A hybrid discrete particle swarm optimization for vehicle routing problem with simultaneous pickup and delivery

Vehicle routing problem (VRP) is an important and well-known combinatorial optimization problem encountered in many transport logistics and distribution systems. The VRP has several variants depending on tasks performed and on some restrictions, such as time windows, multiple vehicles, backhauls, simultaneous delivery and pick-up, etc. In this paper, we consider vehicle routing problem with simultaneous pickup and delivery (VRPSPD). The VRPSPD deals with optimally integrating goods distribution and collection when there are no precedence restrictions on the order in which the operations must be performed. Since the VRPSPD is an NP-hard problem, we present a heuristic solution approach based on particle swarm optimization (PSO) in which a local search is performed by variable neighborhood descent algorithm (VND). Moreover, it implements an annealing-like strategy to preserve the swarm diversity. The effectiveness of the proposed PSO is investigated by an experiment conducted on benchmark problem instances available in the literature. The computational results indicate that the proposed algorithm competes with the heuristic approaches in the literature and improves several best known solutions.     

Electromagnetic shielding efficiency of nonwoven insulation panels designed with recycled textiles and copper wires

Insulation applications of nonwovens has become increasingly important in the construction and automotive industries since the late 1990s. Besides, recycling and reusing fibrous waste becomes one of the most important raw materials of nonwovens to promote effective use of resources recently. On the other hand, metals are now being increasingly replaced by thermoplastics for housing commercial equipment, due to flexibility, light weight, and low cost for electromagnetic shielding purposes. In this study, we design nonwoven insulation panels containing copper wires with different intensity and length to provide electromagnetic wave protection by using recycled textiles. The method is simple, the material is cheaper, and more importantly, the whole material can be produced by using only waste materials. The electromagnetic shielding characteristics of the panels were measured and discussed. The experimental results indicated that the variation in wire length and amount affects the electromagnetic (EM) shielding property. With this method, the products with electromagnetic shielding effect in certain areas can be developed. In particular, there is a big potential for electromagnetic shielding applications in wide bandwidth, such as 1125–2925 MHz.     

Optical and electrochemical characteristics of sol–gel deposited iron oxide films

Homogenous, crack free iron oxide films are prepared by the sol–gel spin coating technique from a solution of iron iso-propoxide and isopropanol. The films were characterized by X-ray diffractometry (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), UV-visible (UV–Vis) spectroscopy and cyclic voltammetry (CV). XRD of the films showed that they had an amorphous structure. The optical constants refractive index (n) and extinction coefficient (k) were measured by scanning spectrometer in the wavelength range of 390–990 nm. The n and k values were found n =2.3±0.01 and k =0.2±0.002 at 650 nm. The electrochemical behavior investigated in 0.5 M LiClO₄ propylene carbonate (PC) electrolyte-CV examinations showed good rechargeability of the Li⁺/e⁻ insertion extraction process beyond 300 cycles. Spectroelectrochemistry showed that these films exhibit weak cathodic coloration in the spectral range of 350–800 nm.     

Smart structures and their applications on active vibration control: Studies in the Department of Aerospace Engineering, METU

This work presents the theoretical and experimental studies conducted in Aerospace Engineering Department of Middle East Technical University on smart structures with particular attention given to the structural modelling characteristics and active suppression of in-vacuo vibrations. The smart structures considered in these analyses are finite and flat aluminium cantilever beam-like (called as smart beam) and plate-like (called as smart fin) structures with surface bonded lead–zirconate–titanate patches. Finite element models of smart beam and smart fin are obtained. Then the experimental studies regarding open loop behaviour of the structures are performed by using strain gauges and laser displacement sensor to determine the system models. Further studies are carried out to obtain H _∞ and μ-synthesis controllers which are intended to be used in the suppression of free and forced vibrations of the smart structures. It is observed that satisfactory attenuation levels are achieved and robust performance of the systems in the presence of uncertainties is ensured. In that respect a comparative study involving H _∞ and sliding mode controls is also conducted. Recently, the studies involving aerodynamic loading are also gathering pace.     

