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121.
122.
I Kabelkova-Jancarkova 《Water science and technology》2006,54(6-7):331-338
This paper presents the assessment of the efficiency of the main biological nitrogen transformation processes in a shallow well-oxygenated river and conditions under which they are active and stabilise. The process dynamics was studied with the help of mathematical modelling of 2 years on-line data series measured in a reach of the Toess River, Switzerland. The algal nitrogen uptake was very stable and unaffected by most but frequent flood events. Daylight photosynthetic nitrogen uptake stabilised at 6 mgN mstreambed(-2) h(-1) (15 degrees C), dark uptake on storage products at rates of 0.5-2.5 mgN mstreambed(-2) h(-1). Nitrogen uptake by heterotrophic bacteria in the hyporheic zone was relatively constant at a level of 1.5-3.5 mgN mstreambed(-2) h(-1). Streambed nitrification could establish only during periods with average an daily concentration of at least 0.3 g(NH4-N) m(-3) in river water for several weeks. The maximum nitrification rate was 35 mgN mstreambed(-2) h(-1) for 3 g(NH4-N) m(-3). The effects of reduced nitrification in the WWTP and of river banks shading on a sudden ammonium peak were simulated. A river reach endangered by ammonium spills should be kept open to sun to favour ammonium uptake by algae. In-stream nitrification reduces ammonium peaks efficiently but leads to toxic nitrite concentrations. 相似文献
123.
X-ray diffraction analysis shows that the transformation during heat treatment from amorphous to crystalline phases of bismuth-borate glass samples takes place in sequences. After a short heat treatment, 5 min at 550 °C, a layered structure with a preferred orientation of crystallites on the surface is observed. After a long heat treatment, 8 h at the same temperature, normal polycrystalline bulk samples are obtained. 相似文献
124.
I. A. Ovid’ko 《Journal of Materials Science》2007,42(5):1694-1708
An overview of experimental study, computer simulations and theoretical models of fracture of nanocrystalline materials is
presented. The key experimentally detected facts on ductile and brittle fracture processes are discussed. Special attention
is paid to computer simulations and theoretical models of nucleation and growth of nanocracks and nanopores in deformed nanocrystalline
materials. Also, we discuss mechanisms for fracture suppression in such materials showing good ductility or superplasticity. 相似文献
125.
Christian P. Romero Jonathan I. Avila Edgardo Cisternas Guerau B. Cabrera Alejandro L. Cabrera Kristiaan Temst Margriet J. Van Bael 《Journal of Materials Science》2007,42(18):7667-7672
Hydrogen desorption curves were obtained from a sample composed of a square arrangement of Co dots with average diameter of
4.4 μm, separated by a distance of 11.6 μm. A macroscopic sample of Co dots grown on a 2.5 × 2.5 cm Si substrate was made
by standard lithographic techniques and used in these experiments. Thermal programmed desorption (TPD) was performed under
ultra-high vacuum conditions. Hydrogen TPD curves were obtained from a 1 × 1 cm Co dots samples displaying a maximum of intensity
at 425 K. Hydrogen TPD curve was also obtained from 1 cm× 1 cm samples of Co films and Co foils for comparison. The hydrogen
TPD curves have decreasing intensity from the Co foils to the Co dots and finally to the Co films. This indicates that there
are more sites for hydrogen adsorption on the Co dots than in the Co films. This is a surprising result because there is approximately
8.7 times less Co atoms exposed in the Co dots that in the Co film sample. A desorption energy of 27 kcal/mol was obtained
for the Co dots suggesting that hydrogen is adsorbed on an hcp hollow site of the Co dot crystalline structure. 相似文献
126.
I.H. Song 《Thin solid films》2007,515(19):7598-7602
This paper is a report on the effect of a single perpendicular grain boundary on the hot-carrier and high current stability in high performance polycrystalline silicon (poly-Si) thin film transistors (TFTs). Under a hot carrier stress condition (Vg = Vth + 1 V, Vd = 12 V), the poly-Si TFT with a single grain boundary is superior to the poly-Si without any grain boundary because of the smaller free carriers available for electric conduction. The shift of transconductance in poly-Si TFT with a single grain boundary is less than 5% after hot carrier stress during a period of 1000 s. The shift of transconductance is about 25% in the case of the poly-Si TFTs without a grain boundary in the channel. On high current stress, the poly-Si TFT without the grain boundary is less degraded than the poly-Si TFT with the grain boundary because the concentrated electric field near the drain junction is lower. 相似文献
127.
We analyze the non-Fermi liquid behavior in the proximity of the quantum phase transition induced by the strong polarization of the electrons due to local magnetic moments in Ni x Pd1-x alloys. We use the renormalization group approach introduced by Hertz–Mi11is–Moriya (HMM) to estimate the temperature dependence of the electrical resistivity for the case of three dimensional itinerant ferromagnets. We study two different cases, namely, the clean and disordered ferromagnets, and argue that at the present time more experimental data are needed to decide if the HMM theory can accurately describe the physical properties in Ni x Pd1-x alloys. 相似文献
128.
Fine particles of cadmium carbonate (CdCO3) were prepared by heating aqueous solutions containing dissolved urea and cadmium sulfate at 85°C for 1 h. Effect of the composition of the reactant mixture on the morphology of the precipitated particles was investigated. It was found that the cadmium sulfate content of the reactant mixture significantly affected the shape and size of the precipitated particles. At certain range of reactant mixture composition, cauliflower-shaped uniform particles were obtained. The later particles were coated with basic copper carbonate (Cu2(OH)2CO3) by heating aqueous dispersions, containing CdCO3 particles, copper (II) nitrate, and urea at 85°C for various periods of time with constant stirring. The coating process was found sensitive to the experimental conditions and in most of the trials; mixtures of the coated and coating precursor particles were obtained. As such, extensive optimizations were carried out and conditions were established for the production of uniformly coated particles.On calcination at 700°C for 1 h, the CdCO3 particles converted into CdO, whereas the coated particles (CdCO3
(core)/Cu2(OH)2CO3
(coating) transformed into CdO(core)/CuO(coating)) without sintering. In the coated particles, the core and coating materials stayed mutually inert during the calcination reaction and independently converted into their respective oxides.All the calcined and uncalcined products were characterized by various physical and chemical methods. 相似文献
129.
130.