Modeling shallow marine carbonate depositional systems

Geological Process Models (GPMs) have been used in the past to simulate the distinctive stratigraphies formed in carbonate sediments, and to explore the interaction of controls that produce heterogeneity. Previous GPMs have only indirectly included the supersaturation of calcium carbonate in seawater, a key physicochemical control on carbonate production in reef and lagoon environments, by modifying production rates based on the distance from open marine sources. We here use the residence time of water in the lagoon and reef areas as a proxy for the supersaturation state of carbonate in a new process model, Carbonate GPM. Residence times in the model are calculated using a particle-tracking algorithm. Carbonate production is also controlled by water depth and wave power dissipation. Once deposited, sediment can be eroded, transported and re-deposited via both advective and diffusive processes. We show that using residence time as a control on production might explain the formation of non-ordered, three-dimensional carbonate stratigraphies by lateral shifts in the locus of carbonate deposition on timescales comparable to so-called 5th-order sea-level oscillations. We also show that representing supersaturation as a function of distance from open marine sources, as in previous models, cannot correctly predict the supersaturation distribution over a lagoon due to the intricacies of the flow regime.     

An examination of the relationship between workload and fatigue within and across consecutive days of work: Is the relationship static or dynamic?

Cognitive–energetical theories of information processing were used to generate predictions regarding the relationship between perceived workload and fatigue within and across consecutive days of work. Repeated measures were taken aboard a naval vessel from a sample of 20 Navy patrol vessel crew members during nonroutine and routine patrols. The hypotheses were tested through growth curve modeling. There was a nonmonotonic relationship between workload and fatigue in the routine patrol; moderate workload was associated with the lowest fatigue. The relationship between workload and fatigue changed over consecutive days in the nonroutine patrol. At the beginning of the patrol, low workload was associated with fatigue. At the end of the patrol, high workload was associated with fatigue. These results suggest that the optimal level of workload can change over time and thus have implications for the management of fatigue, particularly where prolonged operations are involved. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Effects of pH, ionic strength, dissolved organic matter, and flow rate on the co-transport of MS2 bacteriophages with kaolinite in gravel aquifer media

Viruses are often associated with colloids in wastewater and could be transported with colloids into groundwater from land disposal of human and animal effluent and sludge, causing contamination of groundwater. To investigate the role of colloids in the transport of viruses in groundwater, experiments were conducted using a 2 m long column packed with heterogeneous gravel aquifer media. Bacteriophage MS2 was used as the model virus and kaolinite as the model colloid. Experimental data were analyzed using Temporal Moment Analysis and Filtration Theory. In the absence of kaolinite colloid, MS2 phage traveled slightly faster than the conservative tracer bromide (Br), with little differences observed between unfiltered and filtered MS2 phage (0.22 μm as the operational cut-off for colloid-free virus). In the presence of kaolinite colloids, MS2 phage breakthrough occurred concurrently with that of the colloidal particles and the time taken to reach the peak virus concentration was reduced, suggesting a colloid-facilitated virus transport in terms of peak-concentration time and velocity. Meanwhile mass recovery and magnitude of concentrations of the phages were significantly reduced, indicating colloid-assisted virus attenuation in terms of concentrations and mass. Decreasing the pH or increasing the ionic strength increased the level of virus attachment to the aquifer media and colloids, and virus transport became more retarded, resulting in lower peak-concentration, lower mass recovery, longer peak-concentration time, and greater apparent collision efficiency. Increasing the concentration of dissolved organic matter (DOM) or flow rate resulted in faster virus transport velocity, higher peak-concentrations and mass recoveries, and lower apparent collision efficiencies. The dual-role of colloids in transport viruses has important implications for risk analysis and remediation of virus-contaminated sites.     

