Influence of Ultrasonic Oscillation on Static and Sliding Friction

Vibrations of varying frequency and amplitude are used in many technological areas to control and reduce friction. In this study we report the results of systematic high-precision measurements of the static and sliding friction under the influence of ultrasonic oscillations. We investigate the effect of ultrasonic oscillations for in-plane and out-of-plane oscillations in the completely relevant interval of oscillation amplitudes and sliding velocities and for various material pairings. The experimental results are interpreted on the basis of both macroscopic and microscopic models. There are two main effects which are of interest for tribological applications. Firstly, the frictional force typically decreases with increasing oscillation amplitude, with an oscillation amplitude of about 0.1???m typically being sufficient for a significant decrease of frictional force. Secondly, the decrease of force is larger at smaller sliding velocities; therefore, at sufficiently large oscillation amplitudes, the frictional force always increases with sliding velocity. This effect can be used to suppress frictionally induced vibrations.     

Simulating transient phenomena via residual free bubbles

We derive two stabilized methods for transient equations using static condensation of residual-free bubbles. The methods enhance the stability of the Discontinuous Galerkin method.     

A one-pot ultrasound-assisted water extraction/cyclodextrin encapsulation of resveratrol from Polygonum cuspidatum

The ultrasound-assisted extraction (UAE) of resveratrol and other polyphenols from Polygonum cuspidatum has been carried out with the aim of developing an efficient and eco-friendly extraction process. The finely milled roots were sonicated (titanium horn, 19.5 kHz) in methanol, in different cyclodextrin water solutions [β-cyclodextrin (β-CD) or hydroxypropyl β-CD (HPβ-CD)] and also in pure water. UAE dramatically increased the yields and cut down extraction times compared to conventional extraction under stirring. Outstanding results have been achieved with the β-CD solution (1.5% w/w); in fact HPLC analysis showed that the selective inclusion properties of CDs toward phenolic stilbenes gave a much cleaner analytical extract profile. This green method gave 7.51 mg of total resveratrol (free + cleaved polydatin glucoside) per gram of dry plant. Thanks to polyphenol encapsulation within CDs, this extract showed excellent water dispersibility, higher stability and an antioxidant power which is comparable to that of the MeOH extract (DPPH, ORAC_FL). These important features should pave the road for its application in food supplements or phytochemical preparations.     

Electrochemical hydrodehalogenation of polychloromethanes at silver and carbon electrodes

The reductive dehalogenation of CCl₄, CHCl₃, CH₂Cl₂ and CH₃Cl has been investigated by cyclic voltammetry and controlled-potential electrolysis at Ag, glassy carbon (GC) and graphite electrodes in dimethylformamide (DMF) + 0.1 M Et₄NClO₄ in the absence and presence of a proton donor. In particular, the study was focused in the evaluation of the intermediates and final products of the reduction process and how their distribution could be affected by tuning relevant chemical and electrochemical parameters. In general, depending on the value of the applied potential, all polychloromethanes (PCMs) can be partially or completely dechlorinated, methane being exclusively formed in the latter case. The nature of the electrode material and the proton availability of the medium affect drastically the distribution of reduction products. The results point out that at both types of electrode, reduction of PCMs takes place through two competing reaction pathways both leading to methane. One reaction route involves a sequence of reductive dehalogenation steps, with the removal of one chlorine atom at a time, whereas the other is based on hydrogenolysis of carbenes and bypasses the intermediacy of partially dechlorinated PCMs. The presence of a proton source affects substantially the hydrodehalogenation efficiency, enhancing the concentration of intermediate PCMs and the final yield of methane. The silver electrode exhibits an extraordinary electrocatalytic effect resulting in remarkable positive shifts of the reduction potentials of all PCMs with respect to GC. The Ag surface strongly affects the kinetics of the dissociative electron transfer to CH_nCl_(4−n) (n = 0–3) as well as the reactivity of the intermediate radicals, carbanions and carbenes.     

Gas phase complete catalytic oxidation of aromatic hydrocarbon mixtures

In this work oxidation of benzene and ethenylbenzene (IUPAC name for styrene) as single compounds and in binary mixtures over a Pt honeycomb catalyst were investigated. Both aromatic compounds showed zero-order kinetics over a wide concentration range. The ethenylbenzene reaction rate was affected weakly by the presence of benzene, whereas benzene oxidation was inhibited strongly by ethenylbenzene. The Mars-van Krevelen mechanism (which is generally accepted for single aromatic compound oxidation kinetics) gave rise to inconsistencies in describing mixture behaviour. A different kinetic model is proposed, where benzene reacts from the gas phase and ethenylbenzene is adsorbed on the catalyst competing with oxygen for active sites. This model was able to interpret the oxidation of mixtures quite satisfactorily.     

Ru-Containing Polymeric Catalysts for Cellulose Conversion to Polyols

In this paper Ru-containing catalysts based on hypercrosslinked polystyrene (MN-270) and its functional analogues (MN-100 and MN-500) were studied for the first time in cellulose hydrolytic hydrogenation. The catalysts were characterized using transmission electron microscopy (TEM), high resolution TEM, and porosity measurements. Catalytic studies demonstrated that the catalyst containing 1.0 % Ru and based on MN-270 is the most active. The total yield of sorbitol and mannitol was 50 % on the average at 85 % cellulose conversion.     

Capital-energy substitution in manufacturing for seven OECD countries: learning about potential effects of climate policy and peak oil

The simultaneous influence of increasing oil scarcity, greenhouse gas control and renewable energy targets will result in a future of sustained energy prices. Whether modern economies can find a smooth path away from fossil fuels is a fundamental socio-economic and political question, which according to standard economics depends to a large extent on the degree of substitution between energy and capital. We study this issue by modelling the manufacturing sector with a translog cost function in seven OECD countries using the EU-KLEMS database for the period 1970–2005. After a literature survey, different production structures accounting for input substitution, returns to scale and technical change are estimated, and substitution elasticities are derived. Our results indicate a general complementarity or weak substitution relationship between energy and capital, suggesting that an increase in energy price, e.g. due to climate policy or scarcer fossil fuels, will likely reduce capital inputs, which might lead to a lower output of manufacturing.