Electrospun nylon 6,6 nanofibers functionalized with cyclodextrins for removal of toluene vapor

Functional nylon 6,6 nanofibers incorporating cyclodextrins (CD) were developed via electrospinning. Enhanced thermal stability of the nylon 6,6/CD nanofibers was observed due to interaction between CD and nylon 6,6. X‐ray photoelectron spectroscopy and attenuated total reflectance Fourier transform infrared spectroscopy studies indicated the existence of some CD molecules on the surface of the nanofibers. Electrospun nylon 6,6 nanofibers without having CD were ineffective for entrapment of toluene vapor from the environment, whereas nylon 6,6/CD nanofibrous membranes can effectively entrap toluene vapor from the surrounding by taking advantage of the high surface‐volume ratio of nanofibers with the added advantage of inclusion complexation capability of CD presenting on the nanofiber surface. The modeling studies for formation of inclusion complex between CD and toluene were also performed by using ab initio techniques. Our results suggest that nylon 6,6/CD nanofibrous membranes may have potential to be used as air filters for the removal of organic vapor waste from surroundings. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41941.     

Antibacterial oil‐based polyurethane films for wound dressing applications

As an alternative to petroleum‐based polyol, hydroxyl containing material was prepared from linseed oil for polyurethane synthesis. Hexamethylene di‐isocyanate (HMDI) and/or 4, 4′‐methylene diphenyl di‐isocyanate (MDI) were used as isocyanate source. The polymerization reaction was carried out without catalyst. Polymer films were prepared by casting‐evaporation technique. The MDI/HMDI‐based polyurethane and its films had higher T_g and better thermal property than that of the HMDI‐based one because of the existence of benzene ring in the polymer chain. Static water contact angle was determined to be 74° and 77.5° for HMDI and MDI/HMDI‐based films, respectively. Water adsorption was found to be around 2.6–3.6% for both films. In vitro degradation of polyurethanes in phosphate buffered saline at 37°C was investigated by gravimetric method. Fourier transform infrared spectroscopy and scanning electron microscopy were used for confirmation of degradation on the polymer surface. The degradation rate of the HMDI‐based polyurethane film was found higher than that of the MDI/HMDI‐based film. Both the direct contact method and the MMT test were applied for determination of cytotoxicity of polymer films, and the polyurethane films investigated here was not cytotoxic. Silver‐containing films were prepared using Biocera A® as filler and were screened for their antibacterial performance against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, and/or Bacillus subtilis. The films prepared with and without Biocera A® exhibited antibacterial activity. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Mn(II), Co(II) and Ni(II) complexes of 4-(2-thiazolylazo)resorcinol: Syntheses, characterization, catalase-like activity, thermal and electrochemical behaviour

Manganese(II), cobalt(II) and nickel(II) acetates react with the ligand, 4-(2-thiazolylazo)resorcinol, to form complexes of general formula [ML₂] for MCo(II), Ni(II) and [ML₂]·2H₂O for MMn(II). Each of the azo complexes was characterized using elemental analysis, electrolytic conductance, UV–visible spectroscopy and magnetic susceptibility. An octahedral structure is proposed for all complexes prepared, which molar conductance data revealed to be non-electrolytes. IR spectra reveal that the ligand is coordinated to the metal ions in a tridentate manner via the resorcinol OH, azo N and thiazole N groups as donor sites. The electrochemical behaviour of the ligand and its complexes were obtained by cyclic voltammetry. Thermal decomposition studies were undertaken to secure additional information on the structure of the investigated compounds. The manganese(II) complex catalysed the disproportionation of hydrogen peroxide in the presence of imidazole.     

Vitamin A status of healthy children in Manisa,Turkey

Background  

Vitamin A deficiency is a major public health nutrition problem in the developing world. Even subclinical Vitamin A deficiency is associated with increased childhood mortality. Severe maternal vitamin A deficiency may cause increased mortality in the first months of life. There have been a limited number of studies regarding vitamin A status in Turkey. The aim of this study was to assess vitamin A status of healthy children in Manisa, Turkey.     

Fabricating a new immobilization matrix based on a conjugated polymer and application as a glucose biosensor

A new monomer named 4-(dihexylamino)9,12-di(thiophen-2-yl)-7H-benzo[de]benzo[4,5]imidazo[2,1-a]isoquinolin-7-one (ThBN) is synthesized and used as a potential glucose biosensor after electropolymerization of the ThBN on the graphite pencil electrode. The amount of glucose is determined according to the decrease in the amount of oxygen by using cyclic voltammetry technique. Herein, conjugated polymer of ThBN is used as a immobilization matrix. The synthesized PThBN is found to be effective enzymatic biosensor having wide linear glucose determination range between 2.975 × 10⁻³ and 2.087 mM with a limit of detection of 0.0304 mM and a sensitivity of 0.1326 μA/mM cm². This potential enzymatic biosensor has been also tested in commercial samples and found to be useful to detect the glucose concentration.