Metal Single-Atom Cocatalyst on Carbon Nitride for the Photocatalytic Hydrogen Evolution Reaction: Effects of Metal Species

Single-atom (SA) catalysts exhibit high activity in various reactions because there are no inactive internal atoms. Accordingly, SA cocatalysts are also an active research fields regarding photocatalytic hydrogen (H₂) evolution which can be generated by abundant water and sunlight. Herein, it is investigated whether 10 transition metal elements can work as an SA on graphitic carbon nitride (g-C₃N₄; i.e., gCN), a promising visible-light-driven photocatalyst. A method is established to prepare SA-loaded gCN at high loadings (weight of ≈3 wt.% for Cu, Ni, Pd, Pt, Rh, and Ru) by modulating the photoreduction power. Regarding Au and Ag, SAs are formed with difficulty without aggregation because of the low binding energy between gCN and the SA. An evaluation of the photocatalytic H₂-evolution activity of the prepared metal SA-loaded gCN reveals that Pd, Pt, and Rh SA-loaded gCN exhibits relatively high H₂-evolution efficiency per SA. Transient absorption spectroscopy and electrochemical measurements reveal the following: i) Pd SA-loaded gCN exhibits a particularly suitable electronic structure for proton adsorption and ii) therefore they exhibit the highest H₂-evolution efficiency per SA than other metal SA-loaded gCN. Finally, the 8.6 times higher H₂-evolution rate per active site of Pd SA is achieved than that of Pd-nanoparticles cocatalyst.     

Role of the reaction product in the solidification of Ag–Cu–Ti filler for brazing diamond

In order to reveal the mechanism for brazing diamond using Ag–Cu–Ti filler metal, thermoanalysis of elemental metals (silver and copper) either with added diamond micropowder or with added titanium carbide micropowder as nucleant were investigated to detect undercoolings. No undercooling for the solidification of silver with added titanium carbide powder was detected by the thermoanalytical curve, and also no undercooling for copper with added diamond powder was detected. These phenomena suggest that titanium carbide powder acts in the solidification of silver effectively as a nucleant and that diamond powder also acts in the solidification of copper as a nucleant. Fine-grained silver was observed in the micrograph of the silver added with titanium carbide powder. The results of the calculations on the planar disregistry, , and the dispersion energy, Edisp revealed that the Ag (100)–TiC(100) interface and Cu(100)–diamond (100) interface are more stable than the other combinations. The results of undercoolings of various specimens correlated with both planar disregistry and dispersion energy. According to these results, the titanium carbide reaction product is considered to play an important role in the solidification of silver. The brazing strength is considered to arise from the solidification of the brazing filler metal from the titanium carbide reaction product. © 1998 Chapman & Hall     

Quantitative determination of cardiac glycosides in Digitalis lanata leaves by reversed-phase thin-layer chromatography

We have recently chosen to undertake a comprehensive evaluation of the modulation of gene expression by oxidative stress, using mRNA as a marker. Our model system is HA-1 hamster fibroblasts, using conditions under which we observe an adaptive response. Under these conditions, the HA-1 cells respond to a minimally toxic "pretreatment" dose of hydrogen peroxide by synthesizing RNAs and proteins that protect them against subsequent exposure to a highly cytotoxic concentration of hydrogen peroxide. Using the differential display technique to screen for modulated RNAs, we have recently reported an RNA species, adapt15/gadd7, whose steady-state level is significantly induced by a pretreatment dose of hydrogen peroxide (D. R. Crawford, G. P. Schools, S. L. Salmon, and K. J. A. Davies (1996) Arch. Biochem. Biophys. 325, 256-264). Here we report a second induced mRNA, designated adapt33. Two homologous adapt33 mRNAs were revealed by Northern blot hybridization. Both of these species were inducible by hydrogen peroxide, and they were sized at 1.46 and 0.99 kb. These inductions appeared to be dependent upon calcium, occurred as early as 90 min, and were maximal at 5 h. Cell fractionation revealed that a significant proportion of adapt33 RNA is associated with active translation. adapt33 is a novel sequence, as determined by cloning, sequencing, and GenBank analysis. adapt33 represents a new oxidant-inducible RNA and marker of cellular oxidative stress and a potential aid in the study, detection, and possible therapy of oxidant-related disorders.     

