Abnormal manifestation of the high-temperature degradation of the weld metal of a low-alloy steel welded joint

We have shown that hardness, impact toughness, mechanical properties in tension, and the local parameters of fracture mechanics (static and cyclic crack resistance) are sensitive to the operating degradation of weld metal of steam pipelines of thermal power plants made of 15Kh1M1F steel. The simultaneous decrease in the resistance to brittle and plastic fracture (hardness, strength, and impact toughness) represents a phenomenon of the operating degradation of weld metal. We have established a specific correlation between the characteristics of plasticity and other mechanical parameters of operated metal: the increase in °₅ of operated weld metal is in good agreement with the decrease in its strength, whereas the reduction of Ψ correlates with the lowering of resistance to brittle fracture. Electrolytic hydrogenation decreases the characteristics of strength and plasticity of operated weld metal much stronger than in the initial state. The absence of ferritic edgings on the boundaries of primary austenitic grains makes for a low resistance to brittle fracture, and the change in acicular ferrite deteriorates the mechanical properties. The ductile fracture of nonoperated metal is replaced by brittle intercrystalline failure in operated metal. __________ Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 43, No. 1, pp. 73–79, January–February, 2007.     

苯酚羟基化合成苯二酚反应产物分离过程酚焦油的形成原因

对苯酚羟基化合成苯二酚产物分离过程酚焦油的形成原因进行了研究。模拟研究表明,在含有邻苯二酚和对苯二酚的混合溶液中,邻苯二酚比对苯二酚更易氧化缩合生成酚焦油。苯酚羟基化反应液中催化剂残留和催化剂被溶解形成的金属离子对酚焦油的形成具有促进作用;对苯醌的存在对酚焦油的生成具有促进作用;泄漏进入的氧或空气可加速苯二酚的氧化缩合反应;酚焦油生成量随常压脱水和减压精馏过程操作温度的升高、操作时间的延长而增加。醋酸能溶解催化剂活性组分,存在醋酸和金属离子残留问题,从而增加了羟基化反应产物分离过程酚焦油的生成量。在羟基化反应产物中加入Na2HSO3,使羟基化反应产物中的对苯醌还原,同时减少羟基化反应产物中的溶解氧含量,从而起到了抑制脱水和精馏过程中酚焦油生成的作用。     

综采供电计算机辅助设计系统

文章简要介绍了综采供电计算机辅助设计系统的开发工具和主要功能。     

DS／FH／TH混合扩频系统抗干扰性能的计算机模拟

在扩频通信中,抗干扰性能是评价扩频通信体制优劣的重要指标。本文研究DS/FH/TH混合扩频系统的抗干扰性能,建立了系统模型及计算机模拟方案,通过计算机模拟获得了在连续波、脉冲波多音干扰、部分带宽干扰、脉冲噪声干扰情况下的系统误码率曲线,具有一定的实用价值。     

PbS与PbO及硅酸铅反应的动力学和PbO的活度

为了阐明QSL法直接炼Pb的化学反应动力学,研究PbS与PbO及xPbO·SiO_2的交互作用是具有实际意义的。为了避免高温造成PbS和PbO的挥发损失,在较低温度下研究该体系的交互反应动力学,对探索火法炼Pb新工艺具有一定价值。试料是分析纯PbO,PbS和合成的纯xPbO·SiO_2,试料粒度均为100—120 mesh,在配比试样中以PbO:PbS=2:1作基础并混匀,以便保证按化学计量反应产生SO_2。装有试料的刚玉坩埚在密封竖直刚玉管底部低温区用Ar气保护升温加热,待达到预期温度后,坩埚由密封系统中的活动撑杆推到高温区并同时用Ar气载流使产生的SO_2连续为碘量法所测     

Some aspects of twist drill design

A mathematical approach to the flute disposal capacity based on the diameter of the circle which could be inscribed in the flute space is presented. It is important to know what order of drill rigidity is required for good performance when drilling various work materials. The main features of the cross-section profile which could affect the stiffness of a twist drill are the cross-sectional area and the second moment of area. The relationship between the various drill parameters and these features is one aspect to be investigated in this paper. Empirical equations based on the results obtained from this investigation are presented.     

On the determination of the stacking fault energy from extended nodes in Cu2NiZn

Stacking fault energies can be determined from the dimensions of extended dislocation nodes. Different theoretical treatments of the node problem have been published. The aim of the present paper is to compare the results obtained using the theories of Brown and Thöléen, Siems and Jøssanget al and to provide quantitative information about the dependence of the stacking fault energy for Cu₂NiZn on the model used. Extended nodes in networks with mesh size larger than the outer radius of the node (R) can be used for the determination of the stacking fault energy. Isolated nodes as well as network nodes are used to obtain the stacking fault energy in Cu₂NiZn, which appeared to be 33 ± 9 mJ/m².