被动直升机声信号波达方向估计

在分析直升机声信号和背景噪声特点的基础上,提出了1种适合于被动单直升机 目标声信号波达方向(DOA)估计的方法。首先在1帧时间内利用傅立叶变换估计直升机声信 号基频,然后用查表获得的投影矩阵滤除不需要的频率成分,最后用波束形成估计到达角。方 法运算量适中,精度较高,通过对采录的1架某型号直升机声信号的分析验证了该算法的有效 性。     

一种基于交换机的彩铃业务实现方案

首先介绍了在GSM移动网络中实现彩铃业务的原理，然后提出一种基于交换机实现彩铃业务的技术方案，分析了此方案中媒体设备的物理结构和内部信令的交互过程，最后将该方案与基于智能网的方案进行了对比。     

基于嵌入式Web服务器的数字视频监控的解决方案

本文提供了在 ARMS3C2410芯片上基于嵌入式 Web 服务器的网络视频监控的一种解决方案。在压缩方面采用了以 WIS G700SB 为核心的 MPEG-4采集压缩模块。先叙述总体设计思想，然后分软件和硬件两部分进行详细探讨。     

Surface State Mediated NIR Two‐Photon Fluorescence of Iron Oxides for Nonlinear Optical Microscopy

The development of fluorescent iron oxide nanomaterials is highly desired for multimodal molecular imaging. Instead of incorporating fluorescent dyes on the surface of iron oxides, a ligand‐assisted synthesis approach is developed to allow near‐infrared (NIR) fluorescence in Fe₃O₄ nanostructures. Using a trimesic acid (TMA)/citrate‐mediated synthesis, fabricated Fe₃O₄ nanostructures can generate a NIR two‐photon florescence (TPF) peak around 700 nm under the excitation by a 1230‐nm femtosecond laser. By tailoring the absorption of Fe₃O₄ nanostructures toward NIR band, the NIR‐TPF efficiency can be greatly increased. Through internal etching, surface peeling, and ligand replacement, spectroscopic results validated that such resonantly enhanced NIR‐TPF is mediated by surface states with strong NIR‐IR absorption. This TPF signal evolution can be generalized to other iron oxide nanomaterials like magnetite nanoparticles and α‐Fe₂O₃ nanoplates. Using the developed fluorescent Fe₃O₄ nanostructures, it is demonstrated that their TPF and third harmonic generation (THG) contrast in the nonlinear optical microscopy of live cells. It is anticipated that the synthesized NIR photofunctional Fe₃O₄ will serve as a versatile platform for dual‐modality magnetic resonance imaging (MRI) as well as a magnet‐guided theranostic agent.     

Noise limit in heterodyne Interferometer demodulator for FBG-based sensors

This paper reports the results of a recent investigation on the noise-limited performance in heterodyne interferometric demodulation systems for fiber Bragg grating strain sensors. Theoretical and simulation results are presented and compared with experimental results.     

Boosting Piezo-Catalytic Activity of KNN-Based Materials with Phase Boundary and Defect Engineering

Although the piezo-catalysis is promising for the environmental remediation and biomedicine, the piezo-catalytic properties of various piezoelectric materials are limited by low carrier concentrations and mobility, and rapid electron-hole pair recombination, and reported regulating strategies are quite complex and difficult. Herein, a new and simple strategy, integrating phase boundary engineering and defect engineering, to boost the piezo-catalytic activity of potassium sodium niobate ((K, Na)NbO₃, KNN) based materials is innovatively proposed. Tur strategy is validated by exampling 0.96(K_0.48Na_0.52)Nb_0.955Sb_0.045O₃-0.04(Bi_xNa_4-3x)_0.5ZrO₃-0.3%Fe₂O₃ material having phase boundary engineering and conducted the defect engineering via the high-energy sand-grinding. A high reaction rate constant k of 92.49 × 10⁻³ min⁻¹ in the sand-grinding sample is obtained, which is 2.40 times than that of non-sand-grinding one and superior to those of other representative lead-free perovskite piezoelectric materials. Meanwhile, the sand-grinding sample has remarkable bactericidal properties against Escherichia coli and Staphylococcus aureus. Superior piezo-catalytic activities originate from the enhanced electron-hole pair separation and the increased carrier concentration. This study provides a novel method for improving the piezo-catalytic activities of lead-free piezoelectric materials and holds great promise for harnessing natural energy and disease treatment.     

