一种大量元素水溶肥料的制备及其在玉米上的喷施效果

根据玉米需肥特性设计氮磷钾比例,制备了含中微量元素的大量元素水溶肥料,产品氮、磷、钾比例为2∶1∶4,属于高钾中氮低磷型.在河北省安平县前子文村和浙江省新昌县孟家塘村玉米上开展了叶面喷施试验.结果表明:玉米生物学性能得到改善,玉米产量、出籽率、百粒重与容重得到提高;与空白对照相比,平均增产率为5.45％,平均纯增收896.40元/公顷,平均产投比为5.43∶1.     

负极添加NMP对电池性能的影响

锂离子电池负极浆料中添加N-甲基吡咯烷酮(NMP),在极片加热干燥时不能完全除去.残留的NMP吸附在石墨表面,使得SEI膜与石墨结合不牢固.研究了其对电池性能的影响,结果显示,在电池的循环过程中,SEI膜逐渐脱落,导致电池循环寿命缩短,但对电池的容量、内阻、倍率、存储等初期性能不影响.     

Hydrogeochemical Processes and Inverse Modeling for a Multilayer Aquifer System in the Yuaner Coal Mine,Huaibei Coalfield,China

Coal mining can dramatically change hydrogeological conditions and induce serious environmental problems. Fifty groundwater samples were collected from the main aquifers in the Yuaner coal mine (Anhui Province, China). The results show that the main hydrogeochemical processes in the mine include dissolution, precipitation, pyrite oxidation, desulfurization, and cation exchange. The Neogene porous aquifer is affected by groundwater flow conditions; its main hydrogeochemical processes are dissolution of carbonate minerals and gypsum, and cation exchange. The Permian coal measure’s fractured sandstone aquifer was confirmed to be controlled by the region’s geological structure; its main hydrogeochemical processes are desulfurization and cation exchange. The Carboniferous Taiyuan limestone aquifer was determined by both groundwater flow conditions and regional geological structure; its main hydrogeochemical processes are dissolution of carbonate minerals and gypsum, pyrite oxidation, and cation exchange. Additionally, hydrogeochemical inverse modeling of the groundwater flow path confirm the hydrochemistry results and principal component analysis.

     

中药桂枝总黄酮的提取工艺研究

优化桂枝总黄酮的提取工艺，建立桂枝的提取和含量测定方法。通过单因素试验，考察提取方法、提取溶剂浓度、提取体积、提取时间对药材总黄酮含量的影响，采用正交试验，优化提取工艺条件，筛选出桂枝总黄酮的最佳提取工艺。总黄酮最佳提取工艺为75%乙醇、料液比1:40、回流提取时间60 min。该方法能有效测定桂枝药材总黄酮的含量，为该药材的质量标准研究提供一定的科学依据。本方法重复性较好、方法稳定、可行。     

Theoretical study on a kind of cyclization mechanism of boron trichloride and hexamethyldisilazane to form the borazine ring for SiBCN ceramics precursor

Borazine rings act as a pivotal part in siliconboroncarbonitride ceramics (SiBCN) for high-temperature stability and great resistance to crystallization. A detailed investigation of the ring formation mechanism will guide the design and synthesis of SiBCN to meet application requirements under extreme conditions. Boron trichloride (BCl₃) and hexamethyldisilazane (HN(SiMe₃)₂) are common raw materials for the synthesis of precursors for SiBCN. In this paper, quantum chemical calculation was used to study the cyclization reaction mechanism between BCl₃ and HN(SiMe₃)₂ to form trichloroborazine (TCBZ) at the MP2/6-31G (d,p) level of theory. We discussed the structure properties, reaction pathways, energy barriers, reaction rates, and other aspects in detail. The results show that BCl₃ and HN(SiMe₃)₂ alternately participate in the reaction process, accompanied by the release of trimethylchlorosilane (TMCS), and that the entire reaction shows an absolute advantage in terms of energy. In the Step by step reaction, lower reaction barriers are formed due to the introduction of BCl₃ with more heat released compared to that for the introduction of HN(SiMe₃)₂. The final single-molecule cyclization and TMCS elimination steps are found to be faster compared to all previous bimolecular reactions.     

