Design and analysis of a state observer for the temperature front of a retification column

In order to achieve optimal energy-saving, load-dependent operation of rectification columns, development and implementation of model-based control concepts are necessary. This paper reports on the design and step-by-step testing of a state observer for the estimation of two state variables which cannot be measured directly, namely the vapour rate and the location of mass transfer zone (temperature front) in the stripping section of a production column. The procedure is described, and the relevant simulation and operation results are presented and discussed. Initial experience, gained when the concept was put into practical operation, is reported.     

Influence of impurities and deformation temperature on the saturation microstructure and ductility of HPT-deformed nickel

Ni with different purities between 99.69 and 99.99 wt.% was deformed by high-pressure torsion (HPT) to high strains, where no further refinement of the microstructure is observed. The HPT deformation temperature varied between −196 and 400 °C. Both impurities and temperature significantly affect the lower limit of the grain size obtained by HPT. In the investigated samples, carbon was the most important impurity element in controlling the limit of grain refinement. The decrease in grain size due to an increase in the carbon content from 0.008 to 0.06 wt.% for HPT-deformed Ni samples at room temperature enhanced the ultimate tensile strength from 1000 to 1700 MPa. Surprisingly, the carbon content did not deteriorate the ductility, defined as the reduction in area, which is mainly limited by the total amount of impurities besides carbon. Furthermore, the deformation temperature dependency on ductility was not very pronounced and only visible for deformation temperatures above 200 °C.