Indirect Control of Donor/Acceptor Interactions for Highly Efficient Space-Confined Thermally Activated Delayed Fluorescence Emitters

Conformational engineering is essential to further reinforce the luminescent properties of thermally activated delayed fluorescence (TADF) materials featuring through-space charge transfer (TSCT) characteristics. Herein, two TSCT-TADF emitters (8MeDM-B and 8FDM-B) with the methyl and fluorine moieties substituted at the C8 site of the rigid spiro-fluorene bridge is reported. Derivation of the C8 site is first proposed to control the molecular configuration with the ability to indirectly tune the intramolecular interaction between donor and acceptor groups. As a result, 8MeDM-B and 8FDM-B both present small singlet-triplet energy gaps, fast reverse intersystem crossing rates, and high photoluminescence quantum yields. Interestingly, the smaller fluorine atom not the bigger methyl group exhibits more evident electrostatic repulsive force onto the central donor and thus rectifies the central spiro structure. Consequently, the high external quantum efficiency values of 28.8% and 31.7% for 8MeDM-B and 8FDM-B-based electroluminescence devices are achieved, respectively. This study offers a measure for enhancing TSCT-TADF emitters without directly modifying the donor or acceptor.     

TDD-FDD混合组网互操作策略优化和研究

随着用户对移动数据业务的需求不断增长,LTE FDD网络频率、容量等资源不足的问题逐渐凸显,而TD-LTE网络拥有更多的频谱资源,TD-LTE与LTE FDD融合组网可以有效缓解FDD频谱紧张、容量不足的问题,TD-LTE和LTE FDD相互融合并共同发展已成为未来全球移动通信产业的趋势。重点研究了不同场景下,通过参数调整选用不同的TDD/FDD互操作策略,给出该场景下最适合的互操作策略。     

Co3O4 Nanoparticles as Robust Water Oxidation Catalysts Towards Remarkably Enhanced Photostability of a Ta3N5 Photoanode

Despite the fact that Ta₃N₅ absorbs a major fraction of the visible spectrum, the rapid decrease of photocurrent encountered in water photoelectrolysis over time remains a serious hurdle for the practical application of Ta₃N₅ photoelectrodes. Here, by employing a Co₃O₄ nanoparticle water oxidation catalyst (WOC) as well as an alkaline electrolyte, the photostability of Ta₃N₅ electrode is significantly improved. Co₃O₄/Ta₃N₅ photoanode exhibits the best durability against photocorrosion to date, when compared with Co(OH)_x/Ta₃N₅ and IrO₂/Ta₃N₅ photoanodes. Specifically, about 75% of the initial stable photocurrent remains after 2 h irradiation at 1.2 V vs. RHE (reversible hydrogen electrode). Meanwhile, a photocurrent density of 3.1 mA cm^?2 has been achieved on Co₃O₄/Ta₃N₅ photoanode at 1.2 V vs. RHE with backside illumination under 1 sun AM 1.5 G simulated sunlight. The reason for the relatively high stability is discussed on the basis of electron microscopic observations and photoelectrochemical measurements, and the surface nitrogen content is monitored by X‐ray photoelectron spectroscopic analysis.     

采用扫描电镜的ECP技术分析人工合成金刚石晶体中的晶体缺陷

本文应用扫描电镜的ＥＣＰ技术对人造金刚石晶体表面的位错密度，进行了实验分析，并同位错蚀坑分析技术的测量结果进行了比较，结果表明，如采用临界束流强度作为描述ＥＣＰ本征衬度的参数，则它同位错密度间存在明显定量的数学关系，因此上述临界束流强度可用来评价晶体中位错密度的相对变化。