Effects of TiO2 on microstructural,mechanical properties and in-vitro bioactivity of plasma sprayed yttria stabilised zirconia coatings for dental application

One of the most compatible coatings, known as yttria-stabilised zirconia polycrystal (YZP) is deposited on metallic Ti alloys due to its excellent hardness and aesthetic value as well as its low affinity for plaques. However, poor bioactivities of YZP and the existence of micro crack propagations due to the aging of YZP may result in spontaneous implant failure thus limiting its clinical use. In this work, YZP coating reinforced titania (TiO₂), which is formed via a plasma spray technique was investigated in order to enhance the bioactivity and the mechanical properties of YZP coatings for dental implants. Based on microstructural studies performed on the deposited coating, a distinguished lamellar structure comprising YZP and TiO₂ was observed. It was found that the reinforcement of TiO₂ in YZP coating significantly reduced the crack due to the improved densities and the lamellar structure. The mechanical properties were also found to improve with 90% of hardness, 45% of adhesion strength and 54% of Young's Modulus with TiO₂ addition, which is desirable for dental implants. An in-vitro bioactivity test was then conducted by immersing the coatings in a simulated body fluid (SBF). As a result, an apatite formation was found on the YZP/TiO₂ coating surface after 3 days of immersion. Besides, it was verified in an XRD analysis that the crystalline TiO₂ was found in a rutile phase which was highly effective in generating apatite (natural mineral in human bones) on YZP coatings, proving that the bioactivities of the coating were significantly improved. Further studies were also performed on the SBF treatment, which took up to 14 days also demonstrated that only a small decrease in hardness was noted, indicating that YZP/TiO₂ coatings had reached an excellent mechanical stability.     

Soy Protein–Gum Karaya Conjugate: Emulsifying Activity and Rheological Behavior in Aqueous System and Oil in Water Emulsion

The main objective of this study is to investigate the effects of mixing and conjugation of soy protein isolate (SPI) with gum karaya on the characteristics of the hybrid polymer (protein–gum) in both aqueous systems and oil‐in‐water (O/W) emulsions. It was hypothesized that the covalent linkage of gum karaya with SPI would improve the emulsifying activity and rheological properties of both polymers. Conjugation occurred under controlled conditions (i.e., 60 °C and 75 % relative humidity, 3 days). The conjugated hybrid polymer produced smaller droplet with better uniformity, higher viscosity and stronger emulsifying activity than native gum karaya, suggesting the conjugated polymer provided a bulkier secondary layer with more efficient coverage around oil droplets, thereby inducing stronger resistance against droplet aggregation and flocculation. Emulsions containing the native gum karaya produced the largest droplet size among all prepared emulsions (D_3,2 = 8.6 μm; D_4,3 = 22.4 μm); while the emulsion containing protein–gum conjugate (1:1 g/g) had the smallest droplet size (D_3,2 = 0.2 μm; D_4,3 = 0.7 μm) with lower polydispersity. The protein–gum conjugate (1:1 g/g) also showed the highest elastic and viscous modulus, the lowest polydispersity (span) and the highest emulsifying activity among all native, mixed and conjugated polymers. Therefore, the percentage of gum karaya used for production of O/W emulsion can be decreased by partially replacing it with the conjugated gum.     

Development of Pistachio (Pistacia vera L.) Spread

Pistachio nut (Pistacia vera L.) is one of the most delicious and nutritious nuts in the world. Pistachio spreads were developed using pistachio paste as the main component, icing sugar, soy protein isolate (SPI), and red palm oil (RPO), at different ratios. The highest mean scores of all the sensory attributes were depicted by spreads that were made without addition of SPI. It was found that the work of shear was 0 to 11.0 kg s for an acceptable spread. Sensory spreadability, overall texture, spreadability, and overall acceptability were negatively correlated (R > 0.83) with the work of shear of spreads. The findings indicated that the presence of RPO had a direct effect on the viscoelastic behavior of the pistachio spreads. The a values, which are related to the green color of the pistachio product ranged from 1.7 to 3.9 for spread without addition of RPO, and 4.0 to 5.3 in the presence of RPO. Practical Application The development of pistachio spread would potentially increase the food uses of pistachio and introduce consumers with a healthier snack food.     

