Zirconium Diboride with High Thermal Conductivity

Thermal properties were characterized for zirconium diboride produced by reactive hot pressing and compared to ZrB₂ ceramics that were hot pressed from commercial powders. No sintering additives were used in either process. Thermal conductivity was calculated from measured values of heat capacity, thermal diffusivity, and density for temperatures ranging from 298 to 2273 K. ZrB₂ produced by reactive hot pressing achieved near full density, but had a small volume fraction of ZrO₂, whereas hot‐pressed ZrB₂ contained porosity and carbon inclusions. Reactive hot pressing produced a ceramic with higher thermal diffusivity and heat capacity, resulting in thermal conductivities of 127 W·(m·K)^?1 at 298 K and 80 W·(m·K)^?1 at 2273 K, which were up to ~30% higher than typically reported for hot‐pressed ZrB₂.     

Peripheral Artery Disease Is Associated with a Deficiency of Erythrocyte Membrane n-3 Polyunsaturated Fatty Acids

Population-based data suggest that individuals who consume large dietary amounts of n-3 polyunsaturated fatty acids (PUFA) have lower odds of peripheral artery disease (PAD); however, clinical studies examining n-3 PUFA levels in patients with PAD are sparse. The objective of this study is to compare erythrocyte membrane fatty acid (FA) content between patients with PAD and controls. We conducted a cross-sectional study of 179 vascular surgery outpatients (controls, 34; PAD, 145). A blood sample was drawn and the erythrocyte FA content was assayed using capillary gas chromatography. We calculated the ratio of the n-3 PUFA eicosapentaenoic acid (EPA) to the n-6 PUFA arachidonic acid (ARA) as well as the omega-3 index (O3I), a measure of erythrocyte content of the n-3 PUFA, EPA, and docosahexaenoic acid (DHA), expressed as a percentage of total erythrocyte FA. Compared with controls, patients with PAD smoked more and were more likely to have hypertension and hyperlipidemia (p < 0.05). Patients with PAD had a lower mean O3I (5.0 ± 1.7% vs 6.0 ± 1.6%, p < 0.001) and EPA:ARA ratio (0.04 ± 0.02 vs 0.05 ± 0.05, p < 0.001), but greater mean total saturated fats (39.5 ± 2.5% vs 38.5 ± 2.6%, p = 0.01). After adjusting for several patient characteristics, comorbidities, and medications, an absolute decrease of 1% in the O3I was associated with 39% greater odds of PAD (odds ratio [OR] 1.39, 95% confidence interval [CI] 1.03–1.86, and p = 0.03). PAD was associated with a deficiency of erythrocyte n-3 PUFA, a lower EPA:ARA ratio, and greater mean total saturated fats. These alterations in FA content may be involved in the pathogenesis or development of poor outcomes in PAD.     

Synthesis of a PPV‐fluorene derivative: Applications in luminescent devices

Synthesis of a polyfluorene/poly(p‐phenylene vinylene) derivative, the Poly [(9,9′‐di‐hexylfluorenediylvinylene‐alt‐1,4‐phenylenevinylene)‐co‐((9,9′‐(3‐t‐butylpropanoate) fluorene‐1,4‐phenylene)] (LaPPS 42) was performed following Wittig and Suzuki routes. Polyfluorenes and derivatives have been used in electroluminescent devices, and the synthesis described here has the advantage in pave the way to get distinct structures having different emission spectra. An extensive study of its electrochemical, thermomechanical, optical, and structural properties was carried out, as well as its application in electroluminescent devices. Polymer light‐emitting diodes (PLEDs) and polymer light‐emitting electrochemical cells (PLECs) were built using LaPPS 42 as active layer, and their electric and optical characterizations confirm they have a potential as active element in electroluminescent devices. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42579.     

Torrefied biomass‐polypropylene composites

Torrefied almond shells and wood chips were incorporated into polypropylene as fillers to produce torrefied biomass‐polymer composites. The composites were prepared by extrusion and injection molding. Response surface methodology was used to examine the effects of filler concentration, filler size, and lignin factor (relative lignin to cellulose concentration) on the material properties of the composites. The heat distortion temperatures, thermal properties, and tensile properties of the composites were characterized by thermomechanical analysis, differential scanning calorimetry, and tensile tests, respectively. The torrefied biomass composites had heat distortion temperatures of 8–24°C higher than that of neat polypropylene. This was due to the torrefied biomass restricting mobility of polypropylene chains, leading to higher temperatures for deformation. The incorporation of torrefied biomass generally resulted in an increase in glass transition temperature, but did not affect melting temperature. Also, the composites had lower tensile strength and elongation at break values than those of neat polypropylene, indicating weak adhesion between torrefied biomass and polypropylene. However, scanning electron microscopy results did indicate some adhesion between torrefied biomass and polypropylene. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41582.     

Response of isotopically tailored titanium diboride to neutron irradiation

The response of polycrystalline TiB₂ to neutron irradiation was investigated. The material was fabricated using isotopically enriched ¹¹B powders to minimize helium production via the ¹⁰B(n, α)⁷Li reaction. Neutron irradiation was conducted at temperatures of ~200°C and ~600°C to a fast fluence of 2.4 × 10²⁵ n/m² (>0.1 MeV). The material exhibited some swelling, but less swelling at the higher irradiation temperature. No macroscopic damage was observed in the irradiated material, although moderate irradiation-induced micro-cracking was found in the irradiated TiB₂. This study demonstrated improved radiation resistance of isotopically tailored TiB₂ compared with natural boron TiB₂, which exhibited macroscopic fracture by irradiation.     

