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81.
    
A 2D mathematical model was developed in this study to simulate acetone separation from water by using a microstripper device. Model validation was implemented through a comparison of simulation results of acetone removal from water and experimental data for dry nitrogen over a wide range of carrier gas and liquid velocities. A comparison of experimental data and simulation results illustrated reasonable agreement. The results indicate that increasing the liquid velocity reduces the acetone removal rate because increasing liquid velocity results in a decrease in the residence time of liquid in the liquid channel, whereas there is an enhancement in acetone removal with increasing carrier gas velocity. A sharp decrease in acetone concentration in the liquid channel was observed.  相似文献   
82.
    
The purpose of this study is to measure the concentration of gold nanoparticles (AuNPs) attached to folic acid through cysteamin as the linker (FA‐Cys‐AuNPs) and AuNPs in KB human nasopharyngeal cancer cells using dual‐energy CT (DECT). In this study, nanoparticles with a size of ∼15 nm were synthesized and characterised using UV‐Vis, TEM, FTIR and ICP‐OES analyses. The non‐toxicity of nanoparticles was confirmed by MTT assay under various concentrations (40– 100 µg/ml) and incubation times (6, 12 and 24 h). To develop an algorithm for revealing different concentrations of AuNPs in cells, a corresponding physical phantom filled with 0.5 ml vials containing FA‐Cys‐AuNPs was used. The CT scan was performed at two energy levels (80 and 140 kVp). One feature of DECT is material decomposition, which allows separation and identification of different elements. The values obtained from the DECT algorithm were compared with values quantitatively measured by ICP‐OES. Cells were also incubated with AuNPs and FA‐Cys‐AuNPs at different concentrations and incubation times. Subsequently, by increasing the incubation time in the presence of FA‐Cys‐AuNPs, in comparison with AuNPs, DECT pixels were increased. Thus, FA‐Cys‐AuNPs could be a suitable candidate for targeted contrast agent in DECT molecular imaging of nasopharyngeal cancer cells.Inspec keywords: biomedical materials, phantoms, nanoparticles, computerised tomography, nanomedicine, cancer, toxicology, nanofabrication, gold, cellular biophysics, ultraviolet spectra, visible spectra, transmission electron microscopy, Fourier transform infrared spectraOther keywords: Au, time 24.0 hour, time 12.0 hour, time 6.0 hour, head cancer cells, DECT molecular imaging, DECT algorithm, material decomposition, physical phantom, MTT assay, ICP‐OES analyses, FTIR spectra, TEM, UV‐vis spectrophotometry, cysteamin, folic acid, gold nanoparticle concentration, nasopharyngeal cancer cells, dual‐energy CT imaging, neck cancer cells, KB human nasopharyngeal cancer cells, multifunctional gold nanoparticles  相似文献   
83.
In this paper, final surface accuracy in turning the super alloy Monel K-500 is studied. The experiments were conducted on the basis of the design of experiment methodology considering four inputs of tool nose radius, feed rate, depth of cut, and cutting speed, and three outputs of surface roughness, dimensional deviation, and tool wear. The aim of this work is to identify these three phenomena to achieve a desirable machined surface with acceptable finishing and the least deviation from nominal dimensions under different parametric conditions. It was observed that the quality of the machined surface in the direction of the machining length is not constant and, in some trials, the values of Ra increase considerably at the end of the machining length. The results show that cutting speed can improve surface accuracy, in a way that the more the cutting speed, the less the dimensional deviation. Less depth of cut and tool radius affect dimensional deviation as well. Although it has a small effect on dimensional deviation, feed rate plays the most important role in controlling tool wear. Finally, on the basis of Grey relational analysis, a simultaneous optimization is carried out on surface roughness, dimensional deviation, and tool wear values. In order to minimize these responses, optimal parametric conditions are presented. A satisfying correspondence was observed between the predicted results and the confirmation observations.  相似文献   
84.
This paper reports the solids behaviour in a dilute gas-solid two-phase mixture flowing through a packed bed. The positron emission particle tracking (PEPT) technique was used in the work, which allowed investigation of three-dimensional solids motion at the single suspended particle level. Processing of the data gave solids velocity, the residence time of suspended particles, bed tortuosity in terms of solids motion, as well as solids occupancy in the cross-section of the packed bed. The results suggest that the wall effect on the motion of suspended particles is limited to approximately one packed particle diameter under the conditions of this work. Both the average axial and radial velocities of suspended particles, normalised by the superficial gas velocity, change periodically with radial position, but the periodicity does not correspond exactly to the packed particle diameter. The peak and trough values of the average axial velocity of the suspended particles in the bulk region are, respectively, ∼25% and ∼15% of the superficial gas velocity under the conditions of this work and the superficial gas velocity shows little effect. The peak and trough values of the average radial velocity of the suspended particles in the bulk region are, respectively, +5% (positive) and -5% (negative) of the superficial gas velocity. The results of the residence time and tortuosity of the suspended particles show an approximately Gaussian distribution with the peak residence time and tortuosity increasing with decreasing superficial gas velocity. The occupancy data suggest that particles spend more time in an annular region close to the wall, indicating a non-uniform particle distribution across the packed bed cross-section.  相似文献   
85.
    
