Thermodynamics of chemical and electrochemical stability of brasses

Based on the theory of “regular” solutions, the thermodynamic properties of α-, β-, γ-, ɛ-, and η-phases of the Cu-Zn system are described. The surface activity of the elements in the phases is assessed. Potential-pH diagrams for the general system Cu-Zn-H₂O and the manganese brass system H₂O at 25°C are plotted. The nature of passivating films on conventional and special brasses and their composition are elucidated in different pH and potential ranges.     

A Simulation Environment for e-Learning in Digital Design

Deeds is a simulation environment for e-learning in digital electronics. The simulators cover combinational and sequential logic networks, finite state-machine design, and microcomputer interfacing and programming. They are integrated together, and therefore allow the design and test of embedded digital systems. The environment guides students' activities by delivering learning materials through specialized browsers. An extensive collection of learning materials is available. This paper includes an example of activity on a problem assignment.     

Impacts of spectral band difference effects on radiometric cross-calibration between satellite sensors in the solar-reflective spectral domain

In order for quantitative applications to make full use of the ever-increasing number of Earth observation satellite systems, data from the various imaging sensors involved must be on a consistent radiometric scale. This paper reports on an investigation of radiometric calibration errors due to differences in spectral response functions between satellite sensors when attempting cross-calibration based on near-simultaneous imaging of common ground targets in analogous spectral bands, a commonly used post-launch calibration methodology. Twenty Earth observation imaging sensors (including coarser and higher spatial resolution sensors) were considered, using the Landsat solar reflective spectral domain as a framework. Scene content was simulated using spectra for four ground target types (Railroad Valley Playa, snow, sand and rangeland), together with various combinations of atmospheric states and illumination geometries. Results were obtained as a function of ground target type, satellite sensor comparison, spectral region, and scene content. Overall, if spectral band difference effects (SBDEs) are not taken into account, the Railroad Valley Playa site is a “good” ground target for cross calibration between most but not all satellite sensors in most but not all spectral regions investigated. “Good” is defined as SBDEs within ± 3%. The other three ground target types considered (snow, sand and rangeland) proved to be more sensitive to uncorrected SBDEs than the RVPN site overall. The spectral characteristics of the scene content (solar irradiance, surface reflectance and atmosphere) are examined in detail to clarify why spectral difference effects arise and why they can be significant when comparing different imaging sensor systems. Atmospheric gas absorption features are identified as being the main source of spectral variability in most spectral regions. The paper concludes with recommendations on spectral data and tools that would facilitate cross-calibration between multiple satellite sensors.     

Properties of the surface layer on copper formed after deposition and thermal treatment of aluminum gas-thermal coating

The fabrication and properties of the surface layer on copper are investigated after deposition and thermal treatment of the aluminum gas-thermal coating. This process leads to the formation of a protective diffusion layer having high physical, mechanical, and performance characteristics.     

Total Energy Shaping Control of Mechanical Systems: Simplifying the Matching Equations Via Coordinate Changes

Total energy shaping is a controller design methodology that achieves (asymptotic) stabilization of mechanical systems endowing the closed-loop system with a Lagrangian or Hamiltonian structure with a desired energy function - that qualifies as Lyapunov function for the desired equilibrium. The success of the method relies on the possibility of solving two PDEs which identify the kinetic and potential energy functions that can be assigned to the closed loop. Particularly troublesome is the partial differential equation (PDE) associated to the kinetic energy which is nonlinear and inhomogeneous and the solution, that defines the desired inertia matrix, must be positive-definite. In this note, we prove that we can eliminate or simplify the forcing term in this PDE by modifying the target dynamics and introducing a change of coordinates in the original system. Furthermore, it is shown that, in the particular case of transformation to the Lagrangian coordinates, the possibility of simplifying the PDEs is determined by the interaction between the Coriolis and centrifugal forces and the actuation structure. The examples of pendulum on a cart and Furuta's pendulum are used to illustrate the results.     

Approximability Properties for Second-Order Sliding Mode Control Systems

New definitions of approximability are presented for nonlinear second-order sliding mode control systems. Such robustness properties are compared with those already known for first-order methods. Sufficient conditions are obtained for second-order regularization, a sliding error estimate is derived, and some relevant examples are discussed.     

Impact of Preferential P-Diffusion Along the Grain Boundaries on Fine-Grained Polysilicon Solar Cells

Thin-film polysilicon solar cells are a promising low-cost alternative for bulk silicon solar cells due to their reduced material thickness. Recently, we showed that the use of an amorphous silicon/polycrystalline silicon heterojunction emitter instead of a diffused homojunction emitter led to a boost in the open-circuit voltage by 90 mV. Now, we present a full evidence that shows that this improvement is related to the absence of dopant smearing along the grain boundaries. By using scanning spreading resistance microscopy, we found an enlargement of the junction area by a factor of five in case of a homojunction. The tips of the dopant spikes represent lowly doped areas with an enhanced recombination.