Experimental study on the time-dependent dynamic mechanical behaviour of C60 concrete under

To study the dynamic mechanical behavior of C60 concrete at high temperatures, impact tests under different steady-state temperature fields (100, 200, 300, 400 and 500.℃) were conducted under a variety of durations at the corresponding constant high temperature, namely 0, 30, 60, 90 and 120.min, employing split Hopkinson pressure bar (SHPB) system. In addition, the impact tests were also conducted on the specimens cooled from the high temperature to the room temperature and the specimen under room temperature. From the analysis, it is found that C60 concrete has a time-dependent behavior under high-temperature environment. Under 100, 200, 300, 400 and 500.℃ steady-state temperature fields respectively, as the duration at the corresponding constant high temperature increases, the dynamic compressive strength and the elastic modulus decrease but the peak strain generally ascends. After cooling to the room temperature, the dynamic compressive strength and the elastic modulus descend as well, but the peak strain increases first and then decreases slightly, when the duration increases. For specimens under and cooled from the high-temperature, as the temperature increases, the dynamic compressive strength and the peak strain raise first and then reduce gradually,and the dynamic compressive strength of specimen under high temperature is higher than that of the specimen cooled from the same high temperature.     

Rating group therapist interventions: The validation of the Group Psychotherapy Intervention Rating Scale.

The present study seeks to establish the validity of the Group Psychotherapy Intervention Rating Scale (GPIRS), an observer-rated measure of the quality of group leader interventions. Concurrent validity was tested by comparing GPIRS results to 2 group gold standard process measures, the Hill Interaction Matrix and the Group Climate Questionnaire. Significant correlations between leader intervention scores and group member perceptions of group climate, as well as verbal interaction scores, were found. In addition, results indicated correlations between interventions aimed to gain balance between confrontation and warmth and member-rated levels of cohesion. Results lend support for the concurrent validity of the GPIRS. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Structural modifications in stretch-induced crystallization in PVDF films as measured by small-angle X-ray scattering

The nanostructure of stretched and nonstretched PVDF samples was studied by small-angle X-ray scattering (SAXS). The crystallinity of the samples was determined by wide-angle X-ray diffraction (WAXD) and differential scanning calorimetry (DSC), and crystalline phases by Fourier transform infrared spectroscopy (FTIR). The nanostructure can be described by a lamellar stacking of crystalline and amorphous layers, with a fairly well defined long period D and a diffuse-boundary in the interface between the crystalline and amorphous phases. The crystallinity of the stretched sample was found to be greater than that of the nonstretched sample. The long period D and the thicknesses of the crystalline lamellae T_c were found to be greater in the stretched sample than those in the nonstretched sample. The thickness of the diffuse-boundary was evaluated as being ∼ 1.4 nm in the nonstretched sample and 1.1 nm in the stretched sample. It was concluded that the growth of the thickness of the crystalline layer induced by the stretching process (stretch-induced crystallization) occurs partially at expense of the diffuse boundary and also by the coarsening of the structure with the stretching process, because of the diminution in the surface area to volume ratio observed. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Large-Scale Tracing of Ground Water with Sulfur Hexafluoride

Sulfur hexafluoride (SF6) was injected into a 9 km reach of the Santa Ana River in Orange County, CA, over a period of two weeks. The entire flow of this river, which averaged 2.8 m3 s?1, percolated into the ground in the field area. The tracer was monitored at wells near the river to determine subsurface flow patterns and flow times with an accuracy much greater than could be achieved using numerical simulations of ground-water flow. During the experiment, SF6 effectively tagged 3.7 × 106 m3 of water. The tracer plume was mapped in the subsurface for 18 months and indicates that linear ground-water velocities averaged about 2 km year?1. The tracer reached two wells adjacent to the river (about 200 m away) within three weeks, giving evidence that SF6 was not retarded significantly relative to the ground-water flow. This is in agreement with previous laboratory experiments.     

Lexical ambiguity and children's word recognition.

Conducted 2 experiments to examine the word recognition processes of 2nd, 4th, and 6th graders. In Exp I, 72 Ss named target words that were primed by words that had more than 1 meaning. Targets were related either to the more or less frequent sense of the ambiguous prime or were unrelated to it. Findings indicate that older Ss were more likely than younger Ss to restrict processing of ambiguous words to the most frequent meaning. While younger Ss showed approximately equal facilitation for words related to either meaning, regardless of each one's relative frequency, 6th graders apparently retrieved only the most frequent meaning. Exp II, with 36 Ss, was similar to Exp I but included neutral primes and varied the interval between presentation of prime and target. Results show that all groups showed automatic retrieval of both meanings of the ambiguous word. For 6th graders, however, this retrieval was followed by a 2nd stage, in which attention was allocated to the more frequent meaning, maintaining it, while the less frequent meaning was inhibited. Overall data indicate that older children use meaning frequency to narrow the amount of information kept active following word recognition. (34 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)