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71.
Various synchronization algorithms have been introduced in literature during the last decades to deal with the firing squad synchronization problem on cellular automata (CA). Among others defective CA algorithms, where the CA cell is able to transmit information without previous processing, have been also presented. In our case, originating from the classical Mazoyer’s paper, where a minimum-time solution is presented with 6 states, a one-dimensional CA where one cell may permanently fail is presented. In the proposed algorithm, the defective cell can neither process nor transmit information any longer, while it is considered that such dynamic defects may become apparent in any time step of computation. A thorough analysis of the synchronization, in terms of location and time at which cell fails, for the cells found in both sides of defective cell is delivered to decipher the corresponding maximal possible number of synchronized cells in each part of the cut, due to defect, CA array. The proposed algorithm is properly extended to consider more than one defective cells that may occur in the under study one-dimensional CA. Based on the aforementioned analysis, we provide the generalization of synchronization with multiple totally defective cells, while application examples of the generalized CA algorithm in case of two defective cells are also presented. Finally, another intriguing aspect refers to handling of states that could be tentatively characterized as unknown, in a confrontation similar to the previous defective state but also different, since now this(these) cell(s) are not stated as faulty but unknown. As a result, a new one-dimensional CA with less states, compared to the previous CA defective algorithms, able to synchronize the maximal possible number of cells in each part occurs.  相似文献   
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In contrast to pristine zinc phthalocyanine (1), zinc phthalocyanine based oPPV‐oligomers (2–4) of different chain lengths interact tightly and reversibly with graphite, affording stable and finely dispersed suspensions of mono‐ to few‐layer graphene—nanographene (NG)—that are photoactive. The p‐type character of the oPPV backbones and the increasing length of the oPPV backbones facilitate the overall π–π interactions with the graphene layers. In NG/2, NG/3, and NG/4 hybrids, strong electronic coupling between the individual components gives rise to charge transfer from the photoexcited zinc phthalocyanines to NG to form hundreds of picoseconds lived charge transfer states. The resulting features, namely photo‐ and redoxactivity, serve as incentives to construct and to test novel solar cells. Solar cells made out of NG/4 feature stable and repeatable photocurrent generation during several ‘on‐off’ cycles of illumination with monochromatic IPCE values of around 1%.  相似文献   
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Electricity storage systems (ESS) for bulk energy storage are principally used for load levelling purposes or for relieving the intermittency of renewables. Another use is electricity arbitrage through the rule of ‘buy low, sell high’. This operation tracks the market‐clearing price (MCP) profiles and produces profit by exploiting the differences between peak and off‐peak prices. The profits made in this way depend on technology characteristics and the market competition level. We investigate the influence of demand‐side management (DSM) on ESS profitability when the only income is from provision of electricity arbitrage services, by optimizing the time allocation of the charge and discharge operations. Two scenarios of DSM in the market have been selected for two management periods (MP): 1 day and 3 days. The longer MP is examined in order to investigate the potential for higher economic value when energy transfer to the next day is permitted. The key finding is that a very small load shifting from peaks to off‐peaks, due to DSM, significantly affects the ESS profit. The significant profit losses the ESS showed are a result of the high capital costs and the small difference of the peak and off‐peak electricity prices in the Greek market. Therefore, under the assumptions we have made for this research, any attempt to use ESS in ‘buy low, sell high’ operation is not profitable. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
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Nucleic acid amplification testing (NAAT) is the gold standard for infectious disease diagnostics. Currently NAATs are mainly limited to centralized laboratories, while paper-based antigen tests are used for rapid home-based diagnostics. DNA extraction, the initial sample preparation step in NAATs, remains a bottleneck that hinders its development toward home-based kits. This step requires the use of compounds detrimental to the enzymes in downstream DNA amplification. Here, this work overcomes this bottleneck by immobilizing the enzyme achromopeptidase (ACP) on nitrocellulose, to both store and enable the separation of the enzymes from the other steps. This work provides proof-of-concept that immobilized ACP is effective at lysis and release of amplifiable DNA from gram-positive Staphylococcus epidermidis and enables the use of the lysate directly for DNA amplification, without the need for heat deactivation of the enzyme. This sample preparation method requires only incubation at 37 °C and mild agitation, which allows to implement it with fully disposable and affordable equipment. Consequently, this work enables to combine the paper-based DNA extraction method with the isothermal recombinase polymerase amplification (RPA) followed by lateral flow detection to demonstrate a sample-to-answer NAAT packaged as an instrument free self-test kit expanding the capabilities of home-testing beyond antigen tests.  相似文献   
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In ad hoc wireless networks, devices that normally cannot directly communicate route their messages through intermediate nodes. The number of those nodes is called hop count, a useful metric in estimating the distance between 2 nodes. Current methods usually depend on special nodes, called anchors, that need accurate localization information, in order to calculate an estimate for the average distance traversed per hop. The drawback of this approach is that anchor nodes increase the overall cost and complexity of the system. To address this problem, this letter proposes a novel, anchor node–free algorithm that can achieve a useful estimate for actual distance between 2 nodes, by analytically finding an estimate for the average maximum distance traveled per hop and multiplying with the hop count. The only requirement is the a priori knowledge of the networks' node density and the node range. The performance of our method is compared with a recent anchor node–based method and is shown to yield similar location estimation accuracy, despite the fact that it does not use anchor nodes.  相似文献   
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The chemical functionalization of fullerene single molecule magnet Tb2@C80(CH2Ph) enables the facile preparation of robust monolayers on graphene and highly oriented pyrolytic graphite from solution without impairing their magnetic properties. Monolayers of endohedral fullerene functionalized with pyrene exhibit magnetic bistability up to a temperature of 28 K. The use of pyrene terminated linker molecules opens the way to devise integration of spin carrying units encapsulated by fullerene cages on graphitic substrates, be it single-molecule magnets or qubit candidates.  相似文献   
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Myosin family motors play diverse cellular roles. Precise insights into how the light chains contribute to the functional variabilities among myosin motors, however, remain unresolved. Here, it is demonstrated that the fast skeletal muscle myosin II isoform myosin heavy chain (MHC‐IID) can be transformed into a processive motor, by simply replacing the native regulatory light chain MLC2f with the regulatory light chain variant MLC2v from the slow muscle myosin II. Single molecule kinetic analyses and optical trapping measurements of the hybrid motor reveal marked changes such as increased association rate of myosin toward adenosine triphosphate (ATP) and actin by more than twofold. The direct consequence of high adenosine diphosphate (ADP) affinity and increased actin rebinding is the altered overall actomyosin association time during the cross‐bridge cycle. The data indicate that the MLC2v influences the duty ratio in the hybrid motor, suggestive of promoting interhead communication and enabling processive movement. This finding establishes that the regulatory light chain fine‐tunes the motor's mechanical output that may have important implications under physiological conditions. Furthermore, the success of this approach paves the way to engineer motors from a known motor protein element to assemble highly specialized biohybrid machines for potential applications in nano‐biomedicine and engineering.  相似文献   
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