Interactions between anthocyanins and organic food molecules in model systems

The interactions between different glucosidic anthocyanins (pelargonin, cyanin, delphinin, malvin and petunin) and some organic compounds (lactic, galacturonic, tannic, phenolic and sinapic acids; pyrogallol, furfural, pectin, cellulose, hydrolitic lignin) which are present in food‐stuffs were investigated at pH 3.0–4.3 and 25 °C. The interactions were monitored by means of u.v.‐VIS spectra and their different behaviours were highlighted by following changes in absorbance over a range of wavelengths (Δλ and ΔA). Significant effects on absorbance were detected and are discussed in terms of the phenomenon of co‐pigmentation.     

Communication via Mobile Vesicles in Brane Calculi

P systems and Brane calculi are two (families of) computational models inspired by the structure and the functioning of living cells. Although they have different goals there is a recent growing of interests in results that bridge the two research areas.Here we consider an important kind of communication based on the natural budding of mobile membranes (e.g., Golgi apparatus) that is already defined for P systems and we show how to construct an analogous communication in the basic Phago/Exo/Pino Brane calculus.     

Narratives of breast symptom discovery and cancer diagnosis: psychologic risk for advanced cancer at diagnosis

In spite of cancer screening programs, women continue to present with advanced breast cancer. How do women decide whether and when to seek an evaluation for self-discovered symptoms? This study examined 104 narratives told by 80 Anglo-, Latina-, and African-American women who participated in 1 of 16 community-based focus groups. The women's narratives contained powerful thematic messages about breast cancer and their expected behavior in the event of a self-discovered breast symptom. Narrative explanations that predicted an increased likelihood of advanced disease at diagnosis included these factors: incorrect symptom attributions and risk estimations; reluctance to consider the threat posed by the symptom; failure to tell another person about the symptom; and expectations of abandonment by male partners, deportation, prejudice, and refusal of treatment due to poverty. Stories of advanced breast cancer also told of reliance on alternative healing, concerns about overwhelming family resources, and extreme modesty that inhibited obtaining a physical examination. Interventions aimed at earlier detection of breast cancer must connect with the beliefs and assumptions embedded in these narratives, provide pragmatic solutions for perceived constraints on seeking evaluations of self-discovered symptoms, and explore the use of community narratives to confirm the value of early detection of breast cancer.     

A new three-parameter Corresponding States Model for pure Halocarbons Viscosity Prediction

Predictive and semipredictive models for viscosity calculation are currently needed and highly appreciated. Models developed for halogenated refrigerants (HR) and based on Corresponding States (CS) are leading to a prediction accuracy comparable to that of specifically developed models. In the present work, using recently published, highly accurate viscosity dedicated equations, it has been verified that viscosity conforms to a two-parameter CS model is then developed, based on Teja and coworker's three-parameter CS structure. Two fluids of the same family are taken for reference, and the reduced viscosity of a third fluid is obtained in reduced P,T variables. At first the Pitzer acentric factor is proposed as a third parameter, then it is substituted with a temperature-dependent function fitted on saturated viscosity data. The prediction accuracy of the model is comparable to that of the reference fluid equations and, considering its predictive nature, it is a satisfactory tool for the needs of technical applications.     

Colour-difference measurement: The sensitivity of various instruments compared

Because of the progress in electronic technology and the increasing importance of colour quality control in various branches of industry, over the last decades several colour-measuring instruments have been developed, each one with its own design features; the lack of standardization among them might be an obstacle to the spread of colour quality control as a means for product qualification. Colour-difference measurements taken with 11 different models of spectrophotometers [four with 45 (circumferential)/0 geometry and the others with diffuse geometry] were compared with the aim of analyzing their correlation and dispersion. In order to cover different colour-space regions, measurements were taken on test panels painted with four saturated basic hue (red, yellow, green, and blue) acrylic products gradually modified by adding white or black paint. Basic statistical analyses made on colour-difference values (ΔE*_ab, ΔL*, Δa*, and Δb*) resulted in a high correlation among the examined instruments, but a certain variability, particularly as far as certain hues are concerned.     

The pleistocene clastic deposits of the latium coast—Italy

Close to the present Latium coast, at Rio Torto, in the area between Pomezia and Ardea, about 35 km to the South of Rome, there are vast sandy deposits of continental and marine origin that may be associated with ancient coast lines. The extent and thickness of these deposits vary widely and are used as sources for extracting aggregate materials that are successfully used in preparing cement mortars. Field surveys and laboratory tests have helped identify these products as belonging to a paleogeographic environment and to define both their volume and their geographic location. The results obtained have allowed characterization of the sands from a technical point of view and to define their fields of utilization keeping account of their location and their mining availability.     