Automatic 3D model reconstruction of cutting tools from a single camera

Collision detection by machining simulation requires the 3D models of rotating cutters. However, the 3D models of a cutter and holder are not always available. In this paper, a new method is proposed to design an automatic vision-based 3D modeling system, which is able to quickly reconstruct the 3D model of a cutter and holder when they are installed onto the spindle. Only a single camera is mounted on the machine tool to capture the image of the rotating cutter and holder. By viewing the rotating cutter and holder as an object of surface of revolution, the contour of the imaged cutter and holder can be used to reconstruct the 3D model as a stack of circular cross-sections. Then the complete generating function of the cutter and holder can be recovered from the cross-sections. Finally, the 3D model of the cutter is built by rotating the generating function around the spindle axis. The effectiveness and accuracy of the proposed method are verified by experiments on-machine using 12 kinds of cutters and holders, which can satisfy the requirement of collision detection.     

An accurate adaptive NURBS curve interpolator with real-time flexible acceleration/deceleration control

Parametric interpolation has been widely used in CNC machining because of its advantages over the traditional linear or circular interpolation. Many researchers focused on this field and have made great progress in the specific one, NURBS curve interpolation. These works greatly improved the CNC machining with constant feedrate, confined chord error and limited acceleration/deceleration. However, during CNC machining process, mechanical shocks to machine tool caused by the undesired acceleration/deceleration profile will dramatically deteriorate the surface accuracy and quality of the machined parts. This is, in most occasions, very harmful to machine tools. In this paper, an accurate adaptive NURBS curve interpolator is proposed with consideration of acceleration–deceleration control. The proposed design effectively reduces the machining shocks by constraining the machine tool jerk dynamically. Meanwhile, the constant feedrate is maintained during most time of machining process, and thus high accuracy is achieved while the feedrate profile is greatly smoothed. In order to deal with the sudden change of the acceleration/deceleration around the corner with large curvature, a real-time flexible acceleration/deceleration control scheme is introduced to adjust the feedrate correspondingly. Case study has been taken to verify the feasibility and advantages of the proposed design.     

Characterization of terrestrial water dynamics in the Congo Basin using GRACE and satellite radar altimetry

The Congo Basin is the world's third largest in size (~ 3.7 million km²), and second only to the Amazon River in discharge (~ 40,200 m³ s^− 1 annual average). However, the hydrological dynamics of seasonally flooded wetlands and floodplains remains poorly quantified. Here, we separate the Congo wetland into four 3° × 3° regions, and use remote sensing measurements (i.e., GRACE, satellite radar altimeter, GPCP, JERS-1, SRTM, and MODIS) to estimate the amounts of water filling and draining from the Congo wetland, and to determine the source of the water. We find that the amount of water annually filling and draining the Congo wetlands is 111 km³, which is about one-third the size of the water volumes found on the mainstem Amazon floodplain. Based on amplitude comparisons among the water volume changes and timing comparisons among their fluxes, we conclude that the local upland runoff is the main source of the Congo wetland water, not the fluvial process of river-floodplain water exchange as in the Amazon. Our hydraulic analysis using altimeter measurements also supports our conclusion by demonstrating that water surface elevations in the wetlands are consistently higher than the adjacent river water levels. Our research highlights differences in the hydrology and hydrodynamics between the Congo wetland and the mainstem Amazon floodplain.     

A new approach for the solution of singular optima in truss topology optimization with stress and local buckling constraints

The present paper investigates problems of truss topology optimization under local buckling constraints. A new approach for the solution of singular problems caused by stress and local buckling constraints is proposed. At first, a second order smooth-extended technique is used to make the disjoint feasible domains connect, then the so-called ε-relaxed method is applied to eliminate the singular optima from problem formulation. By means of this approach, the singular optimum of the original problem caused by stress and local buckling constraints can be searched approximately by employing the algorithms developed for sizing optimization problems with high accuracy. Therefore, the numerical problem resulting from stress and local buckling constraints can be solved in an elegant way. The applications of the proposed approach and its effectiveness are illustrated with several numerical examples. Received May 2, 2000     

High-intensity multi-bunch beam generation by a photo-cathode RF gun

A multi-bunch photo-cathode RF gun system has been developed as an electron source for the production of intense quasi-monochromatic X-rays based on inverse Compton scattering. The desired multi-bunch beam is 100 bunches/pulse with a total charge of 500 nC and a bunch spacing of 2.8 ns. We modified the gun cavity of a ‘BNL-type IV’ RF gun to allow a CsTe cathode plug in the end plate. The system uses a four-dipole chicane beam line to allow the injection of laser light normal to the cathode surface. We compensate the gun cavity beam loading caused by the high-intensity multi-bunch electron beam by injecting the laser pulse before RF power has filled the cavity. We have achieved a total intensity of 220 nC in 100 bunches with a bunch-to-bunch energy spread under 1.3% (peak-to-peak). This paper concentrates on experiments to generate the high-intensity multi-bunch beam with compensation of the bunch-to-bunch energy spread due to heavy beam loading.