Proline-derived in situ synthesis of nitrogen-doped porous carbon nanosheets with encaged Fe2O3@Fe3C nanoparticles for lithium-ion battery anodes

The homogeneous incorporation of heteroatoms into two-dimensional C nanostructures, which leads to an increased chemical reactivity and electrical conductivity as well as enhanced synergistic catalysis as a conductive matrix to disperse and encapsulate active nanocatalysts, is highly attractive and quite challenging. In this study, by using the natural and cheap hydrotropic amino acid proline—which has remarkably high solubility in water and a desirable N content of ~12.2 wt.%—as a C precursor pyrolyzed in the presence of a cubic KCl template, we developed a facile protocol for the large-scale production of N-doped C nanosheets with a hierarchically porous structure in a homogeneous dispersion. With concomitantly encapsulated and evenly spread Fe₂O₃ nanoparticles surrounded by two protective ultrathin layers of inner Fe₃C and outer onion-like C, the resulting N-doped graphitic C nanosheet hybrids (Fe₂O₃@Fe₃C-NGCNs) exhibited a very high Li-storage capacity and excellent rate capability with a reliable and prolonged cycle life. A reversible capacity as high as 857 mAh•g^–1 at a current density of 100 mA•g^–1 was observed even after 100 cycles. The capacity retention at a current density 10 times higher—1,000 mA•g^–1—reached 680 mAh•g^–1, which is 79% of that at 100 mA•g^–1, indicating that the hybrids are promising as anodes for advanced Li-ion batteries. The results highlight the importance of the heteroatomic dopant modification of the NGCNs host with tailored electronic and crystalline structures for competitive Li-storage features.

     

La<Subscript>1−x</Subscript>Ag<Subscript>x</Subscript>FeO<Subscript>3</Subscript>/halloysites nanocomposite with enhanced visible light photocatalytic performance

La_1?xAg_xFeO₃/halloysites nanotubes (HNTs) nanocomposite was synthesized by sol–gel method. It was characterized by X-ray diffraction, transmission electron microscope, Fourier transform infrared spectroscopy and UV–visible diffused reflectance spectroscopy measurements. The photo-activity of the La_1?xAg_xFeO₃/HNTs nanocomposite was evaluated via degradation of methylene blue (MB) under visible-light irradiation. The results showed that the HNTs with unique pore structure favored the adsorption of organic molecules. Adequate Ag⁺ doping improved the absorption ability for visible light. The La_0.95Ag_0.05FeO₃/HNTs demonstrated the best photocatalytic performance, which achieved as high as 99 % for MB degradation exposed 2 h irradiation. However,further increasing of Ag⁺ doping gradually reduced the photocatalytic activity. The nanocomposite catalyst showed outstanding recyclability after eight cycles which still remained up to 90 %.     

60°镜面光泽测量值不确定度的评定

本文采用光泽度仪对漆膜的60°镜面光泽进行了测量,对产生测量不确定度的因素进行了分析,并对其A类和B类不确定度进行了分别评定,最终获得其测量结果的扩展不确定度。     

Rolling texture and its effect on tensile property of a near-α titanium alloy Ti60 plate

Rolling texture and its effect on tensile properties of Ti60 alloy plates were investigated in the present study. The plates wereβ-rolled at 1070℃ and(α+β)-rolled at 980℃, using uni-directionally rolling(UDR) and cross-directionally rolling(CDR) processes, respectively.β-rolled plates exhibited weak textures, which were attributed to the dispersive orientations of secondary α during the β→α phase transformation. Strong deformation textures formed in(α+β)-rolled plates as a result of slipping mechanisms: the strong T-type texture in UDR plate was related to {10 1 0}[11 2 0] slipping, while the B-type texture in CDR plate was relevant with {0001}[11 2 0] slip. Strong T-type textures led to anisotropic tensile properties. B-type textures would decrease such an anisotropy. The(α+β)-CDR process was found to be a candidate process for reducing anisotropy of Ti60 alloy plates.     

Large capacitance and fast polarization response of thin electrolyte dielectrics by spin coating for two-dimensional MoS2 devices

Nano Research - A spin-coating method was applied to obtain thinner and smoother PEO/LiClO4 polymer electrolyte films (EFs) with a lower level of crystallization than those obtained using a...