The vehicle routing problem with restricted mixing of deliveries and pickups

The vehicle routing problem with deliveries and pickups is one of the main problems within reverse logistics. This paper focuses on an important assumption that divides the literature on the topic, namely the restriction that all deliveries must be completed before pickups can be made. A generalised model is presented, together with a mathematical formulation and its resolution. The latter is carried out by adopting a suitable implementation of the reactive tabu search metaheuristic. Results show that significant savings can be achieved by allowing a mixture of delivery and pickup loads on-board and yet not incurring delays and driver inconvenience.     

P distribution in different sediment fraction of a constructed wetland

The aim of this work was to study the accumulation and fractionation of P in the inlet and outlet sediment of a constructed wetland for the wastewater treatment of a metallurgic plant in Argentina. It was important to predict whether P could be released into the water again by changing environmental conditions or retained over time. P-fractionation was performed using a sequential extraction method. Sediment cores were sliced at depths of: 0-3; 3-7 and 7-10 cm. Sediment showed high pH values and anoxic conditions. In the inlet area, P was principally bound to the carbonate fraction, whereas in the outlet area, it was mainly bound in the residual fraction. This behavior was justified by the effluent composition, which is rich in Ca2+ and Fe3+ and presents high values of pH and conductivity. These conditions favor CaCO3 and Fe(OOH)n precipitation and the subsequent sorption of P to their surface. The sediment active layer involved in the exchange reactions was the superficial one (0-3 cm). The wetland is highly efficient in P retention. P was retained by sediment in fractions that will not release it to the water while chemical and environmental conditions of the system are maintained.     

Distributed Latency-Energy Minimization and interference avoidance in TDMA Wireless Sensor Networks

This paper presents Latency-Energy Minimization Medium Access (LEMMA), a new TDMA-based MAC protocol for Wireless Sensor Networks (WSNs), specially suited to extend the lifetime of networks supporting alarm-driven, delay-sensitive applications characterized by convergecast traffic patterns and sporadic traffic generation. Its cascading time-slot assignment scheme conciliates low end-to-end latency with a low duty-cycle, while supporting multi-sink WSN topologies. Unlike most of the current solutions, LEMMA’s time-slot allocation protocol makes decisions based on the interference actually experienced by the nodes, instead of following the simple but potentially ineffective n-hop approach. Simulation results are presented to demonstrate the ineffectiveness of the n-hop time-slot allocation in comparison with LEMMA, as well as to evaluate the performance of LEMMA against L-MAC, T-MAC and Low Power Listening. The results show that under the target scenario conditions, LEMMA presents lower interference between assigned time-slots and lower end-to-end latency, while matching its best contender in terms of energy-efficiency.     

Optimum design of long-span suspension bridges considering aeroelastic and kinematic constraints

Cable supported bridges are wind prone structures. Therefore, their aerodynamic behaviour must be studied in depth in order to guarantee their safe performance. In the last decades important achievements have been reached in the study of bridges under wind-induced actions. On the other hand, non-conventional design techniques such as sensitivity analysis or optimum design have not been applied although they have proved their feasibility in the automobile or aeronautic industries. The aim of this research work is to demonstrate how non-conventional design techniques can help designers when dealing with long span bridges considering their aeroelastic behaviour. In that respect, the comprehensive analytical optimum design problem formulation is presented. In the application example the optimum design of the challenging Messina Strait Bridge is carried out. The chosen initial design has been the year 2002 design proposal. Up to a 33% deck material saving has been obtained after finishing the optimization process.     

On a novel interpretation of PVC antiplasticization based on some local chain conformations

Summary The transition of a poly(vinyl chloride) after either nucleophilic substitution to various extents or plasticization with distinct amounts of diocytl phthalate has been measured by Dynamical Mechanical Thermal Analysis. Both sets of experiments are shown to result in similar loss of transition. The results are argued in the light of prior work on the substitution mechanism determining role of the mmr chain segments at the end of isotactic sequences. They strongly suggest the mmr structures to interact specifically with plasticizer thereby becoming stiffer (antiplasticization).     

Plasma-enhanced fluorination of YBa2Cu3O7−δ ceramics

The radiofrequency plasma technique involving mixtures of CF₄+O₂ gases has been applied to the surface treatment of high T_c superconducting oxides (YBa₂Cu₃O_7–). Investigation of the various experimental parameters of the process has shown that the improvement of the critical current density, J _c, mainly depends on the inlet precursor composition CF₄+%O₂, on the total pressure and on the reaction time. The presence of fluorine in the bulk of the ceramics has been observed from electron microprobe analysis, together with an increase of the Cu³⁺ content. The plasma-enhanced fluorination (PEF) treatment improves the superconducting properties of the materials: both values of the resistivity in the normal state and of the superconducting transition width are reduced and the critical transition temperature is improved by about 1 K.     

Phosphofructokinase from mantle tissue of Mytilus galloprovincialis. Purification and effects of phosphorylation on the enzymatic activity

Phosphofructokinase purified from mantle tissue of the sea mussel Mytilus galloprovincialis, was phosphorylated "in vitro" by the catalytic subunit of cyclic AMP-dependent protein kinase. The incorporation of phosphate gave rise to an activation of the enzyme by increasing its affinity for fructose-6-phosphate, by decreasing its sensitivity to the inhibition by ATP and by enhancing the effect of allosteric activators (5'-AMP and fructose-2,6-bisphosphate). In addition, the effects of phosphorylation on the catalytic activity are pH-dependent.     

Valence band density of states of small cobalt particles on Si(111) substrate

Small Co particles were prepared by sputter etching of a 4–5 nm thick island-like Co film deposited on Si(111) substrate. The density of states (DOS) of the valence band was measured by means of ultraviolet photoemission (UPS) during the sputter etching to monitor the formation of small Co particles. It was found that at a given thickness of the Co island the Fermi level was shifted by 1.8-1.9 eV toward higher binding energy and theDOS decreased or no states were detectable at the Fermi level. This effect was explained by the formation of small Co particles with electronic structure which is significantly different from that of the bulk Co.     

Synthesis, Structure and Antitumour Properties of a New 1,2-Propylenediaminetetraacetate-Ruthenium(III) Compound

A novel complex formed by ruthenium (III) and the sequestering ligand 1,2-propylenediaminetetraacetic acid (PDTA) has been synthetized and characterized. The structure of the monomeric compound, studied by X-ray diffraction , shows an almost symmetric octahedral geometry around the metal ion, with two chlorine atoms in a cis conformation. The antitumour activity against a variety of murine and human cancers is reported.