Bimetallic Zeolite Catalyst for CO2 Reforming of Methane

The catalytic activity of Ni–Rh on the synthesized BEA zeolite in carbon dioxide reforming of methane has been investigated. Catalysts were prepared using the incipient wetness impregnation method, with a total content of metals up to 5 wt%. Catalysts were characterized through XRD, TPR, N₂ adsorption, SEM, AAS, TG/DSC analyses. The prepared Ni–Rh zeolites were tested for their catalytic activity at 700 °C, at atmospheric pressure, and at CH₄/CO₂ ratio of 1. Catalytic results showed that bimetallic based zeolites exhibit high activity (CH₄ and CO₂ conversion equal to 73 and 78, respectively) but monometallic Rh catalysts were the only one stable against coke formation.     

Interactions of human chorionic gonadotropin with genotype and parity on fertility responses of lactating dairy cows

Fertility-promoting effects of treatment of lactating dairy cattle with human chorionic gonadotropin (hCG) after artificial insemination (AI) have been variable. Here, we tested whether fertility response to hCG in lactating Holstein cows interacts with genotype and parity. Primiparous (n = 538) and multiparous (n = 613) cows were treated with hCG (3,300 IU) or vehicle 5 d after AI. Pregnancy was diagnosed on d 32 and 60 after AI. A subset of cows (n = 593–701) was genotyped for 4 single nucleotide polymorphisms (SNP) previously associated with fertility. Treatment with hCG increased progesterone concentration on d 12 after AI regardless of genotype or parity. Pregnancy per AI was improved by hCG in primiparous cows but not in multiparous cows. Moreover, hCG treatment interacted with a SNP in coenzyme Q9 (COQ9) to affect fertility. Fertility of cows treated with vehicle was greatest for the AA allele, whereas fertility was lowest for the same genotype among cows treated with hCG. Pregnancy per AI was also affected by genotype for heat shock protein A1-like (HSPA1L) and progesterone receptor (PGR), but no interactions were observed with treatment. Genotype for a SNP in prostate androgen-regulated mucin-like protein 1 (PARM1) was not associated with fertility. Overall, results show that variation in response to hCG treatment on fertility depends on parity and interacts with a SNP in COQ9.     

The Yellow River Basin: Water Accounting,Water Accounts,and Current Issues

Abstract

There is increasing recognition of the problems facing China in meeting the growing water demand in the Yellow River basin, the “cradle of Chinese Civilization” and a critically important agricultural and industrial region. Meaningful debate on the range and relative costs of options available to policy-makers in addressing the problem depend fundamentally on an accurate understanding of basin water resources. Unfortunately, the ability of outsiders to participate in the de bate and for Chinese, with their long history of water management, to contribute to similar discussions elsewhere in the world is hindered to some extent by a lack of understanding of differences in water accounting systems and concepts. This paper attempts to address this problem by describing the water accounting system used in the Yellow River basin and elsewhere in China. The paper shows that the primary difference between water accounting methodologies in the Yellow River and those typically applied elsewhere is related to supply accounting in general and groundwater accounting in particular. Although not currently included in its water accounting system, Chinese concepts of environmental water use, when included, will also differ substantially from those familiar to outside researchers. In terms of actual Yellow River balances, the paper highlights the apparent declining trend in basin rainfall and runoff and the dramatic growth in industrial and domestic water use. Together declining supply and rising demand will increasingly cause policy-makers to face hard choices in assessing their water planning options. These choices will only become more difficult as managers in the Yellow River, as elsewhere in the world, try to incorporate ecological needs in the water accounting equation.     

Optimal design of Service Overlay Networks with economic and performance constraints

In the last years, Service Overlay Networks (SONs) have emerged as a promising means to address some of the issues (e.g. end‐to‐end QoS) affecting the current Internet and to favor the development and deployment of new value‐added Internet services. The deployment of an SON is a capital‐intensive investment, since bandwidth with certain QoS guarantees must be purchased from the individual network domains through bilateral Service Level Agreements. Thus, minimizing the economic cost of the logical end‐to‐end service delivery infrastructure is one of the key objectives for the SON provider. When a SON is aimed at end‐to‐end QoS provisioning, its topology must be designed so as to also satisfy the specific requirements of QoS‐sensitive applications. This paper deals with the problem of planning the SON topology in order to take into account both cost and QoS constraints. More specifically, the paper proposes a set of new algorithms for the design of an optimized SON topology, which minimizes the economic cost while simultaneously meeting bandwidth and delay constraints. A performance comparison among such algorithms is finally carried out. Copyright © 2009 John Wiley & Sons, Ltd.     

