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111.
112.
Chemically Resistant,Shapeable, and Conducting Metal‐Organic Gels and Aerogels Built from Dithiooxamidato Ligand 下载免费PDF全文
Daniel Vallejo‐Sánchez Pilar Amo‐Ochoa Garikoitz Beobide Oscar Castillo Michael Fröba Frank Hoffmann Antonio Luque Pilar Ocón Sonia Pérez‐Yáñez 《Advanced functional materials》2017,27(15)
Metal‐organic gels (MOGs) appear as a blooming alternative to well‐known metal‐organic frameworks (MOFs). Porosity of MOGs has a microstructural origin and not strictly crystalline like in MOFs; therefore, gelation may provide porosity to any metal‐organic system, including those with interesting properties but without a porous crystalline structure. The easy and straightforward shaping of MOGs contrasts with the need of binders for MOFs. In this contribution, a series of MOGs based on the assembly of 1D‐coordination polymer nanofibers of formula [M(DTA)]n (MII: Ni, Cu, Pd; DTA: dithiooxamidato) are reported, in which properties such as porosity, chemical inertness, mechanical robustness, and stimuli‐responsive electrical conductivity are brought together. The strength of the M? S bond confers an unusual chemical resistance, withstanding exposure to acids, alkalis, and mild oxidizing/reducing chemicals. Supercritical drying of MOGs provides ultralight metal‐organic aerogels (MOAs) with densities as low as 0.03 g cm?3 and plastic/brittle behavior depending on the nanofiber aspect ratio. Conductivity measurements reveal a semiconducting behavior (10?12 to 10?7 S cm?1 at 298 K) that can be improved by doping (10?5 S cm?1). Moreover, it must be stressed that conductivity of MOAs reversibly increases (up to 10?5 S cm?1) under the presence of acetic acid. 相似文献
113.
Implant Materials: Assessment of Novel Long‐Lasting Ceria‐Stabilized Zirconia‐Based Ceramics with Different Surface Topographies as Implant Materials (Adv. Funct. Mater. 40/2017) 下载免费PDF全文
114.
Tommaso Marchesi D'Alvise Sean Harvey Lisa Hueske Jolanta Szelwicka Lothar Veith Tuomas P. J. Knowles Dennis Kubiczek Carolin Flaig Fabian Port Kay‐E. Gottschalk Frank Rosenau Bartlomiej Graczykowski George Fytas Francesco S. Ruggeri Katrin Wunderlich Tanja Weil 《Advanced functional materials》2020,30(21)
Cellular membranes have long served as an inspiration for nanomaterial research. The preparation of ultrathin polydopamine (PDA) films with integrated protein pores containing phospholipids and an embedded domain of a membrane protein glycophorin A as simplified cell membrane mimics is reported. Large area, ultrathin PDA films are obtained by electropolymerization on gold surfaces with 10–18 nm thickness and dimensions of up to 2.5 cm2. The films are transferred from gold to various other substrates such as nylon mesh, silicon, or substrates containing holes in the micrometer range, and they remain intact even after transfer. The novel transfer technique gives access to freestanding PDA films that remain stable even at the air interfaces with elastic moduli of ≈6–12 GPa, which are higher than any other PDA films reported before. As the PDA film thickness is within the range of cellular membranes, monodisperse protein nanopores, so‐called “nanodiscs,” are integrated as functional entities. These nanodisc‐containing PDA films can serve as semi‐permeable films, in which the embedded pores control material transport. In the future, these simplified cell membrane mimics may offer structural investigations of the embedded membrane proteins to receive an improved understanding of protein‐mediated transport processes in cellular membranes. 相似文献
115.
Katrin Ortstein Sebastian Hutsch Alexander Hinderhofer Jrn Vahland Martin Schwarze Sebastian Schellhammer Martin Hodas Thomas Geiger Hans Kleemann Holger F. Bettinger Frank Schreiber Frank Ortmann Karl Leo 《Advanced functional materials》2020,30(32)
In modern electronics, it is essential to adapt band structures by adjusting energy levels and band gaps. At first sight, this “band structure engineering” seems impossible in organic semiconductors, which usually exhibit localized electronic states instead of Bloch bands. However, the strong Coulomb interaction in organic semiconductors allows for a continuous shift of the ionization energy (IE) over a wide range by mixing molecules with halogenated derivatives that exhibit different quadrupole moments. Here, this effect of energy level engineering on blends of pentacene and two fluorinated derivatives, in which the position but not the number of fluorine atoms differ, is studied. Structural investigations confirm that pentacene forms intermixed phases in blends with the fluorinated species. The investigation of electronic properties and simulations reveals a much larger shift of the ionization energy (1.5 eV) than in previous studies, allowing to test this model in a range not investigated so far, and emphasizing the role of the position of the halogen atoms. The tuning effect is preserved in electronic devices such as field‐effect transistors and significantly influences device characteristics. 相似文献
116.
