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排序方式: 共有710条查询结果,搜索用时 10 毫秒
31.
McDonnell LA Mize TH Luxembourg SL Koster S Eijkel GB Verpoorte E de Rooij NF Heeren RM 《Analytical chemistry》2003,75(17):4373-4381
It is well known in secondary ion mass spectrometry (SIMS) that sample topography leads to decreased mass resolution. Specifically, the ion's time of flight is dependent on where it was generated. Here, using matrix-enhanced SIMS, it is demonstrated that, in addition to increasing the yield of intact pseudomolecular ions, the matrix allows the user to semiquantitatively record the topography of a sample. Through mapping the topography-related mass shifts of the matrix (which leads to decreased mass resolution), the analogous mass shifts of higher mass ions can be deconvoluted and higher resolution and greater sensitivity obtained. Furthermore, the semiquantitative topographical map obtained can be compared with any chemical images obtained, allowing the user to quickly ascertain whether local intensity maximums are due to topological features or represent genuine features of interest. 相似文献
32.
Gert G. Harigel 《Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment》1985,235(2):339-342
A tentative layout for a huge argon bubble chamber/calorimeter/scintillation detector, to be used for neutrino experiments at a multi-TeV accelerator, is described. Such a detector can be operated in beams with various spill duration and it combines the features of a bubble chamber with properties of counter detectors. 相似文献
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Barbara Jaskula Koen Goiris Gert De Rouck Guido Aerts Luc De Cooman 《Journal of the Institute of Brewing》2007,113(4):381-390
A pleasant and consistent bitterness is an essential flavour attribute of beer. Hop‐derived iso‐α‐acids are largely responsible for beer bitterness and accurate determination of these primary flavour compounds is very important in relation to quality control. The most widely used way to determine beer bitterness is based on spectrophotometry, measuring the absorbance of an iso‐octane extract of acidified beer. However, this approach is far from specific as it measures all of the extracted compounds, including non‐bittering principles. For that particular reason, High Performance Liquid Chromatography (HPLC) is increasingly applied for the quantitative determination of hop‐derived iso‐α‐acids and, if present, reduced iso‐α‐acids. However, to obtain accurate data on beer bitterness profiles, both quantitative sample preparation and state‐of‐the‐art HPLC are essential. In this paper, several extraction procedures based on solid phase extraction (SPE) and liquid‐liquid extraction (LLE), respectively, were evaluated and an optimised extraction methodology using H3PO4 for sample acidification prior to extraction is presented. The proposed extraction/HPLC methodology allows for the quantitative recovery and analysis of hop‐derived beer bitterness. 相似文献
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37.
Comparative Assessment of Complex Stabilities of Radiocopper Chelating Agents by a Combination of Complex Challenge and in vivo Experiments 下载免费PDF全文
Shanna Litau Dr. Uwe Seibold Alicia Vall‐Sagarra Prof. Dr. Gert Fricker Prof. Dr. Björn Wängler Priv.‐Doz. Dr. Carmen Wängler 《ChemMedChem》2015,10(7):1200-1208
For 64Cu radiolabeling of biomolecules to be used as in vivo positron emission tomography (PET) imaging agents, various chelators are commonly applied. It has not yet been determined which of the most potent chelators—NODA‐GA ((1,4,7‐triazacyclononane‐4,7‐diyl)diacetic acid‐1‐glutaric acid), CB‐TE2A (2,2′‐(1,4,8,11‐tetraazabicyclo[6.6.2]hexadecane‐4,11‐diyl)diacetic acid), or CB‐TE1A‐GA (1,4,8,11‐tetraazabicyclo[6.6.2]hexadecane‐4,11‐diyl‐8‐acetic acid‐1‐glutaric acid)—forms the most stable complexes resulting in PET images of highest quality. We determined the 64Cu complex stabilities for these three chelators by a combination of complex challenge and an in vivo approach. For this purpose, bioconjugates of the chelating agents with the gastrin‐releasing peptide receptor (GRPR)‐affine peptide PESIN and an integrin αvβ3‐affine c(RGDfC) tetramer were synthesized and radiolabeled with 64Cu in excellent yields and specific activities. The 64Cu‐labeled biomolecules were evaluated for their complex stabilities in vitro by conducting a challenge experiment with the respective other chelators as challengers. The in vivo stabilities of the complexes were also determined, showing the highest stability for the 64Cu–CB‐TE1A‐GA complex in both experimental setups. Therefore, CB‐TE1A‐GA is the most appropriate chelating agent for *Cu‐labeled radiotracers and in vivo imaging applications. 相似文献
38.
