Development of the high performance magnesium based hydrogen storage alloy

Series of MgNi type alloys with Ti, Al, Zr, Pd and Co additive elements were synthesized by mechanical alloying and their electrochemical hydrogen storage characteristics were investigated. Systematical alloy designing indicated that Mg_0.80Ti_0.15Al_0.05Zr_0.05Ni_0.95 alloy has the best electrode performance. The atomic fractions in this alloy were believed to be optimum to get the reasonable amount of hydrogen storage with the improved cyclic stability. Titanium was estimated to enter into Mg(OH)₂ layer during the discharging process and make this barrier layer more penetrable by elemental hydrogen. Al and/or Al-oxides were predicted to dissolve selectively throughout the barrier hydroxide layer and thus reduce the stability of this layer. The main contribution of Zr was estimated to arise from its large atomic size that Zr atoms can create extra sites for the elemental hydrogen in the alloy structure. As the alloy charge transfer resistances decreased, the alloy retention rates increased. Improvement in the alloy capacity retaining rate was also closely related with the hydrogen diffusion coefficients in the alloy.     

Innovative hydrogen release from sodium borohydride hydrolysis using biocatalyst-like Fe2O3 nanoparticles impregnated on Bacillus simplex bacteria

For the first time in this innovative study, microorganisms such as Bacillus simplex bacteria, mostly used in biological activity studies, are used as a bio-supporter agent of iron to release hydrogen from sodium borohydride hydrolysis at 25.0 ± 0.1 °C. The goal is to investigate thoroughly sodium borohydride hydrolysis catalyzed by Fe₂O₃ nanoparticles impregnated on microorganism such as Bacillus simplex (BS) bacteria (Fe₂O₃@BS NPs) known with strong antibacterial properties, which makes innovative them a candidate for hydrolysis reaction. This study was focused on the preparation, identification, and catalytic use of biocatalyst-like Fe₂O₃@BS NPs for hydrogen release from the sodium borohydride hydrolysis at 25.0 ± 0.1 °C. The characterization results made after and before hydrolysis reaction using by SEM/SEM-EDX, FT-IR, XRD, UV–vis, XPS, DLS, ELS Zeta potential, ESR, and TEM techniques reveal the formation of highly active, stable, durable, and long-lived biocatalysts-like Fe₂O₃@BS NPs.     

Experimental investigation on flow improvement in compressor cascades

There is no general rule in the literature to help choose a correct flow control device for any given case of turbomachinery applications. This suggests individual optimization of flow control devices for each specific case. The objective of this study is to prove experimentally the benefits of passive control methods in improving the compressor performance. This allows to reduce the fuel consumption, leading to energy saving and reduction of atmospheric pollution. Two features have been controlled in this study: flow separation over the blade surfaces and the secondary flow over the cascade endwalls. Vortex generator ribs are tested on the blade suction side for flow reattachment on the blade surfaces, and low‐profile vortex generators are tested on the side walls of the compressor cascade against secondary flow losses. Different vortex generator designs are compared for total pressure recovery, flow turning, boundary layer characteristics, and pressure distributions over the endwalls. Copyright © 2016 John Wiley & Sons, Ltd.     

Optical and electrochemical characteristics of sol–gel deposited iron oxide films

Homogenous, crack free iron oxide films are prepared by the sol–gel spin coating technique from a solution of iron iso-propoxide and isopropanol. The films were characterized by X-ray diffractometry (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), UV-visible (UV–Vis) spectroscopy and cyclic voltammetry (CV). XRD of the films showed that they had an amorphous structure. The optical constants refractive index (n) and extinction coefficient (k) were measured by scanning spectrometer in the wavelength range of 390–990 nm. The n and k values were found n =2.3±0.01 and k =0.2±0.002 at 650 nm. The electrochemical behavior investigated in 0.5 M LiClO₄ propylene carbonate (PC) electrolyte-CV examinations showed good rechargeability of the Li⁺/e⁻ insertion extraction process beyond 300 cycles. Spectroelectrochemistry showed that these films exhibit weak cathodic coloration in the spectral range of 350–800 nm.     

Implementing and sustaining lean processes: the dilemma of societal culture effects

Lean processes allow the elimination of waste and the resulting improvements in productivity. However, implementing and sustaining lean processes are easier in some organisations than in others. There may be societal culture differences, as the successes in initial implementation in Japan have not been followed by global success. As organisations accelerate their lean efforts to gain or maintain competitive advantage, studying societal cultural effects seems timely. Understanding of the societal culture that the firm or subsidiary is operating in would be useful in determining how lean processes should lead the effort. Using the cultural dimensions developed by Hofstede, we examine the interconnection of societal culture and lean processes. For example, a societal emphasis on individualism is positively associated with a high level of lean process adoption, in terms of individual employee involvement, individual creativity and firm efficiency. A societal emphasis on high uncertainty avoidance is positively associated with a high level of lean process adoption, in terms of control and standardisation, efficiency and long-term philosophy. A societal emphasis on high power distance is positively associated with a high level of lean process adoption, in terms of control and standardisation, and efficiency. A long-term orientation in the society will be positively associated with a high level of lean process adoption, in terms of all of the dimensions. A societal emphasis on femininity will be positively associated with a high level of lean process adoption, in terms of employee involvement, creativity and long-term philosophy.     