Solid–liquid structural break-up in M2 tool steel for semi-solid metal processing

The success of semi-solid metal processing mostly depends on the formation of suitable starting microstructure, which must consist of solid metal spheroids in a liquid matrix. Various methods of obtaining this structure have been established; they include recrystallisation and partial melting (RAP), strain-induced melt-activated (SIMA), or simple mechanical stirring, to name a few. These methods, as widely discussed, have mostly been applied with light alloys, mainly aluminium based. This article discusses solid–liquid structural break-up in M2 tool steel subjected to a direct re-melting procedure from the as-annealed condition. The role of carbide dissolution in the grain boundary liquation of the steel is described. This leads to the production of near spheroidal solid grains in a liquid matrix, a microstructure suitable for the thixoforming process. Microstructural examination revealed that carbide particles contained in bands at 1220 °C slowly disappeared with temperature. At 1300 °C, the solid grains seemed to be free from carbides. Most of the carbides had now re-precipitated at the grain boundaries. Thixoforming carried out at 1340 and 1360 °C revealed the thixotropic properties of the semi-solid metal slurries. The results indicate a widening of the range of potential routes to thixoformable microstructures.     

Extraction and physicochemical properties of low free fatty acid crude palm oil

Response surface methodology was applied to optimize the pre-treatment of oil palm (Elaeis guineensis) fruit spikelets before oil extraction. The treatment applied was drying at different times and temperatures. The dried spikelets were then subjected to mechanical processes and crude oil was extracted. A central composite design was employed to study the responses, namely percentage of free fatty acids (FFA) and oil yield, and the optimum conditions for minimum FFA and maximum oil yield were identified from their respective contour plots. It was concluded that the pre-treatment should be carried out for 12.8 h at 66.8 °C. Under the optimum conditions, the corresponding response values for FFA and oil yield were 1% and 33.6%, respectively. Some of the physicochemical properties of the extracted oil were then determined. The low free fatty acid crude palm oil exhibited good physicochemical properties and could be useful for industrial applications.     

Enhancement of Thermoelectric Behavior of La0.5Co4Sb12−x Te x Skutterudite Materials

Metallurgical and Materials Transactions A - In this work, the effects of Te doping on the microstructure and thermoelectric properties of the partially filled skutterudite La0.5Co4Sb12 compounds...     

Modelling rainfall intensity from NOAA AVHRR data for operational flood forecasting in Malaysia

Many empirical studies in numerical weather prediction have been carried out that establish the relationship between top‐of‐the‐cloud brightness temperature and rainfall particularly in tropical and equatorial regions of the world. Malaysia is a tropical country that lies along the path of the north‐east and south‐west monsoon rainfall, which sometimes causes extensive flood disasters. Observations have generally shown that heavy cumulonimbus cloud formation and thunderstorms precede the usual heavy monsoon rains that cause flood disasters in the region. In this study, a model has been developed to process National Oceanic & Atmospheric Administration Advanced Very High Resolution Radiometer (AVHRR) satellite data for rainfall intensity in an attempt to improve quantitative precipitation forecasting (QPF) as input to operational hydro‐meteorological flood early warning. The thermal bands in the multispectral AVHRR data were processed for brightness temperature. Data were further processed to determine cloud height and classification performed to delineate clouds in three broad classes of low, middle, and high. A rainfall intensity of 3–12 mm h^?1 was assigned to the 1‐D cloud model to determine the maximum rain rate as a function of maximum cloud height and minimum cloud model temperature at a threshold level of 235 K. The result of establishing the rainfall intensity based on top of the cloud brightness temperature was very promising. It also showed a good areal coverage that delineated areas likely to receive intense rainfall on a regional scale. With a spatial resolution of 1.1 km, data are course but provide a good coverage for an average river catchment/basin. This raises the opportunity of simulating rainfall runoff for the river catchment through the coupling of a suitable hydro‐dynamic model and GIS to provide early warning prior to the actual rainfall event.     

A Risk Poker Based Testing Model for Scrum

In agile software development, project estimation often depends on group discussion and expert opinions. Literature claims that group discussion in risk analysis helps to identify some of the crucial issues that might affect development, testing, and implementation. However, risk prioritization often relies on individual expert judgment. Therefore, Risk Poker, a lightweight risk-based testing methodology in which risk analysis is performed through group discussion that outperforms the individual analyst’s estimation is introduced in agile methods. Keeping in view aforementioned benefits Risk Poker can offer, unfortunately, no study has been conducted to empirically prove its ability to improve the testing process to date. Therefore, this research is aimed at closing this research gap by (i) deploying Risk Poker technique as a risk-based strategy in the agile development lifecycle, and (ii) empirically evaluating improvement of the proposed test process. For this purpose, Risk Poker technique is coupled with test coverage for an innovated testing process in an agile project following Scrum in order to provide adequate test coverage for testing activity. A case study was conducted with 6 teams of undergraduate students to estimate test coverage using Risk Poker for an e-commerce system. Three teams estimated their user stories using Risk Poker, while the rest estimated individually and used an average to obtain the statistical combination. The results showed that the proposed usage of Risk Poker for risk analysis and estimate test coverage outperformed the averaged statistical estimation of risk analysis for user stories.