Investigations on the advanced oxidation processes (AOP) express that one of the effective oxidation agents in the degradation of organic pollutants is the aqueous hydroxyl radical. Therefore, the main aim of this work is the determination of the hydroxyl radical rate constant. To this end, three artificial intelligence methods were used to predict this constant for 457 various water pollutants from 27 molecular structures. The modelling results showed that the proposed decision tree model can determine the mentioned parameter with R‐squared values of 0.9264 and mean relative error of 1.479 for the overall data set. In addition, a comprehensive analysis of input parameters showed that Burden eigenvalue has the most impact on the hydroxyl radical rate constant. Finally, different comparisons were carried out between the suggested algorithms and other published approaches in the literature, which showed a high degree of precision for our models.  相似文献   
86.
In this article, the vibration frequency of an orthotropic nanoplate under the effect of temperature change is investigated. Using nonlocal elasticity theory, governing equations are derived. Based on the generalized differential quadrature method for cantilever and propped cantilever boundary conditions, the frequencies of orthotropic nanoplates are considered and the obtained results are compared with valid reported results in the literature. The effects of temperature variation, small scale, different boundary conditions, aspect ratio, and length on natural nondimensional frequencies are studied. The present analysis is applicable for the design of rotating and nonrotating nano-devices that make use of thermo-mechanical vibration characteristics of nanoplates.  相似文献   
87.
Vacuum membrane distillation is modeled for the purification of water containing organic matter. The separation medium is a hollow‐fiber membrane contactor that is simplified to a two‐dimensional structure with a single porous membrane wall. The model considers the transport phenomena of a vacuum membrane distillation system in porous media, in which the aqueous volatile organic solution was considered as an incompressible and steady fluid. The numerical simulation of the two‐dimensional model of vacuum membrane distillation for an aqueous solution of 1,1,1‐trichloroethane was established under steady state. The effects of the bulk feed temperature and the feed flow rate on the percentage of 1,1,1‐trichloroethane removal from an aqueous solution are discussed.  相似文献   
88.
A non-stoichiometric thermodynamic analysis is performed on the adsorption-enhanced steam reforming of glycerol for hydrogen production based on the principle of minimising the Gibbs free energy. The effects of temperature (600–1000 K), pressure (1–4 bar), water to glycerol feed ratio (3:1–12:1), percentage of CO2 adsorption (0–99%) and molar ratio of carrier gas to feed reactants (1:1–5:1) on the reforming reactions and carbon formation are examined. The results show that the use of a CO2 adsorbent enhances glycerol conversion to hydrogen and the maximum number of moles of hydrogen produced per mole of glycerol can be increased from 6 to 7 due to the CO2 adsorption. The analyses suggest that the most favourable temperature for steam–glycerol reforming is between 800 and 850 K in the presence of a CO2 adsorbent, which is about 100 K lower than that for reforming without CO2 adsorption. Although high pressures are favourable for CO2 adsorption, a lower operating pressure gives a higher overall hydrogen conversion. The most favourable water to glycerol feed ratio is found to be 9.0 above which the benefit becomes marginal. Carbon formation could occur at low water to glycerol feed ratios, and the use of a CO2 adsorbent can suppress the formation reaction and substantially reduce the lower limit of the water to glycerol feed ratio for carbon formation.  相似文献   
89.
This paper is concerned with an upward co-current flow of a gas-solid two-phase mixture through a packed bed, a system employed in a number of industrial processes. Experimental work was carried out by using glass balls for packed bed, and both glass beads and FCC as suspended particles. The effects of solids loading and gas velocity on the pressure drop as well as the static and dynamic solid hold-ups within packed bed were examined. Experimental results showed different behaviour of the FCC from glass beads. At a given gas velocity, pressure drop increased approximately linearly with solids loading with a slope for FCC much higher than that for glass beads. The static hold-up of glass beads was much lower than corresponding dynamic hold-up at a given gas velocity, and it did not seem to change much with solids loading under the conditions of this work. At a given gas velocity, the static hold-up of FCC, however, was found to be comparable with the corresponding dynamic hold-up. An analysis was conducted on the pressure drop using a modified version of the Ergun equation by taking into account the effects of suspended particles on the viscosity and density, as well as the gravitational force. It was found that the modified Ergun equation agreed well with the experimental results of both this work and those reported in the literature. Effort was also made to develop relationships for the dynamic hold-up and the interaction coefficient between the suspended and the packed particles, the so-called solid-phase friction factor in the literature. The dynamic hold-up was found to increase with an increase in the product of velocity ratio of the solid to gas phases and the square root of the diameter ratio of the suspended to packed particles, whereas the interaction coefficient increased in general with increasing Froude number but with significant scattering.  相似文献   
90.
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