A Modified Method for the Determination of N‐Nitrosodiethanolamine in Coconut Diethanolamide Using HPLC with Dual‐Wavelength UV–Vis Detector

A simple and novel method based on high‐performance liquid chromatography with dual‐wavelength ultraviolet detection at 234 and 254 nm has been developed for the determination of underivatized N‐nitrosodiethanolamine in coconut diethanolamide. The correlation coefficient obtained shows that the method is correct.     

A synthesis of functionalized spiro isobenzofuran-1,6′-[1,3] thiazines from phthalic anhydride-malononitrile adduct and ammonium carbamodithioates

The reaction of 2-[3-oxo-isobenzofuran-1(3H)- ylidene]malononitrile, generated from phthalic anhydride and malononitrile, with ammonium alky(aryl)carbamodithioates, leading to the formation of functionalized spiro isobenzofuran-1,6′-[1,3]thiazine systems, in good yields, is reported.     

Cyclic preference scheduling of nurses using a Lagrangian-based heuristic

This paper addresses the problem of developing cyclic schedules for nurses while taking into account the quality of individual rosters. In this context, quality is gauged by the absence of certain undesirable shift patterns. The problem is formulated as an integer program (IP) and then decomposed using Lagrangian relaxation. Two approaches were explored, the first based on the relaxation of the preference constraints and the second based on the relaxation of the demand constraints. A theoretical examination of the first approach indicated that it was not likely to yield good bounds. The second approach showed more promise and was subsequently used to develop a solution methodology that combined subgradient optimization, the bundle method, heuristics, and variable fixing. After the Lagrangian dual problem was solved, though, there was no obvious way to perform branch and bound when a duality gap existed between the lower bound and the best objective function value provided by an IP-based feasibility heuristic. This led to the introduction of a variable fixing scheme to speed convergence. The full algorithm was tested on data provided by a medium-size U.S. hospital. Computational results showed that in most cases, problem instances with up to 100 nurses and 20 rotational profiles could be solved to near-optimality in less than 20 min.     

Design and simulation of a novel metallic microgripper using vibration to release nano objects actively

In this study, we investigate a novel metallic microgripper which is able to grasp and transport nano particles (nano tubes/wires) and release them on desirable substrate by vibrating the gripper arms. This microgripper consists of a chevron actuator to grip nano object electrothermally and interdigited comb drive systems to generate vibration at the gripper arms electrostatically. Metallic (nickel) properties enable the chevron actuator to close the gap and pick the nano particle at low voltage and temperature. In order to reduce the out of plane bending during operation and also increase the gripping force, thickness of the nickel layer must be increased, hence electroplating process is proposed for deposition of nickel layer. To generate vibration at the end effectors, comb drive systems are stimulated by applying two voltage signals at desired resonant frequency to the stators. Practically, by sweeping the frequency of these signals around the resonant frequency the end effectors start vibrating. The vibration results in overcoming the adhesion forces due to inertial effects.     

Support vector regression methodology for prediction of input displacement of adaptive compliant robotic gripper

The prerequisite for new versatile grippers is the capability to locate and perceive protests in their surroundings. It is realized that automated controllers are profoundly nonlinear frameworks, and a faultless numerical model is hard to get, in this way making it troublesome to control utilizing tried and true procedure. Here, a design of an adaptive compliant gripper is presented. This design of the gripper has embedded sensors as part of its structure. The use of embedded sensors in a robot gripper gives the control system the ability to control input displacement of the gripper and to recognize specific shapes of the grasping objects. Since the conventional control strategy is a very challenging task, soft computing based controllers are considered as potential candidates for such an application. In this study, the polynomial and radial basis function (RBF) are applied as the kernel function of Support Vector Regression (SVR) to estimate and predict optimal inputs displacement of the gripper according to experimental tests and shapes of grasping objects. Instead of minimizing the observed training error, SVR _poly and SVR _rbf attempt to minimize the generalization error bound so as to achieve generalized performance. The experimental results show that an improvement in predictive accuracy and capability of generalization can be achieved by the SVR approach compared to other soft computing methodology.     

