Syngas production via combined oxy-CO2 reforming of methane over Gd2O3-modified Ni/SiO2 catalysts in a fluidized-bed reactor

In this research, Ni/SiO₂ catalyst was modified with different amount of Gd₂O₃ and characterized with temperature-programmed desorption of CO₂ (CO₂-TPD) and NH₃ (NH₃-TPD), temperature-programmed reduction with H₂ (H₂-TPR) and X-ray diffraction (XRD). It was found that Gd₂O₃-modified Ni/SiO₂ catalysts possessed higher CO₂ adsorption and activation ability due to the formation of surface carbonate species. H₂-TPR and XRD characterizations found that the strong interaction among nickel, Gd₂O₃ and SiO₂ took place, which improved the dispersion of Ni. Gd₂O₃-modified Ni/SiO₂ catalysts exhibited higher activity and stability for the combined oxy-CO₂ reforming of methane in fluidized-bed reactor. The H₂/CO ratio in produced syngas could be controlled via controlling reaction temperature and CO₂/O₂ ratio in feed.     

Accelerated wear testing with a microfabricated surface to evaluate the lubrication ability of biomolecules on polyethylene

Wear of ultrahigh‐molecular‐weight polyethylene (UHMWPE) and wear‐particle‐induced osteolysis and bone resorption are the major factors causing the failure of total joint replacements. It is feasible to improve the lubrication and reduce the wear of artificial joints. We need further understanding of the lubrication mechanism of the synovial fluid. The objective of this study is to evaluate the lubricating ability of three major components in the synovial fluid: albumin, globulin, and phospholipids. An accelerated wear testing procedure in which UHMWPE is rubbed against a microfabricated surface with controlled asperities has been developed to evaluate the lubrication behavior. An analysis of the wear particle dimensions and wear amount of the tests has provided insights for comparing their lubrication performance. It is concluded that the presence of biomolecules at the articulating interface may reduce friction. A higher concentration of a biological lubricant leads to a decrease in the wear particle width. In addition, in combination with the wear results and mechanical analysis, the roles of individual biomolecules contributing to friction and wear at the articulating interface are discussed. These results can help us to identify the role of the biomolecules in the boundary lubrication of artificial joints, and further development of lubricating additives for artificial joints may be feasible. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

深圳市某商住楼通风空调设计

本文简要介绍深圳某商住楼通风空调系统、水系统的设计及空调方式的选取、简述了各项设计的技术数据,可供同行参考。     

Self-assembly of highly oriented palladium-based nanowires on mica surface

The self-assembly of various nanostructures is recently attracting a great deal of research attention. In this paper, we demonstrate that a palladium chloride aqueous solution, mixed with a proper ammonia solution, can produce Tetra-amminepalladous chloride (Pd(NH₃)₄Cl₂·H₂O) nanowires. These nanowires can spontaneously form the two-dimensional hexagon-oriented Pd(NH₃)₄Cl₂·H₂O arrays on mica surfaces. We can control the length and height of these nanowires by adjusting their deposit time on the mica substrate. This method can be potentially used in making sensors or in making templates to wire and position nanodevices.     

Study on Reduction of Sulfur Content in FCC Gasoline

Reduction of sulfur content in FCC gasoline was studied in a fixed fluid bed (FFB) unit by using metal-modified LV-23 FCC catalyst. The results showed that the sulfur content in FCC gasoline could be reduced with LV-23 catalyst modified with zinc, palladium, zinc-palladium, zinc-cobalt, and zinc-nickel. Among these metals or metal combinations, palladium-containing catalyst was the most effective. Desulfufization of the heavy fraction of FCC gasoline was more effective than full-range gasoline under the same conditions with palladium-containing catalysts. A high reaction temperature was favorable to desulfurization, but it would reduce the yield of liquid product. After desulfurization reaction, the olefm content of product gasoline decreased while the aromatic and iso-alkane contents increased. Removal of thiophene and benzothiophene is higher.     

Nonlinear Thermal Analysis for Qing-Tibet Railway Embankments in Cold Regions

Heat convection in ballast mass in railway embankments is a problem of heat convection in porous media. In order to calculate the temperature distribution of the Qing-Tibet railway embankment from the governing equations used to study forced convection for incompressible fluids porous media, detailed finite-element formulas for heat convection in porous media are derived using Galerkin’s method. The temperature distributions on central lines of the traditional railway embankment, the ripped-rock embankment, and the ripped-rock revetment embankment that were constructed on July 15, 2002 have been analyzed and compared on July 15, October 15 in the 24th year after construction, and January 15 in the 25th year after construction under the climatic and geological conditions on the Qing-Tibet Railway. The calculated results indicate that the traditional railway embankment will raise the permafrost temperature under the embankment base and make the permafrost embankment thermally unstable. The ripped-rock embankment and the ripped-rock revetment embankment will reduce the permafrost temperature under the embankment base in cold regions, therefore maintaining the thermal stability of permafrost. However, the ripped-rock embankment needs more rock mass while the ripped-rock revetment embankment need less rock mass, and its construction cost is lower than that of the former. Therefore, it is highly recommended that the ripped-rock revetment embankment be used for the Qing-Tibet railway embankment structure in high temperature permafrost regions so that the permafrost embankment can be protected as much as possible.     

光纤光栅视觉系统

利用光学衍射原理，研制成了光纤光栅衍射屏，并与计算机神经网络相结合，开发了了一种识别立体形状的视觉系统。本文介绍了光纤光栅的设计原理及计算方法，给出了系统的总体结构及工作原理，完成了三棱 柱，三棱锥、四棱柱，四棱锥和球等立体形状学习与识别，并讨论了实验结果。     

Characterization of proton-exchanged optical waveguides in ZnO:LiNbO3

We report the first demonstration of proton-exchanged optical planar waveguides in x-cut and z-cut LiNbO₃ doped with 6 mol% ZnO using adipic acid as proton source. These waveguides exhibit a graded index profile which can be modeled by a linear step function with a surface index increase of 0.135 and 0.14 for x-cut and z-cut waveguides, respectively. The diffusion constant D_o and the activation energy Q are characterized optically to be 1.64×10⁹ μm²/h and 88.8 KJ/mol for x-cut waveguides, and 1.478×10⁹ μm²/h and 91.25 KJ/mol for z-cut waveguides, respectively. The diffusion rate along the z-axis is slower than that along the x-axis, whereas the surface index increase on z-cut waveguides is larger than that on x-cut waveguides.     

本钢烧结矿冷却及其余热回收的试验研究

从烧结矿冷却并回收其余热的角度出发，介绍了利用烧结机尾落矿空间，采用喷吹空气装置对烧结矿进行冷却的小型模拟试验，从测出的结果来看，有可能成为一种新的烧结矿冷却方式。