Studies of the copolymerisation of acrylic acid with n‐butyl vinyl ether

BACKGROUND: Copolymers of acrylic acid (AA) are important materials for the preparation of glass ionomer cements. Copolymerisation of AA is widely used to alter the acid strength of the material and to increase the number of salt bridges formed in cements. In this paper we report the copolymerisation of AA with n‐butyl vinyl ether (BVE) to form unique copolymers of the hemiacetal ester and with BVE incorporated into the main chain. RESULTS: AA and BVE undergo a spontaneous reaction to form a hemiacetal ester which can itself undergo free radical copolymerisation. The kinetics of this reaction in the bulk state have been examined. In addition, under these conditions BVE is incorporated into the polymer main chain via a free radical mechanism. CONCLUSION: Novel copolymers of the hemiacetal ester and BVE have been prepared in this study. The hemiacetal side chains are labile under moderate heating, being converted back to the acid analogue. Copyright © 2009 Society of Chemical Industry     

In vivo response of strontium and zinc-based ionomeric cement implants in bone

In this study the osteoconductive properties of strontium based ionomeric cements (ICs) named, LG125 and LG119, as well as zinc-based ICs, designated by LG130 and LG132, were compared. Wet ICs were surgically implanted into the femora of weaned Wistar rats for 4 weeks. To assess the percentage osseointegration the perimeter of the implant and the perimeter of bone in contact with the implant were measured using a pointer (the length of bone/implant interfacial contact). Osteoconduction was determined by taking six points at random around the perimeter of each ionomeric rod measuring the thickness of newly formed bone. The degree of osteoconduction was taken as the average thickness of new bone produced on the implant surface. It was found that osteoconduction was greatest in the strontium based IC implant LG125. From these studies it can be concluded that the composition LG125 might provide a useful purpose as a bone cement.     

Starting low but ending high: A reversal of the anchoring effect in auctions.

Counter to the "start high, end high" effect of anchors in individual judgments and dyadic negotiations, 6 studies using a diverse set of methodologies document how and why, in the social setting of auctions, lower starting prices result in higher final prices. Three processes contribute to this effect. First, lower starting prices reduce barriers to entry, which increase traffic and generate higher final prices. Second, lower starting prices entice bidders to invest time and energy (creating sunk costs) and, consequently, escalate their commitments. Third, the traffic generated by lower starting prices can lead bidders to infer value in the item, thereby explaining previous findings that traffic begets more traffic. The authors show that barriers to entry that limit traffic (e.g., a misspelled brand name) lead to anchoring's normal assimilative effect rather than its reversal. By broadening the understanding of anchors to extended social interactions and open markets, the authors identify when and why starting prices anchor. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Preferences of therapists-in-training for client characteristics.

The preferences of 132 therapists-in-training for 16 client characteristics were investigated using a paired comparison methodology. Therapists most preferred to work with clients who were psychologically minded, shared similar attitudes and values, and had dissimilar personally troubling problems. They least preferred to work with clients who were not psychologically minded, had dissimilar attitudes and values, and were older. Order of preferences was not influenced by therapist sex, race, clinical experience, socioeconomic status, sexual orientation, or theoretical orientation. Limitations of this study as well as implications for further research and training are discussed. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

隔爆型设备的新型材料--为安全避免火焰传播,采用多孔材料

用于危险场所的电气设备和保护系统按指令94／9／EC要求，必须设计为防爆型。按防爆要求，设备或保护系统，无论是在正常运行时或故障状态下，不能成为点燃源。在防爆技术发展的进程中，研究出了各种各样的保护方式，这些保护方式在欧洲协调标准中都有相应的规定。在一些保护方式中，如浇封型“m”，充砂型“q”，正压型“p”和油浸型“o”，采用适当的设计方法(保护措施)可以阻止可能产生点燃源的电气装置的部件与爆炸性环境接触；在增安型“e”和本安型“i”中，     

Use of coupled canopy structure dynamic and radiative transfer models to estimate biophysical canopy characteristics

Leaf area index (LAI) is a key variable for the understanding of several eco-physiological processes within a vegetation canopy. The LAI could thus provide vital information for the management of the environment and agricultural practices when estimated continuously over time and space thanks to remote sensing sensors.This study proposed a method to estimate LAI spatial and temporal variation based on multi-temporal remote sensing observations processed using a simple semi-mechanistic canopy structure dynamic model (CSDM) coupled with a radiative transfer model (RTM). The CSDM described the temporal evolution of the LAI as function of the accumulated daily air temperature as measured from classical ground meteorological stations.The retrieval performances were evaluated for two different data sets: first, a data set simulated by the RTM but taking into account realistic measurement conditions and uncertainties resulting from different error sources; second, an experimental data set acquired over maize crops the Blue Earth City area (USA) in 1998. Results showed that the proposed approach improved significantly the retrieval performances for LAI mainly by smoothing the residual errors associated to each individual observation. In addition it provides a way to describe in a continuous manner the LAI time course from a limited number of observations during the growth cycle.