Anion Acceptors Dioxaborinane Contained in Solid State Polymer Electrolyte: Preparation,Characterization, and DFT Calculations

A novel dioxaborinane‐contained solid state polymer electrolyte poly((2‐phenyl‐1, 3, 2‐dioxaborolane‐4‐yl) methyl methacrylate) (P(GMMA‐PBA)) for symmetrical capacitors (SCs) is prepared through solution casting technique. Due to the effect of electron withdrawing of dioxaborinane groups and irregular distributed porous microstructures, the solid polymer electrolyte (SPE) exhibits an optimal ionic conductivity of 0.5 mS cm^?1 at ambient conditions. The electronic properties of dioxaborinane groups and their interaction with anions of electrolyte salts are further studied with density functional theory calculations. SCs fabricated with this polymer film as electrolyte and reduced graphene oxide as electrodes provide a broad potential window of 2.5 V. The energy density of this capacitor ups to 22.49 Wh kg^?1 with a power density of 6.34 kW kg^?1 at 5 A g^?1. After 3000 charge–discharge cycles, the capacitance of the symmetrical SPE capacitor maintains 90% of its initial values.     

Taming Charge Transport in Semiconducting Polymers with Branched Alkyl Side Chains

The solid‐state packing and polymer orientation relative to the substrate are key properties to control in order to achieve high charge carrier mobilities in organic field effect transistors (OFET). Intuitively, shorter side chains are expected to yield higher charge carrier mobilities because of a denser solid state packing motif and a higher ratio of charge transport moieties. However our findings suggest that the polymer chain orientation plays a crucial role in high‐performing diketopyrrolopyrrole‐based polymers. By synthesizing a series of DPP‐based polymers with different branched alkyl side chain lengths, it is shown that the polymer orientation depends on the branched alkyl chain lengths and that the highest carrier mobilities are obtained only if the polymer adopts a mixed face‐on/edge‐on orientation, which allows the formation of 3D carrier channels in an otherwise edge‐on‐oriented polymer chain network. Time‐of‐flight measurements performed on the various polymer films support this hypothesis by showing higher out‐of‐plane carrier mobilities for the partially face‐on‐oriented polymers. Additionally, a favorable morphology is mimicked by blending a face‐on polymer into an exclusively edge‐on oriented polymer, resulting in higher charge carrier mobilities and opening up a new avenue for the fabrication of high performing OFET devices.     

Biomarker-Responsive Nanosystems for Chronic Disease Theranostics

Chronic diseases claim millions of lives every year, and it is of great significance to explore and develop advanced drugs to improve the cure rate of chronic diseases. Nanotheranostics are innovative strategies that enable the integration of diagnostic and therapeutic properties into a single nanosystem. Despite great success in nanotheranostics, their applications of nanotheranostics in nanomedicine are still in their infancy. This is because each disease has its corresponding characteristic pathological microenvironment, which motivates the development of endogenous biomarker-responsive nanosystems to meet the requirements of diagnosis and treatment. Herein, recent progress is presented in biomarker-responsive nanosystems and their biomedical applications. First, biomarker-responsive nanosystems are classified into eight subsections according to the type of chronic diseases, including tumors, cardiovascular diseases, neurological diseases, Wilson's diseases, chronic liver diseases, chronic kidney diseases, diabetes mellitus, and rheumatoid arthritis. In the following, a variety of intriguing applications of biomarkers-responsive nanosystems are briefly elaborated, such as biosensing, diagnosis, therapy, combined theranostics, and early evaluation of therapy effect, etc. Finally, the challenges and future directions from research to clinical translation of these responsive nanosystems are also presented.     

3G无线网络建设问题探讨

移动通信低速语音通信向高速数据通信转变,通信业务由室外向室内转移,无线网络从信号覆盖型向信息容量型演进,网络架构正在发生深刻变革。变革对网络建设、技术和管理提出了新的挑战和要求。针对存在的问题和挑战,提出了相关建议,并介绍了广东联通在技术和管理创新方面的有益尝试。     

保密传真通信系统的仿真实现

实际的保密传真通信系统是一个功能结构复杂的系统。在建立新系统前,通常需要对系统进行建模和仿真以消除系统中潜在的瓶颈,提高系统成功的概率。文中在分析了保密传真通信系统的工作原理之后,对保密传真通信系统的信源编码模块、加解密模块和调制解调模块进行了Matlab仿真实现,仿真结果达到了预期目标。     

基于分等级对象语义图模型的复杂目标自动识别方法研究

目标自动识别是图像处理领域的研究热点。针对现有方法的不足,该文提出一种新的基于分等级对象语义图模型的复杂目标自动识别方法。该方法通过构建分等级对象语义图模型增强对目标与背景间、目标部件间语义约束的利用,引入置信对象网络统计局部特性,利用消息机制传递对象间相互影响,实现概率语义分析。训练中还将产生式和判别式方法结合,提高了目标识别的准确度。在自然和遥感部分目标类别数据集上的测试结果表明,该方法能完成对多种类型和复杂结构目标的识别和提取,具有一定的实用价值。     

Thermal stability investigations of AlGaN/GaN HEMTs with various high work function gate metal designs

The operation of high power RF transistor generates a huge amount of heat and thermal effect is a major consideration for improving the efficiency of power transistors. AlGaN/GaN high electron mobility transistors (HEMTs) on silicon substrates have been studied extensively because of their high thermal conductivity. This study comprehensively investigates the DC, low frequency noise, microwave and RF power performance of Al_0.27Ga_0.73N/GaN HEMTs on silicon substrates at temperatures from room temperature to 100 °C using high work function metals such as palladium (Pd) and iridium (Ir) gate metals. Although the conventional Ni gate exhibited a good metal work function with AlGaN, which is beneficial for increasing the Schottky barrier height of HEMTs, the diffusion of Ni metal toward the AlGaN and GaN layers influences the DC and RF stability of the device at high temperatures or over long-term operation. Pd and Ir exhibited less diffusion at high temperature than Ni, resulting in less degradation of device characteristics after high temperature operation.     

角度计量中三光栅光学系统应用分析

在目前的角度计量工作中普遍采用光电轴角编码器作为测角器件,而光栅系统由于具有分辨率高、稳定性好、出错率低、环境适应性强等特点而得到了计量界的认可。结合计量工作误差处理严谨、不确定度来源分析透彻的要求,在分析了三光栅光学系统原理的基础上,提出了针对其正弦输出信号的自适应滤波方法。     

A Pattern Recognition Method of Personalized Adaptive Learning in Online Education

Mobile Networks and Applications - In order to effectively identify the pattern of personalized adaptive learning in online education and improve the recommendation satisfaction of personalized...     

调整圆弓形散射元参数实现低群速和低色散的慢光效应

圆弓形散射元具有各向异性和多个可控自由度的特点。采用平面波展开方法,通过长轴微调、短轴变化和散射元转动几个方面,优化了光子晶体线性缺陷波导结构,实现了高群折射率和低色散的慢光效应并进行了模拟。结果表明,通过调整长轴和短轴变化,可以获得带宽在10.1～1.1nm,折射率为36.5～287.5的低色散慢光;通过散射元转动,可以获得带宽在11.4～0.8nm、折射率为45.5～293.7的低色散慢光。上述方法还可以获得超低色散和接近零色散效果的慢光。由此表明,选择合适的散射元和调整散射元参数,可以有效地实现高群折射率和低色散的慢光效应。