Studies on cross-linked polyurethane acrylate-based electrolyte consisting of reactive vinyl/divinyl diluents

A series of cross-linked polyurethane acrylate (PUA) electrolytes have been prepared by using 4,4′-methylene bis(phenyl isocyanate), polyethylene glycol, hydroxyethyl methacrylate and different reactive vinyl/divinyl diluents, such as methyl methacrylate (MMA), ethyl acrylate and acrylonitrile, tripropylene glycol diacrylate (TPGDA). The electrolytes were prepared by UV radiation induced cross-linking of the PUA-diluent mixture followed by swelling in a liquid electrolyte (LP-30). Depending upon the composition of the components, these electrolytes exhibited a wide range of mechanical and electrical properties. The system containing MMA as reactive diluent showed highest conductivity, but poor mechanical properties and stability in the liquid electrolyte. The TPGDA cross-linked system possesses a good combination of ionic conductivity and stability in liquid electrolytes. These systems showed good compatibility with Li-electrodes and sufficient electrochemical stability to allow safe operation in rechargeable Li-batteries.     

Thermal properties and crystalline structure of liquid crystalline poly(ethylene terephthalate‐co‐2(3)‐chloro‐1,4‐phenylene terephthalate)

Thermal properties and crystalline structure of liquid crystalline (LC) poly(ethylene terephthalate‐co‐2(3)‐chloro‐1,4‐phenylene terephthalate) [copoly(ET/CPT)] were investigated using differential scanning calorimetry (DSC), thermogravimetry (TGA), limiting oxygen index (LOI) measurement, electron dispersive X‐ray analysis (EDX), X‐ray diffractometry, and infrared spectrometry (IR). The thermal transition temperatures of copoly(ET/CPT) were changed with the composition. Copoly(ET/CPT) showed two thermal decomposition steps and the residues at 700°C and LOI values of copoly(ET/CPT) were almost proportional to its chlorine content. The activation energy of thermal decomposition of LC units was very low compared to that of poly(ethylene terephthalate)(PET) units. Crystal structure of copoly(ET/CPT) (20/80) was of triclinic system with the lattice constants of a = 9.98 A?, b = 8.78 A?, c = 12.93 A?, α = 97.4°, β = 96.1°, and γ = 90.8°, which is very close to that of poly(chloro‐p‐phenylene terephthlate) (PCPT) with the lattice constants of a = 9.51 A?, b = 8.61 A?, c = 12.73 A?, α = 96.8°, β = 95.4°, and γ = 90.8°. When copoly(ET/CPT)(50/50) was annealed at 220°C in vacuum, crystallization induced sequential reordering (CISR) was not observed but the heat of fusion was slightly increased due to the increase of the trans isomer content in PET units. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1286–1294, 2002; DOI 10.1002/app.10451     

Anomalous variations of OFF-State leakage current in poly-Si TFTunder static stress

Studies the anomalous variations of the OFF-state leakage current (I_OFF) in n-channel poly-Si thin-film transistors (TFTs) under static stress. The dominant mechanisms for the anomalous I_OFF can be attributed to (1) I_OFF increases due to channel hot electrons trapping at the gate oxide/channel interface and silicon grain boundaries and (2) I_OFF decreases due to hot holes accumulated/trapped near the channel/bottom oxide interface near the source region. Under the stress of high drain bias, serious impact ionization effect will occur to generate hot electrons and hot holes near the drain region. Some of holes will be injected into the gate oxide due to the vertical field (~(V_Gstress V_Dstress)/T _OX) near the drain and the others will be migrated from drain to source along the channel due to lateral electric field (~V_Dstress/L_CH)     

