minerals are identified, including calcite, dolomite, quartz, talc, and fluorapatite.     

High Temperature Crystallization Process of a-Si Thin-films on Aluminum Nitride Substrates

Crystallization of silicon (Si) from amorphous silicon (a-Si) on foreign substrates has been studied by various research institutes. Crystallization of silicon thin-films on foreign substrates acts as an active layer in silicon thinfilm solar cells. In this research, due to the compatibility of thermal stability and expansion coefficient with Si, we used an aluminum nitride (AIN) substrate as an alternative candidate to glass and other ceramic substrates. P-type amorphous Si 5 μm thin-film was deposited using an ebeam evaporator directly on AIN substrates. The deposited layer was annealed at high temperature (°C) with N2 environment in a conventional tube furnace. Optical characterization was done using an optical microscope to investigate the surface morphology of as-grown and annealed samples. A smoother surface with an average grain size of about 3–4 μm was formed after annealing. Reflectance parameters were measured by UV-vis spectrometry. UV-vis-NIR was studied on as-grown and annealed samples to calculate the quality factor of the Si thin-film which was about 84.4 %. X-ray diffraction (XRD) was used to determine the phase direction of the Si thin-film before and after thermal annealing. It was observed that FWHM varied from 7.73 to 9.30 cm?1, Raman shift was from 520 to 522 cm^?1, and the stressed level also changed from 180 to 540 Mpa after annealing at high temperature for a long time. Interestingly, a crystallinity fraction was achieved of about 90 % at 1100 °C.