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Structural and Multidisciplinary Optimization - As the frontier of modern-day engineering challenges pushes forward, the integration of multiple strategies to reduce manufacturing cost and increase... 相似文献
54.
Ion mobility spectrometers (IMS) are small, lightweight, extremely robust devices with low power requirements, no moving parts, no absolute requirement for gases or vacuums, that can be operated at
ambient temperatures and pressures, and yet are capable of measuring vapour phase concentrations of organic chemicals at very low levels (sub-μg/l). IMS are capable of analysing complex mixtures and producing a simple spectral output. Volatile components produce measurable negative and positive product ions in the spectrometer through chemical ionization. The spectra produced are essentially the vapour phase fingerprints of the target molecules/mixture. Quantitative data can be obtained provided instrument response is within the linear dynamic range of these instruments, but most practical applications of IMS have used the technology in a qualitative manner in situations which require just an above/below threshold or positive/ negative response.In the manufacturing industry there are many examples where the aroma/odour of raw materials has safety or product quality implications. IMS was not developed to replace traditional methods of analysis, e.g. GC/MS or sensory panels, but rather to provide a rapid, qualitative response complementary to more established methods. This paper reports on the use of a hand-held ion mobility spectrometer to characterize the vapours produced by volatile organic compounds,fresh herbs and retail spice mixtures at ambient temperature and pressure. The results show that by monitoring in both ion acquisition modes, ion mobility spectrometers are capable of discriminating between a wide range of products. 相似文献
55.
Effect of ammonium chloride on leaching behavior of alkaline anion and sodium ion in bauxite residue
Yi-wei LI Jun JIANG Sheng-guo XUE Graeme J. MILLAR Xiang-feng KONG Xiao-fei LI Meng LI Chu-xuan LI 《中国有色金属学会会刊》2018,28(10):2125-2134
This study focused on leaching behavior of alkaline anion and sodium in bauxite residue through ammonium chloride treatment. The results showed that the pH of bauxite residue decreased from 10.49 to 8.93, total alkaline anion (
, OH?,
) concentration reduced from 38.89 to 25.50 mmol/L, leaching rate of soluble sodium was 80.86% with ammonium chloride addition of 0.75%, liquid/solid (L/S) ratio of 3 (mL/g), temperature of 30 °C and reaction time of 18 h; L/S ratio was the main factor affecting the removal of alkaline anion and the leaching of sodium. Furthermore, ammonium chloride promoted the dissolution of diaspore and changed the micro/morphological characteristics with the increase of massive structure. The findings of this work will contribute to achieve soil-formation of bauxite residue. 相似文献
56.
Anna Sulley Kathrine Osborn Lorenz James S. Wolffsohn Graeme Young 《Contact lens & anterior eye》2017,40(4):248-252
Purose
To calculate theoretical fitting success rates (SR) for a range of typical soft contact lens (SCL) designs using a mathematical model.Method
A spreadsheet mathematical model was used to calculate fitting SR for various SCL designs. Designs were evaluated using ocular topography data from 163 subjects. The model calculated SR based on acceptable edge strain (within range 0–6%) and horizontal diameter overlap (range 0.2–1.2 mm). Where lenses had multiple base curves (BCs), eyes unsuccessful with the steeper BC were tested with the flatter BC and aggregate SR calculated. Calculations were based on typical, current, hydrogel and silicone hydrogel SCLs and allowed for appropriate on-eye shrinkage (1.0–2.3%). Theoretical results were compared with those from actual clinical trials.Results
Theoretical success rates for one-BC lenses ranged from 60.7% (95% CI 7.2%) to 90.2% (95% CI 3.7%). With two-BC designs, most combinations showed a SR increase with a second BC (84.0%–90.2%). However, one of the two-BC combinations showed only negligible increase with a second BC (72.4%–73.0%). For designs with lower SR, the greatest contributor to failure was inadequate lens diameter. For a given design, differences in shrinkage (i.e. on-eye bulk dehydration) had a significant effect on success rate. In comparison with historical clinical data, there was a positive correlation between small lens fitting prevalence and discomfort reports (r = + 0.95, P = < 0.001) with a poor correlation between theoretical and actual tight/loose fittings.Conclusions
Mathematical modelling is a useful method for testing SCL design combinations. The results suggest that judicious choice of additional fittings can expand the range of fitting success. 相似文献57.
A method is presented for determining the optimal autoclave temperature history for pre-impregnated thermoset composites based
on their failure performance. A coupled finite-element model that incorporates a thermochemical and incremental elastic analysis
is used to predict the residual stress distribution at the edge of a thick composite beam. The optimal autoclave temperature
is sought using a gradient-based optimization algorithm. The objective is designed to maximize the minimum failure load of
the manufactured beam amongst a set of load cases, while the constraints are imposed to ensure that the composite is uniformly
cured and does not sustain temperature damage during the manufacturing process. The hybrid-adjoint, a novel semi-analytic
gradient evaluation technique is developed, that incorporates elements of both the adjoint and direct sensitivity methods.
Results demonstrate that the method is highly accurate and competitive with a full adjoint approach for a moderate number
of design variables. 相似文献
58.
David A. X. Nayagam Richard A. Williams Jun Chen Kylie A. Magee Jennifer Irwin Justin Tan Peter Innis Ronald T. Leung Sue Finch Chris E. Williams Graeme M. Clark Gordon G. Wallace 《Small (Weinheim an der Bergstrasse, Germany)》2011,7(8):981-981
In vivo host responses to an electrode‐like array of aligned carbon nanotubes (ACNTs) embedded within a biopolymer sheet are reported. This biocompatibility study assesses the suitability of immobilized carbon nanotubes for bionic devices. Inflammatory responses and foreign‐body histiocytic reactions are not substantially elevated when compared to negative controls following 12 weeks implantation. A fibrous capsule isolates the implanted ACNTs from the surrounding muscle tissue. Filamentous nanotube fragments are engulfed by macrophages, and globular debris is incorporated into the fibrous capsule with no further reaction. Scattered leukocytes are observed, adherent to the ACNT surface. These data indicate that there is a minimal local foreign‐body response to immobilized ACNTs, that detached fragments are phagocytosed into an inert material, and that ACNTs do not attract high levels of surface fouling. Collectively, these results suggest that immobilized nanotube structures should be considered for further investigation as bionic components. 相似文献
59.
Graeme A. Leiper 《Journal of Energetic Materials》2013,31(4-5):381-404
Abstract An analysis has been developed for the Ballistic Mortar test based on classical mechanics and a two stage chemical reaction rate model. Non-ideal behaviour of the composition was modelled by partial energy release during the detonation phase and secondary exothermic processes during the expansion phase. Erosive grain burning and time delayed reactions were both considered. Gas loss from the mortar cavity due to leakage was included. Predicted mortar performance of several ideal and non-ideal explosives were in good agreement with experimental values. The effects of slow and incomplete reaction of non-ideal compositions have been demonstrated, and it has been shown that measurement of mortar throw angle alone is insufficient to determine the performance of a composition. The model has been used to elucidate the reaction rate behaviour of Ammonium Nitrate and Aluminium in commercial explosives. 相似文献
60.
Abstract Detonation velocity/cartridge diameter measurements have been made on a series of emulsion explosives containing three size fractions of sieved glass microballoons and at two composition density ranges. The data is analysed using a slightly divergent flow code. The results show the interaction between the kinetics and hydrodynamics of the detonation process. 相似文献