Aluminum as an alloying element in high-speed steel was investigated for the first time during the Second World War at the Montanuniversität Leoben. At this time there was an enormous consumption or rather a shortage of molybdenum and especially of tungsten worldwide. Tungsten was not only used for the high-speed steel production but was also very much needed for the war industry. Attempts were made in order to replace these alloying elements in high-speed steels with cheaper elements. It was found that a certain percentage of tungsten and molybdenum in high-speed steel can be replaced or substituted by an aluminium content of 0.3 up to 1.4 mass-% without any loss of cutting performance. However, no detailed metallurgical investigations were carried out to explain and clarify this behaviour of aluminium. The influence of aluminium in high-speed steels is highly controversial, due to the fact that aluminium compared to tungsten and molybdenum is not a carbide-forming element, but the special properties of high-speed steels are mainly gained by the presence of carbides. Despite several works in this field, there is no clear understanding of how aluminium can affect the properties of high-speed steel. In the present work, standard and modern examination methods, such as scanning electron microscope, energy dispersive X-ray spectroscopy, and atom probe tomography, were used to investigate the effect of aluminium on the primary and secondary hardening carbides in high-speed steels. The investigations were conducted on three high-speed steel grades with varying the aluminium content only. 相似文献
39.
Nasir Mahmood Mohammad Sohail Khan Asad Ullah Khan Klaus Werner Stöckelhuber Gert Heinrich 《应用聚合物科学杂志》2010,117(3):1493-1501
This article reports the purification and surface modification of coal ash silica and afterwards its utilization as reinforcing filler in solution‐styrene‐butadiene rubber/butadiene rubber (S‐SBR/BR). The coal ash silica free of unwanted metal ions/mineral oxides was obtained using phosphoric acid. The chemical composition of the purified coal ash silica in comparison to impure coal ash indicates the presence of characteristic hydroxyl functional group at 3440 cm?1 and an increase in the oxygen content as determined with the help of Fourier Transform Infrared and x‐ray photoelectron spectroscopy, respectively. The contact angle analysis shows that after purification the polar part of the surface energy increased to 17.5 from 12 m Jm?2. While the surface area increased to an order of magnitude, i.e., 11.6 to 110.5 m2 g?1. The modification of purified silica particles with bis(3‐triethoxysilylpropyl) tetrasulfane reveal the functionalization of hydroxyl to ‐Si‐O‐R groups as detected at 1560 cm?1. As a consequence, the modified silica based S‐SBR/BR composite resulted in improved mechanical properties due to enhanced silica‐rubber interaction. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
40.
Ron Zevenhoven Anders Wiklund Johan Fagerlund Sanni Eloneva Ben In’t Veen Hans Geerlings Gert Van Mossel Harold Boerrigter 《Frontiers of Chemical Engineering in China》2010,4(2):110-119
The use of carbon dioxide (CO2) and calcium-containing by-products from industrial activities is receiving increasing interest as a route to valuable carbonate
materials while reducing CO2 emissions and saving natural resources. In this work, wet-chemical experimental data was assessed, which involved the carbonation
of three types of materials in aqueous solutions, namely, 1) wollastonite, a calcium silicate mineral, 2) steelmaking slag,
a by-product of steel production, and 3) paper bottom ash (PBA) from waste paper incineration. Aims were to achieve either
a high carbonation degree and/or a pure carbonate product with potential commercial value. Producing a pure precipitated calcium
carbonate (PCC) material that may find use in paper industry products puts strong requirements on purity and brightness. The
parameters investigated were particle size, CO2 pressure, temperature, solid/liquid ratio, and the use of additives that affect the solubilities of CO2 and/or calcium carbonate. Temperatures and pressures were varied up to 180°C and 4 MPa. Data obtained with the wollastinite
mineral allowed for a comparison between natural resources and the industrial by-product materials, the latter typically being
more reactive. With respect to temperature and pressure trends reported by others were largely confirmed, with temperatures
above 150°C introducing thermodynamic limitations depending on CO2 pressure. The influence of additives showed some promise, although costs may make recycling and reuse of additives a necessity
for a large-scale process. When using steelmaking slag, magnetic separation may remove some iron-containing material from
the process (although this is far from perfect), while the addition of bicarbonate supported the removal of phosphorous, aside
from improving calcium extraction. The experiments with paper bottom ash (PBA) gave new data, showing that its reactivity
resembles that of steelmaking slag, while its composition results in relatively pure carbonate product. Also, with PBA no
additives were needed to achieve this. 相似文献