Synthesis,fluorescence emission spectra and chiroptical properties of copolymers of N-vinylcarbazole and optically active fumarates

Optically active (?)menthylethylfumarate (2) and (?)dimenthylfumarate (3) have been synthesised and free radically copolymerized with N-vinylcarbazole (1). Copolymers of (1) and (2) exhibit a strong tendency to alternation in agreement with earlier conclusions from studies of copolymerization of (1) with diethylfumarate. Surprisingly the much more hindered, but symmetrical fumarate, (3) yields copolymers which always have carbazole monomer contents in excess of the 1:1 alternating ratio. Chiroptical measurements indicate significant induced optical activity in the carbazole chromophores of all the copolymers obtained but, in accord with the predominance of alternating structures, there is no real evidence for any sequence-determined maximum in induced circular dichroism. Fluorescence emission spectra of all copolymer samples exhibit significant asymmetric broadening on the long wavelength (low energy) side of the normal carbazole monomeric emission. This broadening is exhibited even by poly (1-co-2) samples for which the monomer compositions strongly indicate alternating sequences and must, therefore, represent interaction between carbazole segments. Accordingly, and in contrast to widely held assumptions, it is concluded that excimer-like emission may be exhibited by alternating copolymers of N-vinylcarbazole. Further evidence for electronic interactions between non-nearest neighbour carbazole units is provided by u.v. absorption and ¹H-n.m.r. spectra of appropriate copolymers.     

Static and dynamic heterogeneities in water

The thermodynamic behaviour of water seems to be related to static heterogeneities. These static heterogeneities are related to the local structure of water molecules and, when properly characterized, may offer an economical explanation of thermodynamic data. 'What matters' most in determining some of the unusual properties of liquid water may be the fact that the local geometry of the liquid molecules is not spherical or oblong, but rather tetrahedral. In respect to static heterogeneities, this local geometry is critical. The dynamic behaviour of water seems to be related to dynamic heterogeneities, which seem to explain the dynamics of supercooled liquid water well.     

Composition and stability of phytochemicals in five varieties of black soybeans (Glycine max)

Phytochemical compositions of five varieties of black soybeans (Glycine max) and their stabilities at room temperature, 4 and −80 °C over 14 months were determined by HPLC systems with electrochemical (ECD) and UV detectors. Polyphenol profiling was carried out by a liquid chromatography–electrospray ionisation-mass spectrometry (LC–ESI-MS) with orbitrap as a mass analyser in both positive and negative ion modes, and polyphenols in aglycone forms were quantified by HPLC–ECD. Five different varieties of black soybeans (G. max) contained 249–405 μg/g dry wt of γ-tocopherol and 6.76–14.98 μg/g dry wt of lutein. Major polyphenols in black soybeans (G. max) were daidzein (193–288 μg/g dry wt) and genistein (145–223 μg/g dry wt), mainly present as glucosides and acetyl glucosides. No significant decrease was found in total phenols of black soybeans (G. max) stored at room temperature, 4 or −80 °C for 14 months. On the other hand, lutein and γ-tocopherol degraded significantly within a month of storage at room temperature (p < 0.01), whereas they remained stable up to 6 months at 4 °C and up to 14 months at −80 °C. The current study indicates that black soybeans (G. max) are rich source of γ-tocopherol and phenols (isoflavones, flavonols, flavan-3-ols, proanthocyanidins and anthocyanin) and that the levels vary depending upon varieties. In addition, storage at low temperature is recommended to reduce the loss of fat-soluble phytochemicals in black soybeans (G. max) over an extended period of time.     

Fast and air stable near-infrared organic detector based on squaraine dyes

In search for an organic material suitable for the detection of near-infrared electromagnetic radiation and at the same time capable of air stable operation of related devices, so to address the many applications envisaged with this technology (remote control, chemical/biological sensing, optical communication, spectroscopic and medical instruments), we explore the performance of a blend of hydrazone end-capped symmetric squaraines and phenyl C₆₁ butyric acid methyl ester. We succeed in developing air stable solution-processed devices with external quantum efficiency in the NIR as high as 3.5% and response times of few hundreds of nanoseconds. Essential to these achievements has been a detailed characterization of the devices performed by correlating the optoelectronic performances to the morphology of the layers (extracted from AFM measurements) and to the charge carrier mobility (extracted from transistor structures), enabling their optimization at the chemical level, by tailoring the squaraine substitution pattern, and at the device level, by tuning the blend composition. We show that a good balance between holes and electrons mobility is essential for high EQE and fast response speed, and that a smooth morphology is mandatory to achieve long term air stability and operability with no need for encapsulation.