Dynamic modeling and CPG-based trajectory generation for a masticatory rehab robot

Human mastication is a complex and rhythmic biomechanical process which is regulated by a brain stem central pattern generator (CPG). Masticatory patterns, frequency and amplitude of mastication are different from person to person and significantly depend on food properties. The central nervous system controls the activity of muscles to produce smooth transitions between different movements. Therefore, to rehab human mandibular system, there is a real need to use the concept of CPG for development of a new methodology in jaw exercises and to help jaw movements recovery. This paper proposes a novel method for real-time trajectory generation of a mastication rehab robot. The proposed method combines several methods and concepts including kinematics, dynamics, trajectory generation and CPG. The purpose of this article is to provide a methodology to enable physiotherapists to perform the human jaw rehabilitation. In this paper, the robotic setup includes two Gough–Stewart platforms. The first platform is used as the rehab robot, while the second one is used to model the human jaw system. Once the modeling is completed, the second robot will be replaced by an actual patient for the selected physiotherapy. Gibbs–Appell’s formulation is used to obtain the dynamics equations of the rehab robot. Then, a method based on the Fourier series is employed to tune parameters of the CPG. It is shown that changes in leg lengths, due to the online changes of the mastication parameters, occur in a smooth and continuous manner. The key feature of the proposed method, when applied to human mastication, is its ability to adapt to the environment and change the chewing pattern in real-time parameters, such as amplitudes as well as jaw movements velocity during mastication.     

Predicting performance in ASEAN banks: an integrated fuzzy MCDM–neural network approach

This paper presents a performance assessment of 88 Association of Southeast Asian Nations banks from 2010 to 2013, using an integrated three‐stage approach on financial criteria that emulates the CAMELS rating system. More precisely, fuzzy analytic hierarchy process is used first to assess the relative weights of a number of criteria related to capital adequacy (C), asset quality (A), management quality (M), earnings (E), liquidity (L), and sensitivity to market risk (S) based on the opinion of 88 Association of Southeast Asian Nations experts. Then, these weights are used as technique for order of preference by similarity to ideal solution inputs to assess their relative efficiency. Lastly, neural networks are combined with technique for order of preference by similarity to ideal solution results to produce a model for banking performance with effective predictive ability. The results reveal that contextual variables have a prominent impact on efficiency. Specifically, parsimony in equity leveraging derived from Islamic finance principles may be the underlying cause in explaining higher efficiency levels.     

Adaptive Network-Based Fuzzy Inference Systems Coupled with Genetic Algorithms for Predicting Soil Permeability Coefficient

This paper extends hybrid-type optimization models of genetic algorithm adaptive network-based fuzzy inference system (GA-ANFIS) for predicting the soil permeability coefficient (SPC) of different types of soil. In these models, GA optimizes parameters of a subtractive clustering technique that controls the structure of the ANFIS model’s fuzzy rule base. Simultaneously, a hybrid leaning algorithm is employed in the ANFIS, as a trained fuzzy inference system (FIS), which optimally determines the parameter sets of the examined FISs in ANFIS. Using an updated large database of SPCs consisting of 338 fine-grained, 178 mixed and 94 granular soil samples, GA-ANFIS framework constructs different models of predicting the permeability coefficient of respectively fine-grained, mixed and granular soils. A fuzzy C-mean technique has been used to cluster the entire data samples of each type of soil and divide them uniformly into training and testing data sets. Different prediction models of SPC have been trained and tested for each of the three soil types, and the appropriate models have been selected. The selected models have been compared with ANN and modified-by-GA empirical prediction models. Results show that the constructed GA-ANFIS models outperform the other models in terms of the prediction accuracy and the generalization capability.