Photodegradation of polypropylene containing a nucleating agent

The effect of including 0.5 wt % talc on the photodegradation behavior of polypropylene (PP) was investigated in injection-molded samples exposed to ultraviolet radiation (UV) in the laboratory for periods of up to 24 weeks. The structure of the talc-nucleated samples was characterized by X-ray diffraction and light microscopy and compared with that of nonnucleated PP, and the information was used to explain the differences in their photodegradation behavior. Measurements of the extent of chemical degradation were made by Fourier transform infrared spectroscopy (FTIR) and gel permeation chromatography (GPC), and they showed that there is no significant effect of a nucleating agent on the kinetics of photooxidation. PP bars containing a nucleating agent showed a larger reduction in mechanical properties with UV exposure and a partial recovery in properties after prolonged exposure was observed with both types of samples. An increase in crystallinity during UV exposure (chemicrystallization) was detected by X-ray diffraction and differential scanning calorimetry (DSC) and the dependence with exposure time was similar in nucleated and nonnucleated samples. DSC was also used to determine the melting behavior and transition temperatures of the specimens during exposure and after recrystallization from the melt. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 64: 2505–2517, 1997     

Autonomous mobile robot global self-localization using Kohonen and region-feature neural networks

This article presents and compares two neural network-based approaches to global self-localization (GSL) for autonomous mobile robots using: (1) a Kohonen neural network, and (2) a region-feature neural network (RFNN). Both approaches categorize discrete regions of space (topographical nodes) in a manner similar to optical character recognition (OCR). That is, the mapped sonar data assumes the form of a character unique to that region. Hence, it is believed that an autonomous vehicle can determine which room it is in from sensory data gathered from exploration. With a robust exploration routine, the GSL solution can be time-, translation-, and rotation-invariant. The GSL solution can also become independent of the mobile robot used to collect the sensor data. This suggests that a single robot can transfer its knowledge of various learned regions to other mobile robots. The classification rate of both approaches are comparable and, thus, worthy of presentation. The observed pros and cons of both approaches are also discussed. © 1997 John Wiley & Sons, Inc.     

Exploiting Airline Reservation Technologies to Improve Navy Training Management

The Navy trains hundreds of thousands of students every year. For Navy training, yield management means offering the right school seats to the right customers (e.g. active duty, reservists, foreign nationals) at the right time to maximize fleet readiness. The yield management methods will permit the Navy to make the best use of its limited training resources. This paper discusses the yield management technologies that will be tightly integrated into the Navy's new on-line training seat reservation system.     

Some aspects concerning modelling the flow and heat transfer in horizontal mantle heat exchangers in solar water heaters

An experimental and numerical investigation has been undertaken to study the heat transfer process in horizontal mantle heat exchangers used in solar water heaters. A rectangular cavity has been used as a simplified geometry. With the aid of particle image velocimetry (PIV) the flow field in the centre‐plane of the rectangular cavity has been visualized. Three‐dimensional flow simulations were performed using a commercial CFD package. The impinging jet formed by the inlet flow directed towards the opposite wall was found to produce localised turbulence in the cavity, with an inlet Reynolds number as low as 360. This turbulence was found to effect the flow field and heat transfer in the cavity when the inlet Reynolds number was above 1200. It is shown that, with the boundary conditions used in this study, most of the heat transferred was in the bottom half of the cavity. This is not the ideal situation for optimization of solar water heating systems. Copyright © 1999 John Wiley & Sons, Ltd.     

The Relational Aspect to High Reliability Organization

The literature on ‘high reliability organizations’ demonstrates how central reliability is to organizing in certain highly demanding settings. In more mundane settings, however, where there may not be a dominant type of catastrophic failure, the meaning attributed to reliability is less likely to be unambiguous and consensual. It is more likely to be explicitly relational: a quality of the relationship between an entity that is being relied on and an entity that is relying on it. This draws attention to the importance of the relying process in contributing to how a system performs and whether it meets expectations. A field study was carried out in a highway construction and maintenance organization to analyse the various understandings of reliability that organizational members had in different contexts. It found that there were multiple understandings – involving a capacity not only to achieve particular outcomes but also comply with norms, fit behaviour to situations, and communicate about what could and could not be achieved. It also found that reliability problems were not solved in some simple sense. Instead they were transformed into other reliability problems that then had to be managed by further effort or by other organizations. We suggest that recognizing the multiple meanings of reliability, the importance of relying, and the way in which reliability problems are transformed from one form to another all have important practical implications.     

A set of electrophoretic molecular markers for strain typing and population genetic studies of Histoplasma capsulatum

A set of eleven biallelic and three multiallelic molecular markers have been developed to analyze populations of Histoplasma capsulatum. All markers are amplified by polymerase chain reaction (PCR) and can be readily scored using minimal amounts of template DNA. The 11 biallelic loci have polymorphic restriction endonuclease sites or small insertions or deletions which may be assessed by agarose gel electrophoresis. These markers are inherited in an unambiguous manner and are ideal for assessing structure and gene flow within US populations of H. capsulatum, but are monomorphic in non-US populations. Both length and sequence variation are present in the multiallelic loci, which can be scored by direct sequencing, polyacrylamide gel electrophoresis, or single-strand conformation polymorphism (SSCP): As they are hypervariable, the multiallelic loci can be used to type isolates and to assess the level of genetic variation within populations. Preliminary results indicate that the three multiallelic markers presented are sufficient to distinguish isolates at the individual level and are polymorphic in both US and non-US populations. This collection of molecular markers will be a useful tool in population and epidemiology studies of H. capsulatum.     

Covalent cross-linking of erythrocyte spectrin by carbon disulfide in vivo

The effects of inflation, generic competition, market introduction of new drug entities, and recent legislation on forecasting drug expenditures are discussed. Inflation as it relates to pharmaceutical prices has been decreasing over the past couple of years. The U.S. Bureau of Labor Statistics reported a 6.9% increase in the Producer Price Index for drugs and pharmaceuticals in 1991, diminishing to a 4.5% increase for part year 1992. Pharmaceutical industry analysts predict overall annual inflation rates for pharmaceuticals in 1993-94 will range from 2% to 11%. Explanations for the recent low inflation rates and the wide variance among analysts may include the uncertainty of future government regulation on price increases and the backlog of FDA approvals for biotechnologically derived agents. To evaluate generic competition, information on patent or market exclusivity expiration can be used. The price of a generic drug may be 60-70% of the brand price at market introduction, but it usually stabilizes at approximately 50% of the list price. Predicting the market entry of new drug products is difficult and requires monitoring of (1) filing dates for new drug applications (NDAs) and (2) changes within the FDA approval process. According to an FDA report, the mean time to approval for an NDA in 1991 was 28.5 months and for a new molecular entity was 30.03 months. These figures represent little change from the previous five years.(ABSTRACT TRUNCATED AT 250 WORDS)