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11.
The conversion of a number of alcohols, ethers, ketones, aldehydes, carboxylic acids, esters, and cyclic compounds and their mixtures on H-ZSM-5 at 673 K was investigated. These compounds can be easily converted to aromatic hydrocarbons if the C/H ratio of the molecule fragment, remaining after elimination of oxygen as water, is less than 0.62. At higher C/H ratios, coking of the catalyst increases, thus reducing its lifetime, a difficulty which can be overcome by hydrogenation of these compounds prior to their conversion over H-ZSM-5. A procedure is proposed for converting at least a part of organic waste chemicals to valuable products instead of burning them. 相似文献
12.
13.
Foued Ameur Paul Fischer Klaus-U. Höffgen Friedhelm Meyer auf der Heide 《Acta Informatica》1996,33(7):621-630
A pac-learning algorithm is -space bounded, if it stores at most examples from the sample at any time. We characterize the -space learnable concept classes. For this purpose we introduce the compression parameter of a concept class and design our Trial and Error Learning Algorithm. We show : is -space learnable if and only if the compression parameter of is at most . This learning algorithm does not produce a hypothesis consistent with the whole sample as previous approaches e.g. by Floyd,
who presents consistent space bounded learning algorithms, but has to restrict herself to very special concept classes. On
the other hand our algorithm needs large samples; the compression parameter appears as exponent in the sample size. We present
several examples of polynomial time space bounded learnable concept classes: – all intersection closed concept classes with
finite VC–dimension. – convex -gons in . – halfspaces in . – unions of triangles in . We further relate the compression parameter to the VC–dimension, and discuss variants of this parameter.
Received May 24, 1994 / July 4, 1995 相似文献
14.
Auslagerungsversuche mit verschiedenen geschweißten und verspannten Proben aus den chromhaltigen austenitischen Manganstählen X 40 MnCrN 19 und X 12 MnCr 18 12 sowie dem chromfreien Stahl X 50 Mn 20 in Meerwasser der Nord- und Ostsee. Makroskopische und mikroskopische Beurteilung der Proben nach sechs Wochen, einem halben Jahr, einem Jahr und zwei Jahren hinsichtlich Beständigkeit gegen unterschiedliche Korrosionserscheinungen, besonders hinsichtlich transkristalliner Spannungsrißkorrosion. 相似文献
15.
Friedhelm Meyer auf der Heide 《Theoretical computer science》1981,13(3):315-322
The number of pebbles used in the black [black-white] pebble game corresponds to the storage requirement of the deterministic [non-deterministic] evaluation of a straight line program. Suppose a distinguished vertex of a directed acyclic graph can be pebbled with k pebbles in the black-white pebble game. Then it can be pebbled with k′≤1/2k(k?1)+1 pebbles in the black pebble game. 相似文献
16.
Christophe Serra Guy Schlatter Nicolas Sary Friedhelm Schönfeld Georges Hadziioannou 《Microfluidics and nanofluidics》2007,3(4):451-461
This paper investigates the modeling of styrene free radical polymerization in two different types of microreactor. A multiphysics
model which simultaneously takes into account the hydrodynamics, thermal and mass transfer (convection, diffusion and chemical
reaction) is proposed. The set of partial differential equations resulting from the model is solved with the help of the finite
elements method either in a 2D or a 3D approach. The different modeled microreactors are on one hand an interdigital multilamination
microreactor with a large focusing section, and on the other hand a simple T-junction followed by a straight tube with three
different radii. The results are expressed in terms of reactor temperature, polydispersity index, number-average degree of
polymerization and monomer conversion for different values of the chemical species diffusion coefficient. It was found that
the 2D approach gives the same results as the 3D approach but allows to dramatically reduce the computing time. Despite the
heat released by the polymerization reaction, it was found that the thermal transfer in such microfluidic devices is high
enough to ensure isothermal conditions. Concerning the polydispersity index, the range of diffusion coefficients over which
the polydispersity index can be maintained close to the theoretical value for ideal conditions increases as the tube reactor
radius decreases. The interdigital multilamination microreactor was found to act as a tubular reactor of 0.78 mm ID but with
a shorter length. This underlines that the use of microfluidic devices can lead to a better control of polymerization reactions. 相似文献
17.
Pentachlorophenylethers (PCP-ethers) of cellulose are prepared using cellulosetosylates as intermediates. The products release no measurable quantities of PCP into buffered solutions (pH 4, 7, and 9, resp.). However, the modified cellulose shows no fungicidal effect in agar plate tests with the usually cellulose-metabolizing fungus, Trichoderma viride. The lack of biological activity is attributed to the stability of the cellulose pentachlorophenyl ether bond. 相似文献
18.
Friedhelm Hase 《Datenschutz und Datensicherheit - DuD》2011,35(12):875-878
19.
Karl Friedhelm Fischer 《Planning Perspectives》2013,28(1):85-93
Berlin — myth and model: on the production of German planning ideology in Berlin. Mythos Berlin. (Exhibition catalogue)1 Berlin, 1987. ISBN 3 88245 147 5. Mythos Berlin. (Concepte)2 Berlin, 1986. ISBN 3 88245 139 4. Die Zukunft der Metropolen: Paris ? London ? New York ? Berlin. (Exhibition catalogue) (3 Volumes) Berlin, 1984. ISBN 3 496 00805 9. Weltstadt Berlin. Ilse Balg (Ed.), Galerie Wannsee Verlag, Berlin, 1986. Platz frei für das Neue Berlin! Geschichte der Stadterneuerung in der ‘größten Mietskasernenstadt der Welt’ seit 1871. Harald Bodenschatz, Transit‐Verlag, Berlin, 1987. 288 pp, DM48, ISBN 3 887 47038 9. 相似文献
20.
The effects of metal exchange between zeolites and alkali metals (Li, Na, K; zeolite Y, ZSM-5, T), alkaline earths (Mg, Ca, Sr, Ba; ZSM-5), transition metals (La, Ce, Cr, Mn, Fe, Co, Ni, Pd, Cu, Zn; ZSM-5) and aluminium (ZSM-5) on the conversion of ethanol were studied. Activities of the catalysts and selectivities for ethene, C3+ olefins, paraffins and arenes strongly depended on the cation, chosen for the modification. Only ethene was formed by alkali exchanged zeolites, the most active being Li-Y. This could be confirmed by a long-term ageing test with Li-Y pellets under semi-industrial conditions. The exchange of ZSM-5 with alkaline earths or transition metals permitted the formation of a wide variety of products, raning from high ethene to high aromatic yields. A correlation between certain product selectivities and electronegativity was only possible in a rough approximation. 相似文献