Dietary krill oil increases docosahexaenoic acid and reduces 2-arachidonoylglycerol but not N-acylethanolamine levels in the brain of obese Zucker rats

Evidence suggests that dietary long chain polyunsaturated fatty acids (LCPUFAs), and particularly those belonging to the n-3 family, may influence the brain fatty acid profile and, thereby, the biosynthesis of endocannabinoids in rodents. However, the doses used are usually quite high and not comparable with human intake. Recently, we have shown that relatively low doses of dietary n-3 LCPUFAs (4 weeks), in the form of either fish or krill oil, balanced for EPA and DHA content, and against a control diet with no EPA and DHA and similar contents of oleic, linoleic and α-linolenic acids, lower the concentrations of the endocannabinoids, anandamide (AEA) and 2-arachidonoylglycerol (2-AG), in the visceral adipose tissue, and of AEA in the liver and heart, of obese Zucker rats. This, in turn, is associated with lower levels of arachidonic acid in membrane phospholipids and with amelioration of some metabolic syndrome parameters. We investigated here whether in Zucker rats, under the same conditions, fish and krill oil are also able to influence LCPUFA and endocannabinoid profiles in brain. Only krill oil was able to increase significantly DHA levels in brain phospholipids, with no changes in arachidonic acid. DHA increase was associated with lower levels of 2-AG in the brain, whereas AEA and its congeners, N-palmitoylethanolamine and N-oleoylethanolamine, were unchanged. We conclude that, despite the strong impact of dietary n-3 fatty acid on endocannabinoid levels previously observed in peripheral tissues, in the brain only 2-AG is affected by dietary krill oil, suggesting that the beneficial effect of the latter on the metabolic syndrome is mostly exerted by modifying peripheral endocannabinoids. Nevertheless, possible effects of dietary krill oil in the brain through modification of 2-AG levels deserve further investigation.     

Simulating the Response of Composite Plates to Fire

The present paper introduces a numerical study on the fire behavior of composites during exposure to a heating source at high incident power. A novel numerical model is proposed which is able to simulate the behavior of composite materials in fire environment providing the composites mass loss rate and heat release rate during heating source application. Two commercial software have been selected as platforms for the implementation of the proposed numerical model COMSOL and ANSYS. In COMSOL the model has been implemented by introducing proper field equations, while a macro, written in Ansys Parametric Design Language, has been used to allow the ANSYS FEM code to numerically simulate, by an incremental procedure, all the relevant physical phenomena related to fire. As an application, an experiment on thermal degradation over a laminated composite plate has been numerically simulated and the numerical model has been validated by comparing the COMSOL and Ansys numerical results to experimental literature data in terms of temperature profile over the panel thickness, Mass Loss Rate and Heat Release Rate. An excellent agreement has been found between the obtained numerical results and the experimental test data for both the adopted numerical platforms. However the ANSYS implementation, which showed to be the most effective in terms of accuracy of results and perspectives of applications to complex numerical models, led to the definition of a powerful tool able to assesses the fire performance of composite structures.     

Effects of boundary conditions on testing of pipes and finite element modelling

The design of many submarine pipelines, especially for operating in deep water, relies on accurate test results for the local buckling collapse of pipes subjected to bending loading. Recent test results have shown apparently anomalous values of axial tensile and compressive strains in comparison to the values that would be expected on the basis of simple bending theory. This could have important consequences for the efficacy of the design factors derived using these anomalous results. Examples of anomalous test results are given in the paper and the cause of the differences between the strain values obtained in the tests and those expected on the basis of simple bending theory are explained using finite element modelling.The major point is that the general application of the simplified engineering theory of bending can be erroneous when ovalisation is imposed or, on the contrary, the boundary conditions of the section are restrained from ovalising deformations.This is a crucial limit state for the design of onshore and offshore pipelines.     

Integration of acoustical information in the perception of impacted sound sources: The role of information accuracy and exploitability.

Sound sources are perceived by integrating information from multiple acoustical features. The factors influencing the integration of information are largely unknown. We measured how the perceptual weighting of different features varies with the accuracy of information and with a listener’s ability to exploit it. Participants judged the hardness of two objects whose interaction generates an impact sound: a hammer and a sounding object. In a first discrimination experiment, trained listeners focused on the most accurate information, although with greater difficulty when perceiving the hammer. We inferred a limited exploitability for the most accurate hammer-hardness information. In a second rating experiment, listeners focused on the most accurate information only when estimating sounding-object hardness. In a third rating experiment, we synthesized sounds by independently manipulating source properties that covaried in Experiments 1 and 2: sounding-object hardness and impact properties. Sounding-object hardness perception relied on the most accurate acoustical information, whereas impact-properties influenced more strongly hammer hardness perception. Overall, perceptual weight increased with the accuracy of acoustical information, although information that was not easily exploited was perceptually secondary, even if accurate. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Flicker noise measurement of HF quartz resonators

Frequency flicker of quartz resonators can be derived from the measurement of S(phi) (f), i.e., the power spectrum density of phase fluctuations phi. The interferometric method appears to be the best choice to measure the phase fluctuations of the quartz resonators because of its high sensitivity in the low power conditions, which is required for this type of resonator. Combining these two ideas, we built an instrument suitable to measure the frequency flicker floor of the quartz resonators, and we measured the stability of some 10-MHB high performance resonators as a function of the dissipated power. The stability limit of our instrument, described in terms of Allan deviation sigma(y)(tau), is of some 10(-14).