Sensitivity analysis of relative accommodation and vergence

A sensitivity analysis was performed to determine the variation in response to changes in parameter values of a previously developed nonlinear static model of accommodation and vergence. To determine normal behavior, model simulation responses were computed using previously obtained parameter values in 4 subjects under 2 conditions. In the first, relative accommodation was evaluated by maintaining the vergence stimulus constant at 2.5 meter angles (MA) and varying the accommodative stimulus from -2.5 to 2.5 diopters (D) in 0.25-D steps. In the second, relative vergence was evaluated by maintaining the accommodative stimulus constant at 2.5 D and varying the vergence stimulus from 25 prism diopters (PD) base-in to 25 PD base-out in 5-PD steps. Sensitivity of the model parameters, consisting of controller gains for accommodation (ACG) and vergence (VCG), crosslink gains for accommodation-to-vergence (AC) and vergence-to-accommodation (CA), deadspace operators for accommodation (AE±AD) and vergence (VE±VD), and the tonic levels for accommodation (ABIAS) and vergence (VBIAS) were assessed by varying them at 50% and 150% of their normal values. It was found that the accommodation and vergence systems mere most sensitive to variation in crosslink gain, moderately sensitive to variation in controller gain and tonic level, and least sensitive to variation in size of the deadspace. These results may provide a quantitative basis for the occurrence of ocular dysfunctions associated with abnormal crosslink gains, such as strabismus, in clinical patients     

Long-wavelength GaInNAs(Sb) lasers on GaAs

The boom in fiber-optic communications has caused a high demand for GaAs-based lasers in the 1.3-1.6-μm range. This has led to the introduction of small amounts of nitrogen into InGaAs to reduce the bandgap sufficiently, resulting in a new material that is lattice matched to GaAs. More recently, the addition of Sb has allowed further reduction of the bandgap, leading to the first demonstration of 1.5-μm GaAs-based lasers by the authors. Additional work has focused on the use of GaAs, GaNAs, and now GaNAsSb barriers as cladding for GaInNAsSb quantum wells. We present the results of photoluminescence, as well as in-plane lasers studies, made with these combinations of materials. With GaNAs or GaNAsSb barriers, the blue shift due to post-growth annealing is suppressed, and longer wavelength laser emission is achieved. Long wavelength luminescence out to 1.6 μm from GaInNAsSb quantum wells, with GaNAsSb barriers, was observed. In-plane lasers from these samples yielded lasers operating out to 1.49 μm, a minimum threshold current density of 500 A/cm² per quantum well, a maximum differential quantum efficiency of 75%, and pulsed power up to 350 mW at room temperature     

Depression in the quantity of intestinal secretory IgA and in the expression of the polymeric immunoglobulin receptor in caloric deficiency of the weanling mouse

Splenomegaly is uncommon in myelodysplasia (MDS) and, although cytopenias may be severe, therapeutic splenectomy is rarely performed. We report the histologic, histochemical, and immunophenotypic findings of nine cases of surgical splenectomy and four postmortem spleens from MDS patients. Four histologic patterns were identified: one dominated by erythrophagocytosis, one characterized by red pulp plasmacytosis, one with extramedullary hematopoiesis as the only salient finding, and one with marked red pulp expansion caused by a monocytic proliferation. Wright-Giemsa and histochemical stains were performed on touch preparations in three cases and played a critical role in the precise subclassification of one MDS patient's hematologic disorder, which ultimately proved to be chronic myelomonocytic leukemia. Splenectomy led to sustained improvement of cytopenias in three cases, but did not eliminate transfusion dependence for the remaining patients. Three splenectomy cases exhibited clustered Leder-negative mononuclear elements: two of these patients experienced disease progression to refractory anemia with excess blasts in transformation or acute myelogenous leukemia during post-splenectomy follow-up, whereas none of the three splenectomy patients without clustered mononuclear elements did. We conclude that splenomegaly in MDS usually reflects the sequelae of dyspoiesis rather than evidence of a proliferative phase, that clustering of Leder-negative large cells may correlate with either a substantial monocytic component or, possibly, increased risk of disease progression, and that the spleen can provide diagnostic as well as prognostic information in MDS patients with splenomegaly.     