Optimal location planning of relay-based next generation wireless access networks

Use of relays is considered one of the most effective ways for capacity enhancement and coverage extension in next-generation broadband wireless access networks (BWAN). The paper investigates the location planning problem in BWANs, aiming at an optimal deployment of relay stations and base stations to enhance capacity. We develop formulations in mixed integer linear programming to effectively capture various planning policies that govern relay and base station placement. Case studies are conducted to verify the effectiveness of the proposed formulations. We show that the same traffic demand can be satisfied with up to 73 % fewer relay stations with a slight (6 %) decrease in the overall network capacity, compared with our benchmark. Based on the developed formulations, we introduce a maximin objective function to properly distribute excess bandwidth to all subscriber stations rather than assigning it to a single one, which surprisingly leads to a significant gain in the rate allocated to each subscriber station.     

Antibacterial oil‐based polyurethane films for wound dressing applications

As an alternative to petroleum‐based polyol, hydroxyl containing material was prepared from linseed oil for polyurethane synthesis. Hexamethylene di‐isocyanate (HMDI) and/or 4, 4′‐methylene diphenyl di‐isocyanate (MDI) were used as isocyanate source. The polymerization reaction was carried out without catalyst. Polymer films were prepared by casting‐evaporation technique. The MDI/HMDI‐based polyurethane and its films had higher T_g and better thermal property than that of the HMDI‐based one because of the existence of benzene ring in the polymer chain. Static water contact angle was determined to be 74° and 77.5° for HMDI and MDI/HMDI‐based films, respectively. Water adsorption was found to be around 2.6–3.6% for both films. In vitro degradation of polyurethanes in phosphate buffered saline at 37°C was investigated by gravimetric method. Fourier transform infrared spectroscopy and scanning electron microscopy were used for confirmation of degradation on the polymer surface. The degradation rate of the HMDI‐based polyurethane film was found higher than that of the MDI/HMDI‐based film. Both the direct contact method and the MMT test were applied for determination of cytotoxicity of polymer films, and the polyurethane films investigated here was not cytotoxic. Silver‐containing films were prepared using Biocera A® as filler and were screened for their antibacterial performance against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, and/or Bacillus subtilis. The films prepared with and without Biocera A® exhibited antibacterial activity. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Controlling the particle size of nanobrookite TiO2 thin films

In this study, pure nanobrookite TiO₂ thin films were successfully deposited on glass substrates with the spin-coating method using titanium butoxide and acetic acid. The particle size of TiO₂ films was controlled by the water:AcAc volume ratio. This study shows that it is possible to obtain single oriented pure brookite films. The structural and optical properties of the nanobrookite TiO₂ thin films were characterized by X-ray diffraction (XRD), atomic force microscopy (AFM), ultraviolet-visible spectroscopy (UV-vis), scanning electron microscopy (SEM), spectrophotometer (NKD), and Fourier transform infrared spectrometer (FTIR).     

Damage of Stainless Steel Components by Olive Paste

Failure of equipment for processing olives interrupted oil production after only 3 weeks in service. Macroscopic and microscopic analyses were used in the present investigation to analyze damaged surfaces. Observations and data suggest that failure was induced via tribocorrosion with a predominance of mechanical damage. This damage is attributed to abrasive wear combined with corrosion of AISI 304L stainless steel in olive paste (seed particles and pulp) mixed with tap water. Microscopic observations revealed fracture and localized plastic deformation in the damaged area along with a tribologically transformed structure and work-hardened surfaces. The tribological behavior of AISI 304L was determined using a pin-on-disc tribometer, and these results were compared to damage on the olive processing equipment. The steel was sensitive to tribo-oxidation, mostly due to abrasion by seeds and steel wear particles, and somewhat due to corrosion reactions with the environment.     

Biodegradation of low‐density polyethylene/thermoplastic starch foams before and after electron beam irradiation

Foamy low‐density polyethylene/plasticized starch (LDPE/PLST) blends at different compositions were produced in the presence of azodicarbonamide (ACA) compound as foaming agent. The LDPE/PLST blends before and after electron beam irradiation were investigated in terms of mechanical properties, bulk density, and structure morphology. Moreover, the biodegradability of these materials was evaluated by the soil burial test for 2 months, in which the buried sheets were also examined by scanning electron microscopy (SEM). The results showed that the increase of PLST content from 24 to 30% was accompanied by a decrease in the yield and break stresses of 10 and 20% for the unirradiated blends without the foaming agent, respectively. Further decrease in these mechanical parameters was observed after the foaming process. The bulk density, void fraction, cell size measurements as well as the examination by SEM illustrate clearly the cell growth of the foam structure. The soil burial test and SEM micrographs indicate the growth of microorganisms overall the blend sheets and that the blend was completely damaged after two months of burying. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007