Development of a framework for the risk assessment of Na-Tech accidental events

Natural events impacting on chemical and process plants may cause severe accidents, triggering the release of relevant quantities of hazardous substances. The present study focused on the development of the tools needed to build up a general framework allowing the extension of quantitative risk assessment procedure to include the analysis of the industrial accidents caused by natural events. Specific methods and models were developed to allow the quantitative assessment of risk caused by two categories of “Na-Tech” accidents: accidents triggered by earthquakes and accidents triggered by floods. The approach allows the identification of the different damage modes expected for process equipment and of the accidental scenarios that may be triggered. The damage models developed allow the calculation of the damage probability of equipment items due to the natural events. A specific methodology was issued to take into account the consequences of the possible contemporary failure of several process units due to the impact of the natural event. The procedure allows the calculation of the overall individual and societal risk indexes including the multiple-failure scenarios caused by the impact of natural events. The overall methodology was applied to the analysis of specific case studies.     

Flavonoids and furocoumarins distribution of unripe chinotto (<Emphasis Type="Italic">Citrus</Emphasis> × <Emphasis Type="Italic">myrtifolia Rafinesque</Emphasis>) fruit: beverage processing homogenate and juice characterization

The present study reports for the first time qualitative and quantitative data about flavonoids and furocoumarins distribution of unripe Citrus × myrtifolia Rafinesque homogenate, used as ingredient of the popular soft drink Chinotto. No data are available in literature about the chemical characterization of flavonoids and furocoumarins of the chinotto homogenate used to produce the industrial extract. Samples for analysis were therefore processed to better reproduce the crude materials used to obtain industrial chinotto extract: the whole fruits were cut in half, seeds removed, softly squeezed discarding part of the juice, and homogenized in small pieces. The polyphenolics separation was made by HPLC–PDA detector coupled to ESI/MS/MS in positive and negative mode. It has allowed the identification and relative quantification of 16 compounds, among which the flavone-C-glycoside lucenin-2, the 3-hydroxy-3-methylglutaryl flavanone glycoside melitidin and five polymethoxylated flavones have been detected for the first time in Citrus × myrtifolia. The flavonoids and furocoumarins distribution was compared with one of the Citrus × myrtifolia juice, and the antioxidant activity of both samples was assessed by ORAC (Oxygen Radical Absorbance Capacity)-fluorescein assay.     

Renewable energy benefits with conversion of woody residues to pellets

In the frame of an Interreg IIIC Network-Operation named RegEnergy, that unites 18 partners from 11 countries of Europe, the feasibility of using the woody by-products for heating purpose in a typical Mediterranean region was investigated. Focusing on the Abruzzo Region as representative sample area, it came out that a significant amount of the above mentioned renewable energetic material is annually available as a consequence of well-consolidated and economically significant agro-industrial activities, forest maintenance and industrial wood production and transformation. In particular, it was found that the total amount of woody residues, as dry substance, are more than 700 kt/a, with 30% resulting from pruning activities related to the cultivation of about 360 km² of vineyards and 450 km² of olive-groves; these residues are concentrated in the hilly part of the region close to the Adriatic sea coast. Starting by this pleasant situation, the feasibility of a properly localized wood pellets production plant was supported by both the economic and energetic analysis. Additional suggestions related to optimal plant localization and to the best use of the woody pellets as substitute of natural gas for heating purposes were reported along with the positive impact of the whole action on the quality of the environment and on the recovery of soil fertility.