MO-Berechnungen an substituierten Sydnonen. III. Quantenchemische Charakterisierung UV-spektroskopisch beobachteter angeregter Zustände von Sydnonazomethinen

MO Calculations on Substituted Sydnones. III. Quantumchemical Characterization of Sydnone Azomethine Exited States Observed by U.V. Spectroscopy The recorded electronic spectra of sydnone azomethines are analysed using the results of PPP-type calculations. The assumption of twisting at the azomethine nitrogen atom analogously to benzalaniline is in accord with the results. Starting from the electronic structure of sydnone and by comparison with benzalanile and sydnone ethylene, the following points are discussed: the influence of substituents at position 3 of sydnone (R³ = CH₃, C₆H₅, p-CH₃OC₆H₄), the extension of the π-electron system in position 4, Z—E isomerism, and negative solvatochromism. It is shown that systems with peculiar characteristic properties are obtained by connection of sydnone and the azomethine group. The photochemical consequences of the calculated electronic structures are discussed.     

Uncertainty Management in the Unit Commitment Problem

Uncertainty in power systems operations has been traditionally managed by multistage decision making and operating reserve requirements. A familiar example of multistage decisions is day-ahead unit commitment and real-time economic dispatch. An alternate approach for managing uncertainty is a stochastic formulation, which allows the explicit modeling of the sources of uncertainty. This paper compares stochastic and reserve methods and evaluates the benefits of a combined approach for the efficient management of uncertainty in the unit commitment problem. Numerical studies show that unit commitment solutions obtained for the combined approach are robust and superior with respect to the traditional approach in terms of both economics and reliability metrics.     

A generalized Gaussian image model for edge-preserving MAPestimation

The authors present a Markov random field model which allows realistic edge modeling while providing stable maximum a posterior (MAP) solutions. The model, referred to as a generalized Gaussian Markov random field (GGMRF), is named for its similarity to the generalized Gaussian distribution used in robust detection and estimation. The model satisfies several desirable analytical and computational properties for map estimation, including continuous dependence of the estimate on the data, invariance of the character of solutions to scaling of data, and a solution which lies at the unique global minimum of the a posteriori log-likelihood function. The GGMRF is demonstrated to be useful for image reconstruction in low-dosage transmission tomography.     

Exact radon rebinning algorithm for the long object problem in helical cone-beam CT

This paper addresses the long object problem in helical cone-beam computed tomography. We present the PHI-method, a new algorithm for the exact reconstruction of a region-of-interest (ROI) of a long object from axially truncated data extending only slightly beyond the ROI. The PHI-method is an extension of the Radon-method, published by Kudo, Noo, and Defrise in issue 43 of journal Physics in Medicine and Biology. The key novelty of the PHI-method is the introduction of a virtual object fpsi(x) for each value of the azimuthal angle psi in the image space, with each virtual object having the property of being equal to the true object f(x) in some ROI omegam. We show that, for each psi, one can calculate exact Radon data corresponding to the two-dimensional (2-D) parallel-beam projection of fpsi(x) onto the meridian plane of angle psi. Given an angular range of length pi of such parallel-beam projections, the ROI omegam can be exactly reconstructed because f(x) is identical to fpsi(x) in Omegam. Simulation results are given for both the Radon-method and the PHI-method indicating that 1) for the case of short objects, the Radon- and PHI-methods produce comparable image quality, 2) for the case of long objects, the PHI-method delivers the same image quality as in the short object case, while the Radon-method fails, and 3) the image quality produced by the PHI-method is similar for a large range of pitch values.     

Compact digitally tunable laser

We present a new design for a digitally tunable laser using two waveguide grating routers with different free spectral range. For an N-channel device, both the number of required amplifiers and the number of required grating arms scale as the square root of N, resulting in a more compact device than previously demonstrated and better scaleability. Contrary to previously demonstrated devices with a reduced number of amplifiers, all wavelength channels are multiplexed together in one common channel, allowing for a higher output power. Tuning speeds below 10 ns are envisioned. Experimental results are presented.     

A 90-nm CMOS Low-Power GSM/EDGE Multimedia-Enhanced Baseband Processor With 380-MHz ARM926 Core and Mixed-Signal Extensions

To meet the widely varying speed and power requirements of multifunctional mobile devices, an appropriate combination of technology features, circuit-level low-power techniques, and system architecture is implemented in a GSM/Edge baseband processor with multimedia and mixed-signal extensions. Power reduction techniques and performance requirements are derived from an analysis of relevant use cases and applications. The 44 mm² baseband processor is fabricated in a 90-nm low-power CMOS technology with triple-well option and dual-gate oxide core devices. The ARM926 core achieves a maximum clock frequency of 380 MHz at 1.4-V supply due to the usage of thin oxide (1.6 nm) devices. Power dissipation can be adapted to the performance requirements by means of combined voltage and frequency scaling to reduce active power consumption in medium-performance mode by 68%. To reduce leakage currents during standby mode, large SRAM blocks, nFET sleep transistors, and circuit components with relaxed performance requirements are implemented using devices with 2.2-nm gate oxide thickness     

40 Gbit/s RZ wavelength converter in a monolithically integrated chip with a tunable laser

An all-optical wavelength-switch module with 40 Gbit/s capacity is integrated monolithically in InP. The device combines an SOA-based wavelength converter and a fast-tunable 8-channel multi-frequency laser. Error-free operation is demonstrated.     

An excursion into classical nonlinear acoustics

This paper is concerned with the derivation of the partial differential equations that govern the propagation of sonic disturbances in an ideal gas under isentropic conditions. The result is a quasilinear hyperbolic system of first order equations and an inequality constraint. The speed of propagation is pressure dependent. It is shown how to deal with the equations and the constraint and how to calculate characteristics and solutions. It is also shown that shock discontinuities can develop which distinguishes the equations from the traditional linear wave equation.     

The busbar system for Wendelstein 7-X prepared for assembly and operational loads

Forschungszentrum Jülich has taken over the design, manufacturing and assembly of the superconducting busbar system for the stellarator Wendelstein 7-X. This includes the busbars itself, the support structure consisting of supports and clamps, and the joints for electrical and hydraulic connection of the busbars and coil terminals. Apart from providing the required electrical connection scheme, the busbar system has to be designed for relevant electrical and mechanical loads. Numerous interfaces and geometric boundary conditions define the confined space to accommodate the busbars and their support elements. This article describes how the individual challenges to engineering have been met in the course of the project. This includes design concepts and the method for iterative design of supports with respect to the individual load distribution caused by the supports itself.     

The effect of water on the tensile yield of polystyrene

When PS is tested in tension but immersed in water the yield stress is unchanged and the crazing stress is increased, as compared with tests conducted in air. The crazing pattern is otherwise unchanged. If the PS is first equilibrated with water and then tested under water, both crazing stress and yield stress are reduced. A very large number of small crazes are generated which result in a 23% increase in the fracture strain.