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111.
磷石膏的综合利用对保护环境、促进企业可持续健康发展具有重要意义,但是磷石膏中的磷、氟、二氧化硅等杂质影响其利用。针对云南磷石膏中二氧化硅含量高的问题,采用正浮选工艺开展了磷石膏提质降杂的实验研究。通过单因素条件实验获得了合适的工艺参数:浮选温度为15 ℃、矿浆pH为2、十二胺用量为300 g/t。在此条件下,进行了“一粗二精”的正浮选开路流程实验,获得了二水石膏(CaSO4·2H2O)质量分数为97.5%、二氧化硅质量分数为1.17%的精矿,所得精矿达到了GB/T 23456—2018《磷石膏》一级品指标的要求;二水石膏回收率为98.58%、二氧化硅去除率为92.23%。通过正浮选不仅成功实现了二水石膏和二氧化硅的有效分离,而且磷石膏中的水溶磷和水溶氟也得到了有效去除,从而提高了磷石膏的品质。 相似文献
112.
A unique electrochemical technique, namely continuous noise resistance calculation (CNRC), was used to obtain electrochemical kinetic information from the formation process of chromate conversion coatings (CCC) on aluminium electrodes. It was found that the noise resistance (Rn) of aluminium electrodes remained almost unchanged during electrodes' immersion in a chromate containing acidic solution where the CCC films were supposed to form rapidly. This result indicates that the formation of CCC was associated with continuous corrosion of the aluminium electrodes and that the CCC films formed on aluminium surface were not intact barrier films, but most likely porous layers. The CCCs became protective only after they were aged in the environment. Based on these findings, the formation and inhibition mechanisms of CCC have been discussed. 相似文献
113.
铝合金熔体旋转喷吹除气净化过程模拟 总被引:1,自引:0,他引:1
采用计算机模拟方法对铝合金熔体旋转喷吹除气净化过程的温度场以及流场进行分析。结果表明,在转杆内部放置一个导气管,可以显著降低气体温度,从而可以有效地解决旋转喷头由于熔剂因高温变软而堵塞的问题;旋转速度和进气流量对铝合金熔体旋转喷吹除气净化效果具有重要影响,应该根据具体情况选择合适的工艺参数。熔池为方形结构时,气体主要从对角处出去,而远离对角处的体积分数却显著降低,甚至可能发生吸气。 相似文献
114.
高纯钛的反复弯曲疲劳 总被引:1,自引:0,他引:1
通过对不同应力幅度下高纯钛的反复弯曲疲劳的研究,发现在较低应力幅度下(~±100MPa),材料表现出循环软化,伴随表面滑移带数量的增加、发达的滑移带挤出片的出现。疲劳裂纹萌生主要与滑移带相关,在挤出物内存在两类疲劳损伤形式:沿滑移带的孔洞和与滑移带垂直的微裂纹。在较高应力幅度下(~±200MPa),则表现为硬化,次滑移及晶界附近多个滑移系同时起动,有大的形变孪晶出现。裂纹于滑移带、李晶界和晶界结点萌生。断口特征复杂,但与表面变形特征有对应关系。TEM亚结构分析表明,随应力幅度的提高,位错组态分别为散乱分布于滑移面的偶极子、位错束带和位错胞。李晶内存在复杂的精细结构,而且有堆垛层错出现。 相似文献
115.
116.
A new concept for the processing and fabrication of rigid-rod molecular composites aiming at the elimination or minimization of phase separation is proposed. This approach calls for a coil-like aromatic polyisoimide which is soluble and compatible with an amorphous matrix polymer or thermosettable oligomer and can undergo facile transformation to the corresponding rigid-rod polyimide in solid composite state, thus imparting the inherently high strength/high modulus properties to the final form. To this end, various synthetic routes were explored to obtain para-diamines which could afford high molecular weight and aprotic-solvent-soluble polyisoimides upon polymerization with pyromellitic dianhydride (PMDA). Four such polyisoimides were prepared, with their inherent viscosities ranging from 0.25 to 1.89 dl g−1 in dimethylacetamide at 30°C. Facile thermally induced isoimide-imide conversion was demonstrated by solid-state (film) Fourier transform infrared spectroscopy. A preliminary evaluation of the compatibility of the polyisoimide/matrix resin was made. In one instance, a film prepared from the polyisoimide derived from PMDA and 3,3′,5,5′-tetramethylbenzidine (TMB) showed no visually detectable phase separation. 相似文献
118.
Keng-hong Tan 《Journal of chemical ecology》2000,26(3):697-704
The Asian house gecko, Hemidactylus frenatus, after being acclimatized to feeding on the melon fly, Bactrocera cucurbitae, consumed fewer numbers of 15-day-old (DO) and older male melon flies compared to sexually immature flies 10 DO and younger. The first male melon fly that performed mating did so on the 10th day after eclosion (DAE), but >80% of the males performed their first mating between 10 and 15 DAE. This confirmed that between 10 and 15 DAE most male melon flies are already sexually mature and producing sex pheromone. Synthetic 1,3-nonanediol, a component of male melon fly sex pheromone produced endogenously, when topically applied onto the thorax of housefly Musca domestica at ca. 80 or 320 ng/fly, reduced consumption by geckos compared with untreated flies in subsequent days after the first day in a four-day feeding test. Raspberry ketone (RK) is consumed and sequestered into the pheromonal gland and later released as a pheromonal component of male melon fly. Houseflies topically treated with 2.6 g RK/fly did not deter predation by geckos. However, houseflies treated with 5.1 g RK/fly caused geckos to consume fewer flies, especially on the third and fourth days during a four-day feeding test, compared with the period when they were offered untreated flies. 相似文献
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120.