适用性 使用丝网印刷的方法对晶圆表面施涂聚酰亚胺保护层相对于传统的旋转-蚀刻工艺技术具有效率和成本的优势.丝网印刷晶圆表面保护只需要两步工序(印刷和固化),而旋转-蚀刻工艺需要七步或更多的工序. 相似文献
117.
Emission Reduction and Capacity Increase in GSM Networks by Single Antenna Interference Cancellation
Stefan Brueck Hans-Juergen Kettschau Frank Obernosterer 《AEUE-International Journal of Electronics and Communications》2004,58(4):274-283
There is an increasing demand to utilize the frequency spectrum of mobile communication systems most efficiently. This means in particular to GSM networks that the frequency reuse shall be planned as low as possible. In this case the system may become limited by interference rather than coverage. One promising technology for GSM mobiles in interference-limited systems is single antenna interference cancellation (SAIC). This receiver technology allows both for increasing the network capacity and for reducing the base station transmit power. The aim of this paper is to assess the emission reduction as well as the system capacity capabilities when SAIC technology is applied in downlink receivers. 相似文献
118.
119.
Petr Kovaricek Peter Nadazdy Eva Pluharova Alica Brunova Riyas Subair Karol Vegso Valentino Libero Pio Guerra Oleksandr Volochanskyi Martin Kalbac Alexander Krasnansky Pallavi Pandit Stephan Volker Roth Alexander Hinderhofer Eva Majkova Matej Jergel Jianjun Tian Frank Schreiber Peter Siffalovic 《Advanced functional materials》2021,31(13):2009007
2D hybrid organic–inorganic perovskites are valued in optoelectronic applications for their tunable bandgap and excellent moisture and irradiation stability. These properties stem from both the chemical composition and crystallinity of the layer formed. Defects in the lattice, impurities, and crystal grain boundaries generally introduce trap states and surface energy pinning, limiting the ultimate performance of the perovskite; hence, an in-depth understanding of the crystallization process is indispensable. Here, a kinetic and thermodynamic study of 2D perovskite layer crystallization on transparent conductive substrates are provided—fluorine-doped tin oxide and graphene. Due to markedly different surface structure and chemistry, the two substrates interact differently with the perovskite layer. A time-resolved grazing-incidence wide-angle X-ray scattering (GIWAXS) is used to monitor the crystallization on the two substrates. Molecular dynamics simulations are employed to explain the experimental data and to rationalize the perovskite layer formation. The findings assist substrate selection based on the required film morphology, revealing the structural dynamics during the crystallization process, thus helping to tackle the technological challenges of structure formation of 2D perovskites for optoelectronic devices. 相似文献
120.
Jun Zhang Patrick Byers Amelie Erben Christine Frank Levin Schulte-Spechtel Michael Heymann Denitsa Docheva Heinz P. Huber Stefanie Sudhop Hauke Clausen-Schaumann 《Advanced functional materials》2021,31(19):2100066
Tissue engineering requires the precise positioning of mammalian cells and biomaterials on substrate surfaces or in preprocessed scaffolds. Although the development of 2D and 3D bioprinting technologies has made substantial progress in recent years, precise, cell-friendly, easy to use, and fast technologies for selecting and positioning mammalian cells with single cell precision are still in need. A new laser-based bioprinting approach is therefore presented, which allows the selection of individual cells from complex cell mixtures based on morphology or fluorescence and their transfer onto a 2D target substrate or a preprocessed 3D scaffold with single cell precision and high cell viability (93–99% cell survival, depending on cell type and substrate). In addition to precise cell positioning, this approach can also be used for the generation of 3D structures by transferring and depositing multiple hydrogel droplets. By further automating and combining this approach with other 3D printing technologies, such as two-photon stereolithography, it has a high potential of becoming a fast and versatile technology for the 2D and 3D bioprinting of mammalian cells with single cell resolution. 相似文献