A formation of compatible poly(vinyl alcohol)/alumina gel composite and its properties

A formation of poly(vinyl alcohol) (PVA)/alumina gel composite was investigated with a viewpoint of compatibility of the composite. An alumina sol was prepared from aluminium iso-propoxide (Al(iPro)₃). The alkoxide was hydrolyzed and the resultant hydrate was peptized to a clear sol with acetic acid. The composite were transparent in whole content of alumina. The effects of dispersed alumina on the sorption of water and mechanical properties of composite were examined. The composites containing PVA 40–50% are flexible. They are folded in various forms and can be drawn five times the initial length in humid state. The residues obtained by calcination to remove PVA at 600°C keep its original form and transparency.     

Effect of deformation mode,dynamic recrystallization and twinning on rolling texture evolution of AZ31 magnesium alloys

In order to obtain quantitative relationship between (0002) texture intensity and hot rolling conditions, conventional rolling experiments on AZ31 magnesium alloys were performed with 20%–40% reductions and temperatures within the range of 300–500 °C. Shear strain and equivalent strain distributions along the thickness of the rolled sheets were calculated experimentally using embedded pin in a rolling sheet. Rolling microstructures and textures in the sheet surface and center layers of the AZ31 alloys were measured by optical microscopy (OM), X-ray diffractometry (XRD) and electron back scatter diffraction (EBSD). Effects of the rolling strain, dynamic recrystallization (DRX) and twinning on the texture evolution of the AZ31 alloys were investigated quantitatively. It is found that the highest (0002) basal texture intensities are obtained at a starting rolling temperature of 400 °C under the same strain. Strain–temperature dependency of the (0002) texture intensity of the AZ31 alloy is derived.     

Several Geotechnical Design and Construction Issues with Akashi Strait Bridge

The Akashi Kaikyo (Strait) Bridge, one of the major bridges of the Honshu-Shikoku bridge network connecting the main island and the Shikoku island, is the world's longest suspension bridge with a center span of about 2,000 m. The bridge was constructed over the Akashi Strait and opened to traffic in 1998 after a construction period of about 10 years. The granite stratum in the Akashi Strait was very deep, while the granite stratum provides the foundations for the other long span bridges which have been constructed in Japan. Three of the four foundations had to be constructed on either a weakly cemented gravelly soil deposit or a sedimentary soft rock layer. The geological structure was carefully investigated and the geotechnical properties, in particular the strength and deformation characteristics of these geomaterial types, were carefully evaluated. To this end, a comprehensive series of advanced triaxial compression (TC) tests were performed on rotary core tube samples of sedimentary soft rock after it was found that the due design was not possible based on unconfined compression tests. Both CD and CU TC tests and cyclic undrained triaxial tests were performed on rotary core tube samples (30 cm in dia.) of the gravelly soil. Based on the data, the long-term and seismic stabilities of the foundations were evaluated. The importance of strain- and pressure-dependent nonlinear stress-strain behaviour at small strains, as well as accurate strain measurements in the laboratory stress-strain tests, was confirmed by analyzing the full-scale behaviour of the foundation during and after construction and comparing the back-calculated stiffness values with those obtained from laboratory stress-strain tests, pressure-meter tests, plate loading tests and field shear wave velocity measurements.     

Tyrosine-based poly(m-phenyleneethynylene-p-phenyleneethynylene)s. Helix folding and responsiveness to a base

The Sonogashira-Hagihara polymerization of 3′,5′-diiodo-N-α-tert-butoxycarbonyl-l-tyrosine methyl ester (1) and 3′,5′-diiodo-N-α-tert-butoxycarbonyl-O-methyl-l-tyrosine methyl ester (2) with para-diethynylbenzene (3) was carried out to obtain optically active poly(m-phenyleneethynylene-p-phenyleneethynylene)s [poly(1) and poly(2)] with M_n’s ranging from 9900 to 15,000 in 80-87% yields. Poly(1) exhibited intense CD signals in DMSO and THF, but did not in CH₂Cl₂, indicating that it took a predominantly one-handed helical conformation in the former two solvents. On the other hand, there was no evidence for poly(2) to take a helical structure in these solvents. Poly(1) turned the CD sign at 390 nm from plus to minus in DMSO/H₂O = 9/1 (v/v) by the addition of NaOH. Alkaline hydrolysis of ester moieties of poly(1) and poly(2) gave the corresponding polymers having carboxy groups [poly(1a) and poly(2a)]. Poly(1a) and poly(2a) increased the CD intensity by the addition of NaOH.     

