Recovery of Phosphoric Acid from Spent Petrochemical Catalysts

Petrochemical catalysts are widely used in the industry. For the production of cumene, zeolite-based catalysts containing phosphoric acid are applied. Over the time, coking deactivates the surface, and the catalyst has to be exchanged and disposed of. Different process approaches for recycling the phosphoric acid-containing catalysts were investigated. Related preliminary investigations have shown that calcination of the used catalyst is necessary prior to reprocessing. By digesting the catalyst with hydrofluoric acid, ∼96 % phosphate was recovered. However, this process is very costly in terms of process technology. More promising is digestion by basic or acidic routes. Several options are possible here, and digestion with H₃PO₄ proved to be particularly suitable. Here, phosphate yields reached up to 98.8 %, with a positive balance of economic efficiency at the same time. The catalyst can be produced and recycled in the same plant with the same reagents, what constitutes a major breakthrough towards sustainability in industrial catalysis.     

Copper diffusion into silicon substrates through TaN and Ta/TaN multilayer barriers

A study of copper (Cu) diffusion into silicon substrates through Ta nitride (TaN) and tantalum (Ta/TaN) layers was investigated based on an experimental approach. TaN _x and Ta/TaN _x thin films were deposited by radiofrequency sputtering under argon (Ar) and Ar-nitrogen (N) plasma. The influence of the N₂ partial pressure on the microstructure and the electrical properties is reported. X-ray diffraction patterns showed that the increase of the N₂ partial pressure, from 2 to 10.7%, induces a change in the composition of the δTaN phase, from TaN to TaN_1.13, as well as an evolution of the dominant crystallographic orientation. This composition change is related to a drastic increase of the electrical resistivity over a N₂ partial pressure of 7.3%. The efficiency of TaN layers and Ta/TaN multilayer diffusion barriers was investigated after annealing at temperatures between 600 and 900 °C in vacuum. Secondary ion mass spectrometry profiles showed that Cu diffuses from the surface layer through the TaN barrier from 600 °C. Cu diffusion mechanisms are modified in the presence of a Ta sublayer. This article was presented at the Multicomponent-Multiphase Diffusion Symposium in Honor of Mysore A. Dayananda, which was held during TMS 2006, the 135th Annual Meeting and Exhibition, March 12–16, 2006, in San Antonio, TX. The symposium was organized by Yongho Sohn of the University of Central Florida, Carelyn E. Campbell of National Institute of Standards and Technology, Richard D. Sisson, Jr., of Worcester Polytechnic Institute, and John E. Morral of Ohio State University.     

Towards the generation of dialogue acts in socio-affective ECAs: a corpus-based prosodic analysis

We present a corpus-based prosodic analysis with the aim of uncovering the relationship between dialogue acts, personality and prosody in view to providing guidelines for the ECA Greta’s text-to-speech system. The corpus used is the SEMAINE corpus, featuring four different personalities, further annotated for dialogue acts and prosodic features. In order to show the importance of the choice of dialogue act taxonomy, two different taxonomies were used, the first corresponding to Searle’s taxonomy of speech acts and the second, inspired by Bunt’s DIT++, including a division of directive acts into finer categories. Our results show that finer-grained distinctions are important when choosing a taxonomy. We also show with some preliminary results that the prosodic correlates of dialogue acts are not always as cited in the literature and prove more complex and variable. By studying the realisation of different directive acts, we also observe differences in the communicative strategies of the ECA depending on personality, in view to providing input to a speech system.     

3D resistive RAM cell design for high-density storage class memory—a review

In this article, we comprehensively review recent progress in the ReRAM cell technology for 3D integration focusing on a material/device level. First we briefly mention pioneering work on high-density crossbar ReRAM arrays which paved the way to 3D integration. We discuss the two main proposed 3D integration schemes—3D horizontally stacked ReRAM vs 3D Vertical ReRAM and their respective advantages and disadvantages. We follow with the detailed memory cell design on important work in both areas, utilizing either filamentary or interface-limited switching mechanisms. We also discuss our own contributions on HfO₂-based filamentary 3D Vertical ReRAM as well as TaO_x/TiO₂ bilayer-based self-rectifying 3D Vertical ReRAM. Finally, we summarize the present status and provide an outlook for the nearterm future.     

Massively parallel Lucas Kanade optical flow for real-time video processing applications

This paper deals with dense optical flow estimation from the perspective of the trade-off between quality of the estimated flow and computational cost which is required by real-world applications. We propose a fast and robust local method, denoted by eFOLKI, and describe its implementation on GPU. It leads to very high performance even on large image formats such as 4 K (3,840 × 2,160) resolution. In order to assess the interest of eFOLKI, we first present a comparative study with currently available GPU codes, including local and global methods, on a large set of data with ground truth. eFOLKI appears significantly faster while providing quite accurate and highly robust estimated flows. We then show, on four real-time video processing applications based on optical flow, that eFOLKI reaches the requirements both in terms of estimated flows quality and of processing rate.     

QoS aggregation for service orchestrations based on workflow pattern rules and MCDM method: evaluation at design time and runtime

Service consumers satisfaction is considered today as one of the main concern to be ensured by service providers, especially with the spread of concurrency and the increase of functionally equivalent services. This satisfaction is closely related to quality of service (QoS) perceived by service consumers. In this context, we propose an approach to determine the satisfaction degree corresponding to the QoS of service-based applications, with regard to service consumers’ QoS expectations. Our approach is based on a preference model, which is built only on the basis of service consumer’s provided information. This preference model is also based on the 2-additive Choquet operator that takes into account preferential dependencies. In this paper, we target both design time and runtime aggregation of QoS of service-based applications.