一株产羧酸酯酶菌的鉴定及酯酶特征的研究

目的:鉴定中国白酒发酵过程中的微生物种类，研究关键酶的特征与作用机制有利于提高白酒的优质品率。方法:本研究用形态学和生理学、16S rRNA、gyr B基因和antiSMASH分析的方法对酒曲中的一株微生物进行了验证；对该菌株的特性进行了研究，采用分子建模的方法获得了羧酸酯酶的3D模型，用分子对接的方法探讨了该菌株的羧酸酯酶的机理。结果:该菌株为产羧酸酯酶的革兰氏阴性菌Pb1（MW580690）；该菌株呈现典型的S型生长曲线，产物曲线为S型，羧酸酯酶活化最优pH范围为5.0~9.0。分子对接结果显示Phe21A为该酶具有催化活性的主要氨基酸，水解三丁酸甘油酯为丁酸和甘油。分子对接结果显示三丁酸甘油酯经过构象变化被转移到催化中心后，进一步被加工；酶的亲水性和疏水性的相互作用表面有利于配体向下转移，进而从疏水性通道释放产物到的酶表面。结论:产羧酸酯酶的菌株为贝莱斯芽胞杆菌，并为羧酸酯酶水解三丁酸甘油酯类物质的底物识别、转移和催化机理提供了新的见解。     

基于熵权TOPSIS的工程咨询机构BIM技术应用能力评价

构建工程咨询机构BIM技术应用能力评价的指标体系,提出改进的熵权TOPSIS评价模型,以4个典型的工程咨询单位为例,进行BIM技术运用能力评价。研究表明,BIM行业的整体水平已经有了明显的提升,但是区域间的发展还存在一定差距。     

突发疫情对染料行业影响及对策

一场新型冠状病毒肺炎疫情的爆发给染料行业的发展带来了影响,既有负面消极,也有积极影响。疫情将促进染料行业绿色发展,推动染料行业走向信息化、智能化时代,走向高质量发展,指出只要坚持绿色、创新和智能化,就能战胜疫情,推动中国染料行业稳健发展。     

河南省灵宝市董家埝银矿原生晕特征及地质意义

董家埝银矿是豫西小秦岭矿集区南成矿带目前发现的唯一大型矿床。为了矿床深部勘查工作的顺利进行,了解有用元素在垂向上的变化规律,选用原生晕地球化学方法,通过典型矿床剖面的原生晕特征研究,实现对深部矿体变化趋势的判断。经计算,确定As、Sb、Ag、Au、Cu、Pb、Zn、Co和Mo等9种元素可作为指示元素,其中As和Sb为前缘晕指示元素,Ag、Au、Cu、Pb和Zn为近矿晕指示元素,Co和Mo为尾晕指示元素。分带指数和浓集指数2种方法计算得出的元素在分带序列上的位置总体趋势一致。用分带指数法确定的主矿体自上而下的原生晕轴向分带序列为Co-Mo-Cu-Au-Sb-Zn-Pb-Ag-As,出现"反分带"现象。结合原生晕地球化学参数变化特征、矿体剥蚀程度研究和理想模型,预测M1-I主矿体向深部仍有较大的延伸。研究成果可以为区域同类型矿化地质体深部的趋势判断和决策提供参考。     

复杂难选铁矿石悬浮磁化焙烧-高效分选技术

针对传统铁矿石磁化焙烧技术与装备存在焙烧产品质量差、产能低、能耗高和环境污染严重等问题，创造性提出了一种“预热-蓄热还原-再氧化”悬浮磁化焙烧新工艺。该工艺具有原料适应性广、焙烧产品质量均匀、回收率高、生产能耗低、无污染等特点，适合处理赤铁矿、褐铁矿、菱铁矿及其混合型难选铁矿石。通过多年的潜心基础研究与技术攻关，形成了非均质矿石颗粒悬浮态流动控制、蓄热式高效低温还原、铁物相精准调控与余热同步回收等一系列关键技术，建成了500kg/h复杂难选铁矿石悬浮磁化焙烧-高效分选半工业试验平台。