可持续发展实验住宅——日本积水住宅公司实验住宅案例介绍

可持续发展实验住宅是在东京城市住宅区中建设的一栋有研究性质的实验住宅,其宗旨是要通过充分利用风、阳光等自然的力量来实现不依赖于机械设备的节能而且舒适的生活.借鉴传统日本住宅的优点,创造重视居住者心理感受的生活环境,并通过居住实验证实了该住宅可以让居住者感受到比客观测定的物理环境值更具舒适性的居住品质.     

Optical and adhesive properties of composite silica-impregnated Ca-α-SiAlON:Eu2+ phosphor films prepared on silica glass substrates

The compaction of a Eu-doped Ca-α-SiAlON phosphor powder was performed by electrophoretic deposition (EPD). The effect on the adhesion and optical properties of the silica precursor as both a binder of the powder and a filler of the air voids were evaluated. The adhesion of the silica impregnated composite film to the silica glass substrate was characterized by the tape test. The improvement of the external quantum efficiency was confirmed from the PL spectra measurement after the silica impregnation. The temperature dependence of the external quantum efficiency was also investigated in order to discuss the advantage of using the silica precursor as a binder for high-brightness LED applications.     

From the Sup-Decomposition to Sequential Decompositions

W-operators are discrete set operators that are both translation invariant and locally defined within a finite window W. A particularly interesting property of W-operators is that they have a sup-decomposition in terms of a family sup-generating operators, that are parameterized by the operator basis. The sup-decomposition has a parallel structure that usually is not efficient for computation in conventional sequential machines. In this paper, we formalize the problem of transforming sup-decompositions into purely sequential decompositions (when they exist). The techniques were developed for general W-operators, specialized for increasing W-operators and applied on operators built by compositions of dilations and erosions.     

Improvement of poly(vinyl alcohol)/poly(vinylpyrrolidone) blended hydrogel by radiation crosslinking

1IntroductionHydrogelisapolymericmaterial(syntheticornaturaJ)whichswellswhenplacedincontactwithwaterbutisnotsolubleandhastheabililtytoretainwaterwithinitsstructare.InIecentyears,muchattentionhasbeenfocusedontheresearchanddevelopmentofthepolymerhydIogelsforbiomaterials,suchascontactlenses,wounddressing,enzymeimmunoassay,cathetersanddIugdeliverysystems[1~3].Adressingisoftencoveredonthewotmdtoaccelerateitshealing.TheIearetwokindsofdiessings:drytypeandwettype.Ithasbeenreportedthatheallngwithawe…     

Driving simulator experiment on the moving stability of an automobile under strong crosswind

In expanding expressway networks in Japan, various types of structures have been constructed, e.g., long span bridges and bridges with high piers. The expressway structures are well designed for the external dynamic forces, e.g., earthquakes and strong winds. However, for further safety promotion of the expressway networks, it is important to evaluate the drivers’ responses under strong dynamic disturbances. The present authors have investigated the moving stability of a vehicle under seismic motion based on both numerical simulation and virtual experiments using a driving simulator. Strong crosswind is considered as another factor that makes it difficult for drivers to control their vehicles. This study investigates the moving stability of a vehicle under strong crosswind based on numerical analyses and driving simulator experiments. To predict the future position of a moving vehicle including the reaction of a driver, the second-order predictable correction model is used in the numerical analyses. The results obtained from the numerical and experimental studies are compared and the validity of the driver model is discussed. It is expected that this research is helpful for the decision-making of expressway closure under strong wind and the design of wind barriers.