Characterization of arylamine N-acetyltransferase in Enterobacter aerogenes

N-acetyltransferase (NAT) activity was determined by incubation of purified Enterobacter aerogenes enzyme with 2-aminofluorene (2-AF) as the substrate, followed by high pressure liquid chromatography assays. The NAT activity from E. aerogenes was 0.58 +/- 0.08 nmol/min/mg protein for 2-AF. The values of apparent K(m) and Vmax were 0.72 +/- 0.14 mM and 2.45 +/- 0.29 nmol/min/mg protein, respectively, for 2-AF. The optimal pH value for the enzyme activity was 7.5 for the 2-AF tested. The optimal temperature for enzyme activity was 37 degrees C for the 2-AF substrate. The molecular weight of NAT from E. aerogenes was 44.9 kD. Among a series of divalent cations and salts, Zn2+, Ca2+, and Fe2+ were demonstrated to be the most potent protease inhibitors, and only ethylenediaminetetraacetic acid significantly protected the NAT. Iodoacetamide, in contrast to other agents, markedly inhibited NAT.     

Preparation and densification of superconducting YBa2Cu3Ox ceramics

The solid-state reaction method to form the superconducting oxide YBa₂Cu₃O _x was studied. It was found that the starting cupric and yttrium components accelerated the decomposition of the BaCO₃ component. At a constant heating rate of 10 ° Cmin^–1 in thermogravimetric analysis, the temperature of complete decomposition,T _f, was lowered from greater than 1000 ° C in pure BaCO₃ to between 915 and 985 ° C. The effectiveness in decreasingT _f can be ranked in the order of oxalate, carbonate and oxide. The highest sintered density achieved in this study was 6.03 g cm^–3 (/_th = 95%) at 990 ° C and 5.85 g cm^–3 (/_th = 92%) at 960 ° C. The source of cupric ion had the largest effect on densification. The use of cupric carbonate resulted in a consistently high Archimedes density of about 6.00gcm^–3 and large dimensional shrinkage of about 20% at 990 ° C for 12h. In contrast, the use of cupric oxide gave the lowest density and smallest shrinkage. Within the same powder lot, higher sintered density and smaller dimensional shrinkage were observed in samples with higher initial green density and compaction pressure. However, the data suggested that the enhanced densification and higher density achieved by the use of cupric carbonate and oxalate cannot be accounted for by the different physical characteristics of the powders and the mechanics of powder compaction, measured collectively by the green density.     

Roll‐to‐roll UV embossing process applied for light bar‐based sub‐wavelength gratings for backlight

This study proposes a roll‐to‐roll process‐based sub‐wavelength grating, which is attached on a light bar to turn the side‐lit red/green/blue (620, 520, and 450 nm) incident rays into a uniformly and normally output white light with high illuminance from the light bar's surface. On the basis of the rigorous coupling wave analysis, the relationship between the first‐order transmission/reflection efficiency and the pitch of the gratings with different shapes was analyzed. The optimal design can effectively reduce the coupling length and enhance the white color balance for display applications.     

Extrinsic calibration of a camera and laser range finder using a new calibration structure of a plane with a triangular hole

Sensor fusion of a camera and laser range finder is important for the autonomous navigation of mobile robots. Finding the transformation between the camera and laser range finder is the first necessary step for the fusion of information. Many algorithms have been proposed, but these tend to require many different steps in order to achieve reliable and accurate results. A calibration structure that has triangular hole on its plane is proposed for the extrinsic calibration of a camera and laser range finder. Locations of laser scan data that are invisible on the calibration plane can be determined using property on the proposed calibration structure. First, we classify the laser scan data into two groups where one is on the plane and the other is off the plane. Then, we determine the absolute location of the laser scan data on the plane through a search of the parameters of the line. Finally, we can establish 3D-3D correspondences between the camera and laser range finder. Extrinsic calibration between a camera and laser range finder is found using a conventional 3D-3D transformation computing algorithm. Keywords: Calibration k]camera k]extrinsic calibration k]laser range finder