有机硅环氧树脂及其复合材料的光固化研究

通过研究光引发剂的种类、用量、光照时间和光敏剂等对树脂光固化后凝胶率的影响,确定了ES-06有机硅环氧树脂光固化的工艺条件,在质量分数分别为5%的二苯基碘鎓六氟磷酸盐光引发剂和5.5%的多元醇链转移剂作用下,光照10 min后紫外光开环聚合产物的凝胶率可达80%.利用湿法手工铺叠工艺和光固化技术,制备了玻璃布/有机硅环氧树脂复合材料,测试并分析比较了有机硅环氧和双酚A环氧复合材料的力学性能.结果表明,光固化有机硅环氧树脂基复合材料层板的拉伸强度和层间剪切强度较优,分别为158.5 MPa和9.9MPa,而两者的弯曲性能和拉伸模量相当.     

不同饱和度环氧大豆油的合成与性质表征

本文用无溶剂法制备环氧大豆油(ESO),研究了反应温度和反应时间对产物环氧值的影响。通过研究环氧大豆油的环氧值与反应时间以及反应温度的关系,选择最佳反应条件。在75℃下,大豆油和过氧乙酸分别反应1、2、3和4 h,分别获得环氧值为0.243、0.317、0.356和0.383 mol/100 g的环氧值不等的环氧大豆油,并研究不同饱和度对环氧大豆油的理化性质的影响。     

沮河流域径流变化特征及归因分析

径流变化的特征及归因分析对区域水资源规划和合理开发利用具有重要意义。本文以沮河流域为研究区域,利用线性回归法、五年滑动平均法及重标极差（R/S）分析法阐述水文要素的变化规律,通过Mann-Kendall突变检验和有序聚类法确定沮河黄陵站径流序列突变年份,利用基于Budyko假设的互补关系法及累积量斜率变化率比较法（SCRAQ法）对径流变化进行归因分析。结果表明,1967—2019年期间沮河流域年降水量呈上升趋势,年潜在蒸发量和年径流深呈下降趋势,且径流序列在1985年发生突变;两种方法计算得到的气候变化对径流减小贡献率分别为24.04%和11.71%,人类活动的贡献率分别为75.96%和88.29%,水利水保措施及煤矿开采等剧烈的人类活动是沮河流域径流减小的主要驱动因子。     

类石墨层状硼碳化合物的导电和抗氧化性能的研究

通过高温高压方法制备了一种晶化程度较高的类石墨层状BC3化合物.在5.5GPa压力条件下,温度越高,制得的硼碳样品晶化越好,电阻率越小.在1500℃、5.5GPa下制得的层状硼碳样品的电阻率ρ=1.2×10-4Ω·m,略大于同等条件下制备的纯碳样品的电阻率ρ=1.1×10-4Ω·m.这种层状硼碳化合物在620℃左右开始氧化,比纯碳样品的初始氧化温度高大约100℃,替代的硼明显的改善了碳的抗氧化性能.     

振动系统中磁流变流体阻尼模型的研究

研究了磁流体的阻尼力特性,提出了基于粘性阻尼和回滞阻尼组成的迟滞阻尼力模型,进行了磁流变阻尼器阻尼力的响应谱分析,并用Newmark数值积分方法分析了带有磁流变流体阻尼器梁结构的多自由度振动系统在不同磁场强度和激励频率作用下的位移响应.结果表明:迟滞阻尼力模型能够很好地描述磁流体阻尼器的力学性能,而且形式简单,概念明确,适合实际应用.     

Protection by Thermal and Chemical Activation with Cerium Salts of the Alloy AA2017 in Aqueous Solutions of NaCl

A wide variety of anticorrosive treatments for aluminum alloys that can be employed as “green” alternatives to those based on Cr(VI) are currently under development. This article reports a study of the morphological and anticorrosive characteristics of surface layers formed on the Al–Cu alloy AA2017 by immersion treatment in baths of cerium salt, accelerated by increased temperature and the employment of hydrogen peroxide. Scanning electron microscopy (SEM)/X-ray energy dispersive spectroscopy (XEDS) studies of the samples treated have demonstrated the existence of a heterogeneous layer formed by a film of aluminum oxide/hydroxide on the matrix, and a series of dispersed islands of cerium over the cathodic intermetallics. The protective efficacy has been evaluated using electrochemical techniques, linear polarizations (LP) and electrochemical impedance spectroscopy (EIS), and salt spray tests. The results obtained indicate that the layer provided good resistance to corrosion in media with chlorides, and the method gives a considerable reduction of the time required for the immersion treatments.     

Interface Characterization in Fiber-Reinforced Polymer–Matrix Composites

A novel methodology is presented and applied to measure the shear interface strength of fiber-reinforced polymers. The strategy is based in fiber push-in tests carried out on the central fiber of highly-packed fiber clusters with hexagonal symmetry, and it is supported by a detailed finite element analysis of the push-in test to account for the influence of hygrothermal residual stresses, fiber constraint and fiber anisotropy on the interface strength. Examples of application are presented to determine the shear interface strength in carbon and glass fiber composites reinforced with either thermoset or thermoplastic matrices. In addition, the influence of the environment (either dry or wet conditions) on the interface strength in C/epoxy composites is demonstrated.     

Entire Life Time Monitoring of Filament Wound Composite Cylinders Using Bragg Grating Sensors: II. Process Monitoring

This article is the second of a series of three papers concerning monitoring of filament wound cylinders using Bragg gratings. In this second part, the tooling presented in Part I is used to embed gratings and thermocouples in filament wound glass reinforced epoxy composite cylinders during fabrication. Bragg grating strain was obtained from wavelength and temperature response, by a calibration technique described here. Results from tests on five cylinders show the Bragg grating’s capability to monitor strain evolution during fabrication, and the capacity to detect several phenomena occurring during cure is established, in addition to quantifying the initial material condition of the cylinder before it enters service.     

The influence of Elfreda Chatman’s theories: a citation context analysis

The range of theoretical frameworks currently being used by researchers into information behaviour is abundant and diverse. We need to examine thoroughly the contribution of theories and models to further research, as this would help to improve future investigations in the field. This paper adopts this approach, by thoroughly examining the influence that Elfreda Chatman’s three middle-range theories have had on subsequent research. A citation context analysis was carried out on the basis of those received by Information poverty theory, life in the round theory and normative behaviour theory. Analysis covered the year of publication, the type of work and the subject-matter of the citing documents. The cites in context or theoretical incidents were analysed for frequency of citation in citing documents, the content of Chatman’s work being cited, the context co-citation analysis, the citation style and the citation location. The analysis of citation in context has allowed us to draw a distinction between the author and her work, while verifying that not all cites are the same. These differences reflect the unequal relevance of these theories to subsequent research.